人工湿地研究现状与展望

自1950s开始系统性研究以来,人工湿地研究日趋深入,也得到了广泛的应用.本文基于文献报道,对人工湿地研究的历程特别是我国的研究进行了分析,分为起步探索、迅猛发展和规范应用三个阶段.梳理了人工湿地的研究现状,主要集中在如何提高脱氮除磷效率、对新兴污染物的去除、人工湿地根区微生物结构与功能以及人工湿地模型四个方面.核心还是提高人工湿地对污染物的去除效率并解释其机理.未来需要长期监测数据支撑的理论实践结合的设计规程;进一步揭示人工湿地的生物过程;建立合理简化的模型,对系统进行准确预测.     

旁路多级人工湿地对巢湖流域南淝河水的净化效果

为了削减南淝河输入巢湖的污染物,建成南淝河旁路多级人工湿地水质净化示范工程,包括预处理系统、垂直潜流湿地系统和水平潜流湿地系统3个工艺单元.2014年3月至2015年2月对人工湿地各净化单元出水进行周年监测,分析各净化单元对污染物的去除效果,并探讨季节变化对去除效果的影响.结果显示,旁路多级人工湿地体现较高的去除效果.对高锰酸盐指数(COD_(Mn))、总氮(TN)、铵态氮(NH_4~+-N)和总磷(TP)的总去除率分别为70.9%、43.7%、43.5%和76.6%.COD_(Mn)和TP的平均出水浓度均优于《地表水环境质量标准》(GB 3838-2002)中的Ⅳ类水标准,而NH_4~+-N的平均出水浓度优于《城镇污水处理厂污染物排放标准》(GB 18918-2002)一级A类标准.各净化单元对污染物的去除差异显著,COD_(Mn)的去除主要发生在预处理单元,其对COD_(Mn)削减的净化率为65.1%;TN、NH_4~+-N和TP的去除主要发生在垂直潜流湿地单元,其对TN、NH_4~+-N和TP削减的净化率分别为23.2%、27.1%和51.1%.不同季节,旁路多级人工湿地对污染物去除具有一定差异,对COD_(Mn)和TP的去除率均表现为夏季秋季春季冬季,对TN的去除率表现为秋季春季夏季冬季,对NH_4~+-N的去除率表现为秋季夏季春季冬季.最后,建议通过增加碳源和增大水力停留时间来进一步优化该工艺,以有效提高脱氮效果.     

A decadal-scale numerical model for wandering,cobble-bedded rivers subject to disturbance

Alluvial rivers are composed of self-formed channels which are sensitive to disturbances in their flow and sediment-supply regimes. Regime changes commonly occur over decadal and longer timescales and can be caused by anthropogenic alterations such as dam construction and removal. Advances in numerical modeling have increased our ability to explore geomorphic adjustments over long timescales; however, many models designed to be run for decades or longer assume that banks are immovable or that channel width is constant. Since river channels often respond to disturbance by adjusting their geometry, this is a significant shortcoming. To investigate the impact of long-term sediment supply alterations on channel geometry and stability, we have adapted MAST-1D, a reach-scale bed evolution model, to incorporate functions for bank erosion, vegetation encroachment, and local avulsions. The model is designed for medium-large, coarse multithreaded rivers and can be run over long (decades–centuries) timescales. Bank erosion is a function of the mobility and transport capacity for structurally-important grains which protect the bank toe. Vegetation growth is proportional to point bar width and occurs during conditions of low shear stress. Local avulsions occur when aggradation causes channel depth to drop below a threshold. We apply the model to the Elwha River in Washington, USA with the goal of investigating if and when the river recovers from dam emplacement and removal. The Elwha was dammed for nearly 100 years, and then two dams were removed, releasing a large pulse of sediment. We have modeled the set of reaches between the two dams. Our simulations suggest that channel response to dam emplacement occurs gradually over several decades but that the channel recovers to near pre-dam conditions within about a decade following the removal. The dams leave a lasting legacy on the floodplain, which does not completely recover, even after two centuries. © 2019 John Wiley & Sons, Ltd.     

Is There Any Correlation Between Landscape Characteristics and Total Nitrogen in Wetlands Receiving Agricultural Drainages?

In the case of increasing fragmentation of wetlands, the study of the relationship between wetland landscape characteristics and total nitrogen(TN) in water is of great significance to reveal the mechanism of wetland water purification. Taking the Naoli River(NR) wetlands in Northeast China as the research object, 10 uniformly distributed sampling sites in the study area were sampled in August 2015 to test the TN concentration and interpret the images of NR wetlands in the same period. Taking the sampling site as the control point, the whole wetlands were divided into 10 regions, and the landscape index of each region was extracted. In order to reveal whether the landscape characteristics are related to the TN concentration in the wetlands water body, the landscape index and the TN concentration in the control point water body were analyzed by correlation analysis, step-by-step elimination analysis and path analysis to reveal whether the landscape characteristics are related to the TN concentration under wetlands receiving agricultural drainages. The results showed that the correlation coefficients between four area indexes or eight shape indexes and TN concentration did not reach a significant correlation level(P > 0.05), indicating that TN removal was not only determined by a single landscape index. The path coefficient of edge density(ED) index is –0.41, indicating that wetland patch connectivity is the primary factor of TN removal, and there is no relationship between the larger patch area and the higher TN removal. The removal of TN in wetlands is restricted by the synergistic effect of landscape area and shape characteristics.     

镀镍多壁碳纳米管对序批式反应器性能及其微生物群落的影响

本文研究了长期暴露条件下镀镍多壁碳纳米管(MWCNTs-Ni)对序批式反应器(SBR)性能、微生物酶活性和微生物群落的影响。研究结果表明,10mg/LMWCNTs-Ni的长期暴露未对SBR去除有机物产生影响,而NH+4-N的去除率由(99.10±0.60)%明显降至(39.04±1.61)%。与进水中未加入MWCNTs-Ni时的第32天相比,活性污泥比耗氧速率(SOUR)和脱氢酶(DHA)活性在第148天时分别降低了17.43%和24.32%;而脱氮速率和与脱氮相关的微生物酶活性均降低了60%以上,从而导致SBR对氮的去除效果明显降低。MWCNTs-Ni的长期暴露导致活性污泥活性氧(ROS)产生量和乳酸脱氢酶(LDH)释放量在第148天时分别增加了67.23%和65.33%,表明MWCNTs-Ni的长期暴露能够诱导活性污泥中微生物产生氧化应激和细胞膜损伤。高通量测序结果表明,长期暴露于10mg/L的MWCNTs-Ni条件下,活性污泥中与硝化过程相关菌属(Nitrosomonas、Nitrosospir、Nitrospira)和与反硝化过程相关菌属(Dokdonella、Dechloromonas、Steroidobacter、Devosia、Thermomonas)的相对丰度明显降低,进而影响到SBR对氮的去除。该研究结果可为评价MWCNTsNi对污水生物处理系统的潜在影响提供一定的理论基础和技术依据。     

竹环填料生物滤器在两种海水鱼养殖废水处理中的运行效果及微生物群落分析

以点带石斑鱼(Epinephelus malabaricas)、半滑舌鳎(Cynoglossus semilaevis)养殖排放水为处理对象,在生产现场研究了竹环填料生物滤器处理高盐度、低氨氮负荷海水养殖废水的运行效果以及挂膜阶段和稳定运行阶段微生物群落变化规律。结果表明,点带石斑鱼养殖废水进水氨氮质量浓度为0.93～1.33 mg/L,氨氮去除率达到27%～39%,挂膜时间需45 d;半滑舌鳎养殖废水进水氨氮质量浓度为0.38～0.52 mg/L,氨氮去除率达到20%～30%,挂膜时间需65 d。另外,对生物滤器挂膜阶段和稳定运行阶段的氨氧化细菌数量和亚硝酸氧化细菌数量进行了统计,氨氧化细菌的数量在点带石斑鱼和半滑舌鳎养殖排放水处理系统中分别达到104～105 CFU/mL和103 CFU/mL,亚硝酸氧化细菌数量则分别达到104 CFU/mL和103 CFU/mL,并分析了温度、进水氨氮负荷、反硝化作用对半滑舌鳎养殖废水生物滤器亚硝酸盐积累现象的影响。     

渤海油田泡沫吞吐解堵技术研究与应用

稠油油藏由于储层胶结疏松,原油胶质、沥青质含量高,加上稠油中重质组分与细粉砂、泥质成分混在一起,往往在防砂管柱筛孔处形成堵塞,造成近井地带堵塞,影响了油井产能。常规的有机解堵或酸化增产措施很难解除这种复合堵塞,即使解堵后,效果也不理想。针对上述问题,提出了泡沫流体吞吐解堵技术,进行了室内实验和数值模拟计算。优选的高效清洗剂Po-Ca,在5%浓度时降黏率达到99.28%、对油砂的清洗效率达到94.6%,并通过在渤海油田一口稠油井首次成功应用后该井由停产井变为产量为28-30 m^3/d的高产井,取得了满意的效果。该技术为海洋稠油油藏低产低效井综合治理提供了一种新的技术手段,对渤海油田低产低效井的增产具有重要的意义。     

Dyeing and printing wastewater treatment using fly-ash coated with chitosan

Printing and dyeing industry is a considerable source of environmental contamination. In this study treatment of printing and dyeing wastewater with a new type of sewage treatment agent, fly-ash coated with chitosan particles (FCCP), was examined. The effects of pH, stirring time, sedimentation time and temperature on color, COD, turbidity and NH₃-N removal were determined. The optimum dosage of FCCP and the influence of individual factors on removal efficiency were tested. The optimum parameters determined using the L₁₆(4⁵) orthogonal experiment were as follows: FCCP (weight ratio of chitosan to fly-ash 1:6) dosage, 4 g·L⁻¹; temperature, 35°C; pH, 4. The stirring time and sedimentation time were 20 min and 5 h, respectively. Under these optimum conditions, the color, COD and NH₃-N removal ratios were 97%, 80% and 75%, respectively.