山东蓝宝石的呈色机制及改色试验

利用穆斯堡尔谱分析结果以及前人光谱分析等资料，从铁离子的价态入手，重新确立了山东蓝宝石的呈色机制，确定出致蓝因素与致黑因素。认为Fe^2 与Ti^4 对可见光565nm的吸收是使蓝宝石产生美丽蓝色调的原因，而Fe^3 对可见光442nm的吸收是使蓝宝石呈黑色的原因，并在此基础上进行了以消除Fe^3 、保障并增加Fe^2 和Ti^4 为宗旨的改色实验，取得了较好的效果。     

REMOTE SENSING OF THE SEASONAL VARIATION IN COLUMN ABUNDANCE OF ATMOSPHERIC CH4*

Infrared solar spectra on clear days were measured automatically by an infrared solar spectrometer(ISS) with 0.4 cm^-1 resolution developed by us.A line-by line(LBL) computation method was used to calculate theoretical atmospheric absorption.In the wavelength range of 3.410-3.438 μm.the absorption is mainly due to atmospheric methane and water vapor.Columnatmospheric methane was retrieved from the recorded infrared solar spectra.The seasonal variation of column atmospheric methane in Hefei has been obtained from the measuremental data of nearly 18 months since the April of 1997.and found that it is similar to that of background data.The instruments.principles of measurement and some of results were introduced,and the results are also discussed briefly in the paper.     

A study of design spectra based on attenuation relationship of ground motion

In recent years, more and more studies are focused on the performance in seismic design instead of the strength of structures. People have realized that the structure deformation (displacement) can describe the damage more properly and directly than the strength (force). The displacement design spectra need to be constructed within more wide range of the period and the damping for the displacement-based seismic design.     

Calculation of the UV Absorption Spectra of As(III) Oxo- and Thio- Acids and Anions in Aqueous Solution and of PF3 in the Gas-phase

Changes in the UV spectra of As(OH)₃ solutions with variations in pH and temperature have recently been used to determine the temperature dependence of the pK_a of the acid. In previous studies I used quantum mechanical techniques to study changes in structure and vibrational spectra as a function of pH for arsenites and thioarsenites. I previously calculated UV spectra for ``molecular' minerals, like realgar As₄S₄. Here I use a number of different quantum mechanical methods, both Hartree-Fock and density functional theory based, to calculate the UV spectra for both a related simple well-characterized gas-phase molecule PF₃ and for As(OH)₃ and As(SH)₃ and their conjugate anions and some neutral and anionic oligomers in aqueous solution. For the monomeric species small numbers of water molecules have been explicitly included, in a supermolecule or microsolvation approach. I find that UV absorption energies accurate to a few tenths of an eV can be obtained both for gas- phase PF₃ and for neutral arsenious acid in aqueous solution, for which the UV absorption maximum is calculated to occur around 6.5 eV, consistent with experiment. Accurate calculation of the UV energies for arsenite anions in aqueous solution is much more difficult, since basis set size and solvation effects are considerably larger than for the neutral molecules, but fairly reliable results can still be obtained. Deprotonation is found to reduce the lowest calculated UV transition energy by about half an eV. Oligomerization also reduces the lowest calculated UV energy by at least half an eV. Replacement of one or all the –OH groups by –SH groups reduces the lowest calculated UV energies by about 2 eV. UV excitation energies have been calculated for oligomeric species as large as As₃E₃(EH)₃ and As₄E₆, where E = O, S, and may be useful for identifying such species in solution.     

北京地区一次特大强风过程边界层结构的研究

利用北京325 m气象塔资料对1993年4月9日北京地区出现的一次特大强风过程的边界层结构（风、温、风切变及阵风特征）进行了分析。随着该次大风的过境，边界层内风场出现数个风速高值中心，高度位于200～300 m，时间间隔1～3 h。伴随上层风速垂直切变和阵风特性。湍流能谱的计算结果表明了大尺度涡旋对边界层湍流微结构的影响。     

太阳宇宙线高能电子能谱的形成

提出了一个太阳脉冲和经变耀斑中高能太阳宇宙线电子能谱的形成模型，探讨了高能电子通过日冕捕获区的库仑损失、轫致辐射和同步辐射等物理过程，首次研究了日冕等离子体尾场对太阳宇宙线电子的加速及其能谱的形成．所得结果和观测谱能很好地符合，从而较合理地阐明了脉冲耀斑和经变耀斑两类太阳宇宙线高能电子谱的结构．     

Collection and analysis of atmospheric ozone samples

Anomalies found in the isotope ratios of ozone are traceable to the ozone formation process. Metastable electronic states may be responsible for the preferred production of the heavy molecules. While laboratory isotope data and first tropospheric results agree well in the magnitude of isotope enrichments, stratospheric measurements show often higher values. Only through the collection of ozone samples can sufficiently large amounts of gas be obtained to analyze the three isotopes ⁴⁸O₃, ⁴⁹O₃, and ⁵⁰O₃. Collector systems have been developed and successfully operated in the troposphere and in the stratosphere. They will play in the future an important role in atmospheric oxygen isotope studies.     

植物在不同形态和不同状态下的荧光光谱特征研究

本文从光合作用的角度出发,讨论了植物叶片在不同形态、不同状态下的荧光光谱特征以及它们对荧光光谱的影响。文章涉及了以下几方面的内容:(1)植物在离体形态和活体形态下的荧光光谱特征;(2)叶片正面与反面的荧光光谱特征;(3)植物不同器官对荧光光谱的影响;(4)叶片放置时间对荧光光谱的影响;(5)叶片经不同处理时对荧光光谱的影响等。其目的是为激光荧光技术用于植被遥感的实施提供基础数据。     

A data collection and analysis system for research on rock fracturing

We have made a data collection and analysis system for recording microcracks in rock to study the three dimensional pattern of fracture and the dynamic properties of rock during pressurization. This system, with 8 channel data detection, records in real-time, from the initial microcracks to the final vibration waveform excited by the master fracture. The detected data are recorded digitally at the hard disk of an IBM computer (or 286, 386 personal computer) as well as transmitted to disk. The sampling rate for each channel is 10 MHz. Collecting every acoustic emission events in the loaded rock sample with 8 channels by this system, mathematically modelling the AE event travel time, and taking the coordinates of the AE event hypocenter and the three components of P wave velocity as unknown parameters, we set up a set of residual equations for joint inversion, so that the three dimensional localization of AE event hypocenters can be completed under variable velocities, which will lay foundations for the research on rock fracture clearly. The Chinese version of this paper appeared in the Chinese edition ofActa Seismological Sinica,13, 489–495, 1991. The design and development of the system, and the experiments are sponsored by the Chinese Joint Seismological Science Foundation.     

地气动态提取技术的研制及在寻找隐伏矿上的初步试验

地气探测技术是８０年代中期发展起来的寻找隐伏矿的化探新方法。这种方法有可能为当前和今后解决寻找厚层运积物覆盖区的隐伏矿所面临的难题提供一种强有力的手段。但由于其效率低、成本高、操作不方便限制了它的使用。为此，我们开发研制了一种快速动态提取地气技术。通过在某一隐伏矿上的试验，取得了令人满意的效果，并从理论上探讨了地气的迁移机制。为今后开展利用这一技术寻找厚层运积物覆盖区隐伏矿的工作创造了良好的开端。