孔道结构化合物(H3NCH2CH2NH3)3[(VO)4(PO4)2(HPO4)4]的钒氧化态与热稳定性关系研究

热处理脱除有机模板易导致VPO体系孔道结构化合物结构破坏,从而阻碍此类材料的实际应用。以孔道结构化合物(H3NCH2CH2NH3)3[(VO)4 (PO4 )2 (HPO4 )4 ](简称V2P3 en)为研究对象,利用热分析(DSC TG)、动态原位高温X 射线衍射(XRD)及多功能X 射线光电子能谱(XPS)等方法,研究了该化合物在不同气氛热处理过程中模板脱除及结构演化规律,重点探讨了钒氧化态的变化对结构稳定性的影响。结果表明,加热过程中随着有机模板的分解脱除,形成较强的还原环境,骨架中的部分钒被还原(V4+→V3+),使原有的配位环境([VⅣO5]三角双锥、[VⅣO6]畸变八面体)与钒的氧化态不符而导致结构重组。因此,钒氧化态的变化是影响热稳定性的重要因素之一。     

“麦莎”远距离台风暴雨的排熵指数分析

对2005年8月5日山东省一次远距离台风暴雨过程进行了诊断分析。从引起远距离台风暴雨的几个因素,分析此次山东地区强降水过程与台风“麦莎”及中纬度西风带系统的关系,判别台风暴雨的类型;应用耗散结构理论,分析了排熵指数与远距离台风暴雨区的关系。结果表明：该次暴雨过程是在远距离台风（0509号“麦莎”台风）和西风槽相互作用下产生的;非纬向的高、低空急流对本次暴雨过程起着重要作用;负熵变区（IRE〈0）对应着暴雨区,负熵变区的汇合反映远距离台风暴雨的落区,排熵指数对远距离台风暴雨分析预报有一定的指示作用。     

硫铝酸盐水泥去除微污染水体中磷的性能及机理

微污染湖泊、水库等水体中磷的去除已成为水质研究的主要方向.磷是造成水体富营养化的关键因素,其浓度较低时即可导致水体富营养化与水华的发生,许多除磷方法对低浓度磷的去除效果不佳.因此,我们从22种天然矿物、火山灰质材料和水硬性材料中,筛选出了能高效去除低浓度磷的硫铝酸盐水泥(代号R.SAC 42.5,简称R),该材料在中性...     

提高生态浮床系统脱氮除磷效率研究进展

生态浮床系统处理技术因具有投资少、易操作、无二次污染兼具良好景观性等优点而被广泛应用于各种类型污染水体的治理。生态浮床系统是一个复合生态工程系统,其对污染的去除机理是一个错综复杂的过程,填料、水生植物、水生动物和微生物共同发挥着重要作用。主要概述生态浮床系统的发展状况、脱氮除磷机理、限制因素及存在问题;重点概述以细菌固定化技术和曝气等方式的外在法和以改进生态浮床系统构造形式、筛选优势浮床植物等方式的内在法,来提高生态浮床系统脱氮除磷效率;展望了生态浮床污水处理系统未来的研究与应用前景。     

THE REMOVAL OF Zn,Cd,Pb,AND Cu IN THE CHANGJIANG ESTUARY

The waters with salinity from 10 to 23 comprise the main removal region of ion and particulateforms of heavy metals in the Changjiang estuary.The positive correlationships between Zn,Cd,Pb,Cuand the reciprocal of transparency,COD and chlorophyll-a showed that the removal of heavy metalsclosely correlate with the distribution of suspensions,the adsorption of organic materials and theassimilation by organisms.The removal of heavy metals in the Changjiang estuary water were consistentwith the sedimentation rate of the sediments in these waters,sediment types and the distributions ofheavy metals contents in the sediments.     

基于热红外遥感技术的腾冲地区地热异常区温度反演研究

我国云南腾冲地区地热资源丰富,对地热资源进行定量的预测评价势在必行。而以遥感为手段进行地表温度的反演是地热研究的重要方法。本文利用ETM数据的Band6热红外通道,对工作区进行温度反演并通过消除阴影影响对反演温度进行修正使得温度差异较大的情况得到改善,减少了太阳照射造成的温差影响。结果表明,研究区地表温度分布主要有3个区域;通过温度反演结果与已知地热点叠加分析,选取14~21℃为进行地热预测评价的有利区间。     

不同气水比对两种人工湿地除污效果的影响

为比较不同气水比下各类型人工湿地的除污效果,选取火山石、炉渣和牡蛎壳作为人工湿地构建基质,研究两种人工湿地(表面流和潜流人工湿地)在不同气水比(0,2,4,6,8)下对污水的净化效果。结果表明:潜流型人工湿地对COD、NH_4~+-N及TP的去除率均高于表面流人工湿地;尤其是在COD的去除过程中,当气水比≥4时,潜流式湿地对污染物的去除效果显著高于表面流人工湿地。此外,适当曝气可显著提高人工湿地对COD、NH_4~+-N及TP的去除率,气水比为4时,表面流和潜流人工湿地对COD及TP的去除率显著高于气水比为0和2时的去除率。对NH_4~+-N而言,表面流和潜流人工湿地分别在气水比为8和6时达到最大去除率。气水比和人工湿地类型的交互作用对污染物的去除率影响不显著,在实际工程中可以忽略组合效应,致力于确定湿地类型及气水比各自对湿地除污效果的最优条件。     

Plowing paradise: snow clearing and urban solar radiation absorption

Abstract

Urban heat islands result from human modification of land surfaces. Snow cover reduces heating due to its reflectivity; however, urban snow is quickly plowed, thus altering surface radiative properties. The goal of this study was to evaluate the extent to which municipal snow removal affects the magnitude of solar input associated with changes in the radiation balance. Incoming and reflected shortwave radiation, surface radiating temperature, air temperature, and snow depth were measured with portable devices at eight sites in Syracuse, New York. Sites were classified as cleared, undisturbed, or snow piles. Measurements were taken following fresh snowfall, and continuing until snow had melted. A HOBO weather station provided hourly baseline conditions. Longevity of snow varied across snow site types, with greater persistence when in piles and on open areas. Albedo was reduced and surface temperatures were higher over cleared areas. The difference between absorbed energy due to clearing was quantified using an albedo regression model for undisturbed sites and comparing these to average reflectivity of cleared surfaces. The magnitude difference over the study period ranged from 841 million to 1670 million MJ. Snow plowing is therefore a significant source of additional energy that enhances the winter urban heat island.