13X沸石分子筛的比表面积和孔分布

对利用钾长石粉水热合成的13X沸石分子筛分别进行了比表面积和孔分布测定。结果表明:13X沸石分子筛比表面积约为621.50~747.40 m²/g,总孔体积约为0.344 70~0.393 70 cm³/g;具有高比例且孔径小于2.50 nm的微孔,中-小型实验样品(SXZ-10g和SXZ-1kg)的微孔体积比例相近,为81.33%~84.70%,而扩大实验样品(SXZ-10kg)的微孔体积比例为67.90%~67.98%。13X沸石分子筛微孔的含量是决定13X沸石分子筛具有高比表面积和高效吸附性能的前提。     

同轴双向回转钻进破岩效率研究

国内外相关研究均显示同轴双向回转可有效降低钻具振动和提高破岩效率,但双向回转相对传统单向回转的钻进效率的提升水平研究较少。据此,本文建立双向回转钻头以及单向回转钻头与岩石相互作用的有限元模型,以破岩比功作为评价指标量化比较分析了2种钻头的破岩效率。通过定义双向钻头内外壁尺寸差、内外钻头的间隙、内钻头壁厚与双向钻头内外壁尺寸差之比、内外钻头转速比和内外钻头底部高度差5种核心参数,并设计正交试验完成了仿真分析。结果显示,内外钻头高度差与内外钻头间隙对于破岩比功影响比较小,内外钻头尺寸差、内外钻头转速比和内钻头壁厚与双向钻头内外尺寸差之比对破岩比功影响显著。     

基于钻进状态监测的智能工况识别

钻进过程状态监测旨在实时描述钻进工况,判断运行性能优劣程度进行非优追溯,及时指导司钻人员调整作业操作,保证钻进过程安全、高效、稳定开展。钻进工况是钻进系统运行状态的反映,因此开展面向状态监测技术的钻进工况识别研究具有重要的理论和应用价值。本文针对钻进工况识别问题,基于状态监测数据,建立基于支持向量机的钻进工况识别模型,对钻进工况进行识别。综合工况识别结果,对钻进效率进行评估,并对影响钻进效率的因素进行讨论,寻找提升钻进效率的手段。最后,采用钻进现场实钻数据进行仿真实验,验证所提方法的可行性和有效性。     

陕南安康盆地膨胀土工程地质特性研究

安康盆地是我国典型膨胀土分布区。由于膨胀土的胀缩效应致使该地区工业与民用建筑、铁路、公路等工程建设造成严重危害。本文重点对安康盆地三种类型膨胀土的物质成分、微观结构和工程地质特性进行了研究,阐述了安康盆地膨胀土的地质灾害。     

黄河积石峡水库I号滑体变形趋势分析

通过对黄河积石峡水库库外Ｉ＃滑坡体变形趋势分析，认为该滑坡在地震及水雾影响下是稳定的，但稳定系数变动在＂１＂左右，从水工建筑物的安全角度来看是不符合要求的，需要进行治理。     

The status of the passive treatment systems for acid mine drainage in South Korea

This study was performed to investigate the operating status, evaluate the problems, and discuss possible improvement methods of passive treatment systems for acid mine drainage (AMD) in South Korea. Thirty-five passive treatment systems in 29 mines have been constructed from 1996 to 2002 using successive alkalinity producing systems (SAPS) as the main treatment process. We investigated 29 systems (two for metal mines), 19 of which revealed various problems. Overflows of drainage from SAPS, wetland, or oxidation ponds were caused by the flow rate exceeding the capacities of the facilities or by the reduced permeability of the organic substance layer. Leakages occurred at various parts of the systems. In some cases, clogged and broken pipes at the mouths of the mine adits made the whole system unusable. Some systems showed very low efficiencies without apparent leakage or overflow. Even though the systems showed fairly good efficiencies in metal removal ratios (mainly iron) and pH control; sulfate removal rates were very poor except in three systems, which may indicate very poor sulfate reductions with sulfate reducing bacteria (SRB) as a means.     

水化蒙脱石在浓电解质溶液中的特征及对溶液电导率的影响

经水化的蒙脱石,具有特殊的性能.本文通过经纯水水化的蒙脱石和未经纯水水化的蒙脱石,在浓Nil_4Cl溶液中的行为及对溶液电导率的影响,说明蒙脱石经纯水水化,在其表面形成较厚的水化膜,在浓NH_4Cl溶液中不易被NH_4~(+)离子“剥离”掉,表现出具有特殊的胶体性能.     

东北高空湿度变化特征及其与地面气温和降水的关系

利用1971~2005年探空和地面观测资料,详细分析了东北地区高空比湿和相对湿度的时空变化特征,并探讨了比湿和相对湿度与地面气温、降水量的关系。结果表明：东北地区比湿空间分布主要受到水汽来源的影响,地面由东南向西北递减,高空由南向北递减;相对湿度受水汽、海拔高度和纬度的共同影响,地面和对流层下层由南向北先减后增,对流层中层由南向北递增,赤峰向通辽延伸的西南-东北向干舌地面最明显,随高度增加逐渐减弱。1971~2005年,东北地区比湿从地面到高空均为增加趋势,对流层中下层的增加趋势更加显著;相对湿度在地面呈显著减小趋势,对流层中层呈显著增加趋势。大气比湿与地面气温在年、季尺度上存在一致的显著正相关关系,大气相对湿度与地面气温在季节尺度上存在显著负相关关系;对流层中下层相对湿度与降水量相关最显著;地面气温升高对东北气候趋于干旱化起了重要作用,高空相对湿度增加有利于降水增加,气温与比湿的相互消长,影响了气候的干、湿变化。     

The saturation of calcite and aragonite in the Arctic Ocean

We report on the chemical saturation of CaCO₃ in the waters of the Arctic Ocean calculated from total alkalinity (A_T) and total dissolved inorganic carbon (C_T). Data based on four different expeditions are presented: International Arctic Ocean Expedition (IAOE-91), Arctic Ocean Section 94 (AOS94), Polarstern Arctic '96 expedition (ACSYS 96), and Joint Ocean Ice Study 97 (JOIS 97). The results show a lysocline at around 3500 m for aragonite and that most of the Arctic Ocean sea floor lies above the lysocline for calcite. The only anomaly is the low degree of saturation at the shelf break depth in the Canadian Basin seen in the sections of the AOS94 and JOIS 97 cruises, correlated with nutrient maxima and very low O₂ concentration, suggesting decomposition of organic matter. The insignificant variability in degree of saturation between the deep waters of the different basins in the Arctic Ocean indicates a very low sedimentation/remineralisation of organic soft matter.     

温度和盐度对几种大型海藻生长率和NH4-N吸收的影响

温度和盐度对细基江蓠繁枝变型(Gracilaria tenuistipitata var.liui)、孔石莼(Ulva pertusa)和蜈蚣藻(Grateloupia filicina)生长率及细基江蓠繁枝变型NH₄-N吸收的影响进行了实验研究.结果表明,温度和盐度对上述3种海藻生长率及NH₄-N吸收均有显著影响.3种海藻的生长适宜温度和盐度范围分别为细基江蓠繁枝变型20～30℃,15～30,孔石莼15～25℃,15～40,蜈蚣藻20～25℃,25～35;最大日特定生长率(SGR)分别为8.66%,12.28%,2.24%;N饥饿细基江蓠繁枝变型对NH₄-N的吸收存在短期的快吸收.细基江蓠繁枝变型NH₄-N吸收的最适温度和盐度范围分别为15～25℃,10～25.生长率及NH₄-N吸收速率与温度和盐度之间分别存在以下关系:SGR_G.t.=0.873(S-5.487)(T-9.007)e(-0.0708S-0.0745T);SGR_U.p.=0.222(S-2.665)e-0.047S(T-9.98)e-0.00057(T-9.98)2.7;SGR_G.f.=2.6×10-4(S-10.856)(T-11.704)e0.156T-3.36×10-6STe0.219T;V_upt=11.812(S-4.081)(T-9.221)e-0.1S-0.148T.