Possible chemical structures and biological precursors of different vitrinites in coal measure in Northwest China

Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state ¹³C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in ¹³C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in ¹³C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and ¹³C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.     

Room-temperature equation of state of Li<Subscript>2</Subscript>VOSiO<Subscript>4</Subscript> up to 8.5 GPa

High-pressure single-crystal X-ray diffraction measurements of lattice parameters of the compound Li₂VOSiO₄, which crystallises with a natisite-type structure, has been carried out to a pressure of 8.54(5) GPa at room temperature. Unit-cell volume data were fitted with a second-order Birch-Murnaghan EoS (BM-EoS), simultaneously refining V ₀ and K ₀ using the data weighted by the uncertainties in V. The bulk modulus is K ₀ = 99(1) GPa, with K′ fixed to 4. Refinements of third order equations-of-state yielded values of K′ that did not differ significantly from 4. The compressibility of the unit-cell is strongly anisotropic with the c axis (K ₀(c) = 49.7 ± 0.5 GPa) approximately four times more compressible than the a axis (K ₀(a) = 195 ± 3 GPa).     

Biaxial test simulations using a packing of polygonal particles

The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd.     

饱和粉砂不稳定性的试验研究

通过对净砂和级配良好粉砂(含10 %粉土)进行一系列三轴固结不排水试验（CU）,研究了粉土、孔隙比和围压对饱和粉砂不稳定性的影响。试验结果表明,净砂与粉砂在不排水剪切条件下均会出现应变软化现象（即不稳定性）。同一围压下脆性指数(IB)随孔隙比增加,但不稳定线的应力比随孔隙比增加而减小。引用等效粒间孔隙比(ege)后,净砂和粉砂在ege-ln p?平面上拥有基本相同的临界状态线。在临界状态理论及等效粒间孔隙比的基础上,提出在同一修正状态参数(?ge)下净砂和级配良好粉砂有相似的不稳定性。     

基于Mindlin理论Winkler地基参数的Kalman滤波识别

提出了Winkler地基参数的Kalman滤波识别方法。引入Mindlin理论后,推导了Winkler地基上板的控制微分方程。利用Fourier变换,推求了Winkler地基上简支板的Fourier闭式解。推导了Winkler地基参数的Kalman滤波方程,研究了Winkler地基参数的Kalman滤波识别的具体计算步骤。研究表明,运用Kalman滤波理论进行Winkler地基参数的识别,能有效地估计Winkler地基参数;Winkler地基参数的滤波收敛速度和精度受地基参数初始值选取和位移实测资料的影响,且Kalman滤波理论也可用于其他地基模型地基参数的识别。     

秦山核电站邻近水域的流况分析

本文分析了秦山核电站邻近水域各测站的实测流、潮流和佘流分布及季节变化。结果表明:测区内潮流为非正规丰日浅海潮流,其运动形式呈往复流。核电站二期工程取水口附近(L_1,18站)为一大流速区,而一期工程出水口周围(L_2,L_2′站)有一相对小的流速区。大流速区落潮流历时大于涨潮流历时,而相对小流速区则相反;大流速区的余流较小,而小流速区的余流大。在四个季节中,涨潮流速秋季最大,春季次之,夏季最小;落潮流速秋季最大,夏季次之,春季最小。余流冬、秋两季较大。在实测流中以潮流为主,径流和季风的作用也相当显著。     

多传感器观测下带乘性噪声系统的逆向滤波与反褶积融合算法

针对多传感器观测环境下带乘性噪声系统的逆向最优滤波与反褶积融合估计问题 ,本文提出了 1种基于极大似然准则的最优融合算法。该算法中各单传感器间并行计算 ,并且融合中心与单传感器处理中心间无反向通讯 ,因而执行效率较高。仿真表明 ,该融合算法产生的逆向滤波与反褶积比单传感器处理结果有较明显提高     

机载雷达高度计对海况及海面风速的测量研究

运用我国自行研制的ＺＨＧ－１型Ｘ波段机载雷达高度计于１９９５年４月１３日－４月１８日在青岛附近海域进行的海上飞行实验数据，及导出的均方根波高、有效波高、均方根波陡算法模型，得到了上述海况参数值。     

Waveform Shaping of Sonar Transducers for Improving the Vertical Resolution in Sub-bottom Sediments Profiling

Vertical resolution is of fundamental importance in sonar exploration and is directly related to the duration of the acoustic pulse generated by the transducer. The shorter the radiated pulse, the higher the vertical resolution. Many sub-bottom profiling sonar systems use piezoelectric transducers because they are reversible and well understood. Piezoelectric projectors are normally resonant transducers, which are intrinsically narrowband. A piezoelectric transducer is usually driven by a tone-burst. However, it is possible to use Fourier techniques to find a pre-compensated electrical driving function so that the transducer radiates a prescribed wider band acoustic waveform. This technique can be applied to synthesize zero-phase cosine-magnitude, Gaussian, and bionic pulses, with a conventional sandwich transducer. Zero-phase cosine-magnitude waveforms provide minimum length pulses (and therefore maximum resolution) within a prescribed frequency band.The aim of this paper is to illustrate the synthesis of wideband acoustic pulses using an underwater piezoelectric projector. The conventional acoustic waveform radiated when a Tonpiltz transducer is transiently excited using a “click” and allows its frequency response function to be measured. This function is used to design the electrical signal which then drives the transducer so that it radiates the shortest pulse compatible with its mechanical response. The significant resolution enhancement of the waveform shaping process is illustrated by its application to a sediment wedge model.     

珠江三角洲网河区水位变化趋势研究

根据珠江三角洲网河区29个验潮站的实测验潮记录,应用傅氏变换与最平滤波器串联的方法来消除月均序列的周期波动对确定水位变化趋势的影响,由低通序列一元线性回归分析确定各站水位的变化趋势;结果表明,周期波动对确定海平面变化趋势的影响是显著的.应用经验正交函数(EOF)对网河区的水位变化场进行分解,由相互独立的时间函数和空间特征函数表征网河区区域的水位变化特征;应用时间特征函数计算区域水位的平均变化率为0.02mm/a.根据验潮站的水位变化趋势,探讨网河区水位变化与河床冲淤的关系.