不同碳源强化地下水中生物脱氮模拟试验研究

地下水中NO3^-N污染是普遍存在的环境问题,生物脱氮作用是去除该污染的主要机制,而生物脱氮菌群和营养碳源又是这种作用进行的主要限制性因子,该文应用这一理论将人工接种驯化并优势培养制备的生物脱氮菌剂,分别与不同种类不同配入量比的营养碳源物质一起施用,进行系列污染水体的生物脱氮模拟试验研究,以确定用于治理地下水中NO3－N污染的微生物菌剂和促进生物脱氮作用的营养碳源种类及其最佳配入量比值,探索修复治理地下水中大面积NO3－N污染的方法。     

大口径瓦斯地质孔钻探技术

运用非平衡钻探工艺理论，对煤矿瓦斯地层进行大口径钻孔的钻探，使目标层富集的高压瓦斯经抽放后得到释压，确保煤矿安全生产。在针对小构造带形成的角砾岩、松散煤层、不稳定地层等瓦斯地质条件下，采用中压风作为冲洗介质进行钻探中所存在的问题，重新设计了新型的钻具级配、正反向一体化钻头等，并且对风介质的排渣机理进行了阐述和分析。同时，就实践中遇到的问题和解决方法进行了总结。     

Bromide removal and recovery with layered double hydroxides as an adsorbent

Grignard regents have been applied extensively in chemical industry, especially in pharmacy. A mass of bromide-containing wastewater was produced after reaction, and ozonation of these organic contaminants can produce bromate and other brominated pollutants. The US Environmental Protection Agency （EPA） has established a maximum contaminant level of 10 μg/L for bromate in finished water. Therefore, it is necessary and significant to remove the DBP （disinfection by-products） precursor - bromide. On the other hand, since the bromine is a valuable element, recovery of it from wastewater is significant. Bromide removal is important to control DBP （disinfection by-products） contaminant and an ion exchange process is one of several treatment processes for this purpose. Layered double hydroxides （LDHs） are useful as adsorbents for bromide removal because of theft ion exchange properties. In this study, the adsorption properties of LDHs for bromide and the method of regeneration of this material were examined. It has been found that the LDHs with Mg/Al molar ratio of 2 represented the highest capacity to remove bromide ion from aqueous solution at pH 6.0. The equilibrium isotherms of uptake of bromide by CLDH were well fitted by the Langmuir equation. Bromide adsorbed on the LDHs was effectively desorbed at 30% Na2CO3 solution and the LDHs were regenerated at the same time. The regenerated LDHs could be reused repeatedly for the bromide removal. Bromide in the exhausted desorption solution was recovered as bromine by oxidation using Cl2.     

Optimization strategies for sediment reduction practices on roads in steep,forested terrain

Many forested steeplands in the western United States display a legacy of disturbances due to timber harvest, mining or wildfires, for example. Such disturbances have caused accelerated hillslope erosion, leading to increased sedimentation in fish‐bearing streams. Several restoration techniques have been implemented to address these problems in mountain catchments, many of which involve the removal of abandoned roads and re‐establishing drainage networks across road prisms. With limited restoration funds to be applied across large catchments, land managers are faced with deciding which areas and problems should be treated first, and by which technique, in order to design the most effective and cost‐effective sediment reduction strategy. Currently most restoration is conducted on a site‐specific scale according to uniform treatment policies. To create catchment‐scale policies for restoration, we developed two optimization models – dynamic programming and genetic algorithms – to determine the most cost‐effective treatment level for roads and stream crossings in a pilot study basin with approximately 700 road segments and crossings. These models considered the trade‐offs between the cost and effectiveness of different restoration strategies to minimize the predicted erosion from all forest roads within a catchment, while meeting a specified budget constraint. The optimal sediment reduction strategies developed by these models performed much better than two strategies of uniform erosion control which are commonly applied to road erosion problems by land managers, with sediment savings increased by an additional 48 to 80 per cent. These optimization models can be used to formulate the most cost‐effective restoration policy for sediment reduction on a catchment scale. Thus, cost savings can be applied to further restoration work within the catchment. Nevertheless, the models are based on erosion rates measured on past restoration sites, and need to be updated as additional monitoring studies evaluate long‐term basin response to erosion control treatments. Copyright © 2006 John Wiley & Sons, Ltd.     

增厚大陆岩石层热边界层对流剥离的数值模拟

用数值模拟方法模拟了增厚大陆岩石层热边界层被对流地幔剥离并为软流层物质替代的动力学过程．结果表明,在初始温度分层分布、侧向均匀但存在微小热扰动的流场中,80km厚的增厚岩石层热边界层约需60Ma才能被完全剥离,剥离的速率微弱地依赖扰动的强度;在已建立好的流场中,同样厚度的增厚热边界层只需约10Ma就可被剥离．模拟结果暗示青藏高原地壳及岩石层在岩石层增厚和剥离以前就很热,其下伏地馒中可能已存在建立好的上地幔小尺度对流系统,而该尺度的对流系统很可能是由特提斯海洋岩石圈俯冲和消减诱发的     

Analysis of oil lens removal by extraction through a seepage face

Removal of LNAPL (oil) from an aquifer is described using a multiphase flow model. At the well boundary seepage face conditions are imposed. These conditions are implemented in a numerical model and withdrawal in a twodimensional domain is simulated for two different geometries of the oil lens and for varied values of the physical parameters. Assuming vertical equilibrium, the oil flow equation is reduced by vertical integration. The well boundary condition is approximated by imposing zero oil lens thickness. Similarity solutions of the reduced equations for the two geometries show good agreement with the numerical results in most cases.     

华北地区重力场变化与构造运动的关系

根据重力场和形变场观测结果及其年变化率,结合均衡异常（经典和现代的补偿模型）和地质构造及其演化历史,探索了该区的重力场和构造运动特征。研究结果表明：华北地区处于再活动阶段;岩石圈弹性厚度薄,以致地壳破裂严重;有一大的正均衡异常区（北京以南）,说明此处质量运移多,也正是地震发生多的地带。     

大气有机污染分析和评价：Ⅲ.美国迈阿密市大气有机污染监测与分析

自１９９４年６月至１９９５年３月对（美）迈阿密市大气颗粒物及干、湿沉降物中的多种有机化合物进行了定量分析与监测，并依据分析结果结合分子参数对有机污染水平的季节性变化、气候条件影响和清除机理等进行了探讨。     

Study of metal aerosol systems as a sink for atmospheric SO2

The chemical removal of SO₂ in the presence of different aerosol systems has been investigated in laboratory experiments using a dynamic flow reactor. The aerosols consisted of wetted particles containing one of the following substances: MnCl₂, Mn(NO₃)₂, MnSO₄, CuCl₂, Cu(NO₃)₂, CuSO₄, FeCl₃, NaCl. The SO₂ removal rate R was measured as a function of the SO₂ gas phase concentration (SO₂)_g, the spatial metal concentration C_Me, and the relative humidity rH in the reactor. A first-order dependence with regard to (SO₂)_g was observed for each type of aerosol. For the Mn(II) and Cu(II) aerosols R was found to be a non-linear function of C_Me except for MnSO₄ and Cu(NO₃)₂ particles. The removal rate showed a significant increase with the relative humidity particularly when rH was close to the deliquescence point of the wetted particles. Among the Mn(II) and Cu(II) aerosols investigated Mn(NO₃)₂ was found to be most efficient for the chemical removal of SO₂ at atmospheric background conditions, especially in haze and fog droplets. The results further indicate that the catalytic oxidation of S(IV) in such aerosol systems may be as efficient as its oxidation by H₂O₂ in cloud water.     

Wet removal of highly soluble gases

Partition, not kinetics, ultimately determines the concentration of highly soluble gases in cloud droplets. Partition equations are formulated and applied to idealized air-mass thunderclouds and precipitating stratus. Contribution to aqueous concentrations from sub-cloud scavenging of highly soluble gases is estimated at between 10 and 20% under relatively unpolluted conditions. Data indicate that evaporation can produce enhancements in concentration of as much as a factor of 3. The calculations give large-scale mean coefficients of wet removal of highly soluble gases of about 2.8×10^-6 s^-1 (4-day residence time) for air-mass thunderclouds and precipitating stratus. Removal is so effective that the mean scale heights of these gases should be decreased to 2 km or less. The criterion of high solubility in this paper is that K ^H (Henry's Law coefficient) > 10⁵ mol l^-1 atm^-1. Gases that are effectively highly soluble include HCl, HNO₃, H₂SO₄, H₂O₂, NH₃ in acid droplets, SO₂ in oxidizing droplets (and probably some light amines and sulfonic acids), but not SO₂ in the absence of oxidants, nor HCHO. A variation of removal coefficient and scale height with solubility is presented. A comparison of atmospheric NH₃ concentrations deduced from rain NH₄ ⁺ and measured directly gives reasonable agreement.