兰州市冬季SO2大气环境容量研究

通过数值模拟方法,研究了兰州市冬季SO2的大气环境容量,为大气污染的总量控制方法提供了前提和依据。本文利用RAMs三维非流体静力大气动力模式模拟的气象场驱动中尺度大气扩散模式(HYPACT),模拟出SO2的浓度分布及每个污染单元对于地面浓度的分担率。根据SO2的国家环境空气质量标准(下称质量标准),用线性规划的原理和方法计算了兰州市冬季典型日条件下SO2的大气环境容量。     

Sources and variability of CO2 in a prealpine stream gravel bar

Gravel bars (GBs) contribute to carbon dioxide (CO₂) emissions from stream corridors, with CO₂ concentrations and emissions dependent on prevailing hydraulic, biochemical, and physicochemical conditions. We investigated CO₂ concentrations and fluxes across a GB in a prealpine stream over three different discharge‐temperature conditions. By combining field data with a reactive transport groundwater model, we were able to differentiate the most relevant hydrological and biogeochemical processes contributing to CO₂ dynamics. GB CO₂ concentrations showed significant spatial and temporal variability and were highest under the lowest flow and highest temperature conditions. Further, observed GB surface CO₂ evasion fluxes, measured CO₂ concentrations, and modelled aerobic respiration were highest at the tail of the GB over all conditions. Modelled CO₂ transport via streamwater downwelling contributed the largest fraction of the measured GB CO₂ concentrations (31% to 48%). This contribution increased its relative share at higher discharges as a result of a decrease in other sources. Also, it decreased from the GB head to tail across all discharge‐temperature conditions. Aerobic respiration accounted for 17% to 36% of measured surface CO₂ concentrations. Zoobenthic respiration was estimated to contribute between 4% and 8%, and direct groundwater CO₂ inputs 1% to 23%. Unexplained residuals accounted for 6% to 37% of the observed CO₂ concentrations at the GB surface. Overall, we highlight the dynamic role of subsurface aerobic respiration as a driver of spatial and temporal variability of CO₂ concentrations and evasion fluxes from a GB. As hydrological regimes in prealpine streams are predicted to change following climatic change, we propose that warming temperatures combined with extended periods of low flow will lead to increased CO₂ release via enhanced aerobic respiration in newly exposed GBs in prealpine stream corridors.     

BOOK REVIEWS

Books Reviewed in this article: Lob Trees in the Wilderness . Clifford and Isabel Ahlgren . Satellite Microwave Remote Sensing . T. D. Allan , ed. Sunbelt Cities: Politics and Growth Since World War II . Richard M. Bernard and Bradley R. Rice , eds. Legacy of Minneapolis: Preservation Amid Change . John R. Borchert , David Gebhard , David Lanegran , and Judith A. Martin . Bloomington, MN: Preparing a Historic Preservation Ordinance. Richard J. Roddewig . The Mountains of Northeastern Tasmania, A Study of Alpine Geomorphology . Nel Caine . Introductory Cartography . John Campbell . Englewood Cliffs, NJ: Changing Climate . Manual of Remote Sensing, Second Edition . 2 Vols. Robert N. Colwell , ed.-in-chief; David S. Simonett and John E. Estes , vol. eds. Remote Sensing in Meteorology, Oceanography and Hydrology . A. P. Cracknell , ed. Multidimensional Scaling . Mark L. Davison . Environmental Karst . Percy H. Dougherty , ed. The Urban Environment . Ian Douglas . Geomorphology of Europe . Clifford Embleton , ed. An Introduction to South Asia . B. H. Farmer . Great Geological Controversies . A. Hallam . Hazardous Waste Management: In Whose Backyard? Michalann Harthill , ed. Energy for Subsistence . Margaret Haswell . Perspective on Ratzel's Political Geography . James M. Hunter . Economic Deposits and their Tectonic Setting . Charles S. Hutchison . Energy Risk Assessment . Herbert Inhaber . Discovering the Vernacular Landscape . John Brinckerhoff Jackson . Climate and Energy Systems: A Review of Their Interactions . Jill Jäger . Dilemmas in Regional Policy . Antoni Kuklinski and J. G. Lambooy , eds. California Farmland: A History of Large Agricultural Landholdings . Ellen Liebman . The Spatial Organization of New Land Settlement in Latin America . Jacob O. Maos . Dark Continent: Africa as Seen by Americans . Michael McCarthy . Westport, CT: Climatology: An Introduction . John E. Oliver and John J. Hidore . Columbus, OH: The Geography of Warfare . Patrick O'Sullivan and Jesse W. Miller . The Expanding City. Essays in Honour of Professor Jean Gottmann . John Patten , ed. Scotland's Environment During the Last 30,000 Years . Robert J. Price . Integrated Urban Models . S. H. Putman . Development and the Environmental Crisis: Red or Green Alternatives? Michael Redclift .     

Impact of experimental parameters for manometric equipment on CO2 isotherms measured: Comment on “Inter-laboratory comparison II: CO2 isotherms measured on moisture-equilibrated Argonne premium coals at 55°C and up to 15 MPa” by Goodman et al. (2007)

Modelling the sorption properties of coals for carbon dioxide under supercritical conditions is necessary for accurate prediction of the sequestering ability of coals in seams. We present recent data for sorption curves of three dry Argonne Premium coals, for carbon dioxide, methane and nitrogen at two different temperatures at pressures up to 15 MPa. The sorption capacity of coals tends to decrease with increasing temperature. An investigation into literature values for sorption of nitrogen and methane by charcoal also show sorption capacities that decrease dramatically with increasing temperature. This is inconsistent with expectations from Langmuir models of coal sorption, which predict a sorption capacity that is independent of temperature. We have successfully fitted the isotherms using a modified Dubinin–Radushkevich equation that uses gas density rather than pressure. A simple pore-filling model that assumes there is a maximum pore width that can be filled in supercritical conditions and that this maximum pore width decreases with increasing temperature, can explain this temperature dependence of sorption capacity. It can also explain why different supercritical gases give apparently different surface sorption capacities on the same material. The calculated heat of sorption for these gases on these coals is similar to those found for these gases on activated carbon.     

Regional search, selection and geological characterization of a large anticlinal structure, as a candidate site for CO2-storage in northern Germany

This paper reports on the regional screening, selection and geological characterisation of a potential on-shore CO₂ storage site (saline aquifer) in north-eastern Germany. The main objective of this study was to identify and investigate a candidate storage site, capable to accommodate the total amount of approximately 400 million tons of CO₂. Such a volume is produced by a modern, lignite-fired power plant within its operation lifetime of approximately 40 years. Within north-eastern Germany, several saline aquifers of Triassic, Jurassic and Cretaceous age have been evaluated with respect to their regional occurrence, storage potential and basic reservoir properties. Subsequent to a ranking, considering different criteria, the anticlinal structure Schweinrich holding suitable saline aquifers of the uppermost Triassic and lowest Jurassic has been selected from a number of identified candidate sites. According to results of the geological site characterisation, including structural geological investigations and 3D reservoir modelling, the structure Schweinrich seems to be a suitable site for industrial large scale CO₂ storage. Further data acquisition (new wells and 3D seismics) and research (more detailed and comprehensive modelling) is needed in order to prove the structural integrity of the storage site and assure long-term safety.     

Site characterization for CO<Subscript>2</Subscript> geologic storage and vice versa: the Frio brine pilot,Texas, USA as a case study

Careful site characterization is critical for successful geologic storage of carbon dioxide (CO₂) because of the many physical and chemical processes impacting CO₂ movement and containment under field conditions. Traditional site characterization techniques such as geological mapping, geophysical imaging, well logging, core analyses, and hydraulic well testing provide the basis for judging whether or not a site is suitable for CO₂ storage. However, only through the injection and monitoring of CO₂ itself can the coupling between buoyancy flow, geologic heterogeneity, and history-dependent multi-phase flow effects be observed and quantified. CO₂ injection and monitoring can therefore provide a valuable addition to the site-characterization process. Additionally, careful monitoring and verification of CO₂ plume development during the early stages of commercial operation should be performed to assess storage potential and demonstrate permanence. The Frio brine pilot, a research project located in Dayton, Texas (USA) is used as a case study to illustrate the concept of an iterative sequence in which traditional site characterization is used to prepare for CO₂ injection and then CO₂ injection itself is used to further site-characterization efforts, constrain geologic storage potential, and validate understanding of geochemical and hydrological processes. At the Frio brine pilot, in addition to traditional site-characterization techniques, CO₂ movement in the subsurface is monitored by sampling fluid at an observation well, running CO₂-saturation-sensitive well logs periodically in both injection and observation wells, imaging with crosswell seismic in the plane between the injection and observation wells, and obtaining vertical seismic profiles to monitor the CO₂ plume as it migrates beyond the immediate vicinity of the wells. Numerical modeling plays a central role in integrating geological, geophysical, and hydrological field observations.     

南极普里兹湾及邻近海域二氧化碳的分布及其海气通量

本文根据１９９１年１２月至１９９２年１月在普里兹湾及其邻近海域所作的现场观测，采用红外分析法测定了表层水和大气ＣＯ２分压，结果表明，表层水ＰＣＯ２的分布大致呈近岸低、远岸高的特征，其分布变化主要受生物活动控制。利用通量计算模式，估算出ＣＯ２在调查海域的平均海－气通量为－７１．９ｇ／（ｍ２ａ），通量的可能误差主要来自与风速有关的交换系数。     

Tunable diode laser measurements of trace gases during the 1988 Polarstern cruise and intercomparisons with other methods

Measurements of NO₂, HCHO, and H₂O₂ were made by the highly specific method of mid infra-red absorption spectroscopy using tunable diode lasers (TDLAS) during the 1988 Polarstern expedition. The TDLAS data are compared to those obtained during the cruise using less direct methods. Southern Hemisphere NO₂ levels suggest nett photochemical destruction of O₃ in the boundary layer. Northern Hemisphere HCHO averaged 0.47±0.2 ppbv; the HCHO measurements are used in a simple calculation to estimate OH noontime maxima of 3–6×10⁶ cm^-3.     

On the scavenging of gaseous nitrogen compounds by large and small rain drops: II. Wind tunnel and theoretical studies of the simultaneous uptake of NH3, SO2 and CO2 by water drops

An experimental investigation of the simultaneous absorption of NH₃ and SO₂ from the ambient atmosphere by freely falling water drops has been carried out in the Mainz vertical wind tunnel. The experimental results were found to be in good agreement with the results derived from computations with the Kronig-Brink convective diffusion model and also with a model which assumes a drop to be well mixed at all times. Encouraged by this agreement, these computation schemes for the uptake of gas by single drops where incorporated in a pollution washout model with realistic SO₂, NH₃ and CO₂ gas profiles. This model allows an entire raindrop size distribution to fall through a gas layer. The results of this plume-model show that the SO₂ uptake is strongly dependent on the NH₃ concentration in the atmosphere and on the rainrate. We also find that the small drops contribute more towards the washout of these gases. In the case of simultaneous presence of NH₃ and SO₂, desorption of these gases is negligible.     

中华哲水蚤抗氧化系统对海水酸化的响应

海洋浮游动物可以对因二氧化碳浓度升高导致的海水酸化做出敏感的响应,然而关于海水酸化对其生理机能的研究却较少。因此,我们研究了暴露于不同二氧化碳浓度（0.08,0.20,0.50 and 1.00%）的酸化条件下中华哲水蚤主要抗氧化酶以及2种解毒酶的活性变化情况。结果表明,暴露于酸化海水中的中华哲水蚤的GPx酶活性显著高于对照组,然而,其它抗氧化组分,包括GST、SOD活性,GSH水平和GSH/GSSG比值均被显著抑制。中华哲水蚤的ATPase活性被海水酸化显著刺激,而AchE活性却显著被抑制。此外,主成分分析结果表明,各指标变化的75.93%可以用第一和第二主成分解释。因二氧化碳浓度升高导致的海水酸化可以通过影响桡足类体内一些酶类的活性来影响其新陈代谢及存活。在未来的研究工作中,需要对海水酸化和其它环境因素的协同作用对桡足类的影响作进一步研究。