Geochemistry of Subvolcanic-Type Copper-Silver Deposits in Eastern China

The metallogenesis of subvolcanic deposits is controlled by subvolcanic activities. The copper polymetallic deposits are genetically related to intermediate-acid rocks, and the silver polymetallic deposits are more closely related to acid rocks. The abundance of Cu is relatively high in the intermediate-acid rocks and subvolcanic rocks, whereas the abundances of Pb, An and Ag are high in acid rocks, indicating rich ore-forming elements in original magmas. The study of REEs shows that the magmatic type related to copper deposits is the syntectic type, and that related to silver polymetallic deposits is mainly the re-melting type. The deposits were formed under medium-low temperatures and low salinity. The metallogenic times were the late stage of the early Yanshanian or the late Yanshanian, dating 78-147 Ma.     

华峰尖火山通道地球物理场地球化学异常特征及其与成矿作用的关系

治岭头金银矿及杨梅岗铅锌矿、治岭头黄铁矿均生成在华峰尖火山通道的边缘断裂带内。研究火山构造不但对找矿和成矿预测有重要意义,而且对研究矿床的生成时代、成因类型也有重要意义。治岭头金银矿虽然生成在陈蔡群变质岩的糜棱岩带内,许多研究者认为是变质热液矿床。从矿体的产出部位与火山通道的关系看：应为火山热液矿床,生成时代应为燕山早期。     

草鱼、鲤鱼肠道、肝胰脏消化酶活性的初步研究

用两种不同蛋白质和糖类水平的饲料喂养草鱼、鲤鱼夏花及一龄鱼种，通过对两种鱼肝胰脏及肠道的消化酶活性测定发现，在一定温度条件下，随着水温升高，两种鱼肠道及肝胰脏的蛋白酶和淀粉酶比活均升高；鱼类摄食后六小时酶比活明显大于摄食后二十四小时的酶比活，在水温２５℃条件下，用两种不同饲料分别饲养草鱼、鲤鱼六周后发现：随着饲料蛋白质水平的提高，草鱼、鲤鱼肝胰脏中蛋白酶比活明显升高鲤，而总肠变化不显著；随饲料中糖量水平的提高，草鱼肝胰脏及肠道的淀粉酶比活明显升高，而鲤鱼差异不显著．草鱼，鲤鱼肠道蛋白酶比活以后肠最高，中肠次之，前肠最小。而肠道淀粉酶比活性却随饲料成分而发生差异。两种鱼肝胰脏消化酶活性均为一龄鱼种大于夏花阶段，这与组织切片的观察结果相符。     

异育银鲫气单胞菌病原菌鉴定和药敏试验

从患病异育银鲫体内分离到5株可疑菌株,经API 20NE细菌生化鉴定,YCS07-03和YZ07-11株鉴定率为99.2%和99.3%。注射感染中5×108 CFU.mL-1剂量组表现出较强的致病性,12 d死亡率100%。菌株在营养肉汤培养液中呈均匀混浊状;在营养琼脂平皿中呈灰白色半透明菌落;在血琼脂培养基中呈光滑灰白色菌落,YZ07-11株出现透明的β溶血环;在TCBS培养基呈黄色菌落;在SS和麦康凯培养基中形成无色透明的扁平菌落。经负染电镜观察,菌株两端圆,呈直杆状,无芽孢,极生单鞭毛,菌株大小(短径×长径)分别为1.53μm×2.71μm和0.80μm×2.12μm。菌株经生化实验鉴定为温和气单胞菌(Aeromonas sobria)和嗜水气单胞菌(Aeromonas hydrophila)。试验结果表明:菌株对丁胺卡那霉素、头孢噻肟、庆大霉素、左氟沙星、复合磺胺、氟嗪酸、洛美沙星、复方新诺明、链霉素和新霉素均产生高度敏感;对万古霉素为中度敏感;氨苄青霉素、羧苄青霉素、强力霉素和青霉素产生耐药。     

Determination of Trace Silver in Polymetallic Ore Samples by Flame Atomic Absorption Spectrometry after Solid‐Phase Extraction Using a Microcolumn Comprising Eggshell Membrane

A rapid and inexpensive method was developed for the determination of trace silver in polymetallic ore samples by use of eggshell membrane (ESM), a natural biomaterial, as the solid‐phase extraction (SPE) adsorbent coupled with flame atomic absorption spectrometry (FAAS). The ESM was used for the separation/pre‐concentration of silver, and the parameters affecting sensitivity, such as pH, sample flow rate, eluent volume and eluent flow rate, were carefully investigated. ESM was found to be an effective solid phase extractant for the adsorption of trace silver over a wide range of acidity from 0.02 to 0.50 mol l^?1 HNO₃. The sample solution in 0.4 mol l^?1 HNO₃ was pumped through an ESM microcolumn at the rate of 1.0 ml min^?1. Silver was absorbed, and then eluted with a solution of 1.0% m/v thiourea–0.5% v/v HCl. Under these optimal conditions, ESM exhibited a good enrichment efficiency for silver with a dynamic adsorption capacity of 1.7 mg g^?1. The proposed method was applied to the FAAS determination of trace silver in polymetallic ores and geological reference materials, GSO‐2, 3 and 5, and GSD‐11, GSD‐12, and the determined values were in good agreement with certified values.     

河南桐柏县破山银矿和银洞坡金矿的硫同位素研究

河南桐柏县围山城金银成矿带的破山银矿和银洞坡金矿位于河前庄背斜的轴部和两翼,围岩为歪头山岩组,矿体受地层和构造的双重控制。两个矿床的矿石硫同位素δ34S值变化范围很窄,位于-1.8‰～5.3‰之间,具塔式效应,与围岩的硫同位素组成类似,具有深源硫的特征,由混合总体筛分可推测围岩提供了大部分硫源,破山银矿δ34S∑S为2.8‰左右。同时赋矿围岩的Au、Ag含量远远高于地壳丰度,因此可推断成矿物质主要来源于围岩歪头山岩组。     

西藏谢通门展咱木部异常区铅锌找矿前景

从区域地质、水系沉积物测量、土壤测量和高精度磁测等方面对西藏展咱木部地区的铅锌找矿前景做初步分析。出露地层主要为第三系始新统年波组的晶屑凝灰岩及安山玢岩,区内出露岩体主要为始新世花岗岩及小面积的花岗斑岩。利用1∶5万水系沉积物测量编制异常图,发现区内Pb、Zn、Ag、Au、Sb、Cu、Ba、Hg、Sn、As等元素有不同规模的明显异常,且Pb、Zn异常规模较大。通过土壤剖面可以看出Pb、Zn异常更显著。高精度磁测结果显示,化探异常位于磁异常附近。磁异常的定性分析对这些金属矿的深部找矿预测可以提供有利证据。磁异常显示该区是热液成矿的有利部位。通过研究元素间组合关系发现,Pb、Zn与Ag、As、Sb、Cu的关系密切,结合化探异常和地质特征,推断区内可能存在与火山岩有关的铅锌多金属矿床类型。研究表明研究区内寻找与火山岩有关的铅锌（银）多金属矿有较好的找矿前景。     

用双硫腙－泡沫塑料反相色层萃取原子吸收法测定废水中的微量银

本文研究了双硫腙负载的聚氨酯泡沫塑料对水溶液中银离子的反相色层萃取行为，试验了Ｐｈ，流速、洗脱液及洗脱方法的影响。回收率试验表明，该法能定量捕集废水中银离子，结果令人满意。     

CMF模式的排他性依据和造山型银矿实例：东秦岭铁炉坪银矿同位素地球化学

河南熊耳山区的铁炉坪银矿定位于高级变质基底中的NE向断裂带中,是熊耳山脉状造山型金、银、铅锌矿床的重要组成部分。成矿作用包括了早、中、晚3个阶段,分别形成石英-黄铁矿,多金属硫化物和碳酸盐脉3类矿物组合。早阶段成 矿温度大约为373℃左右,成矿流体δD=-90‰,δ~(13)C_(co_2)=2.0‰,δ~(18)O=9‰,来源较深;晚阶段流体温度<203℃,δD=70‰,δ~(13)C_(co_2)=-1.3‰,δ~(18)O=-2‰,属于浅源大气降水热液;中阶段流体均一温度210～249℃,δD=-109‰,δ~(13)C_(co_2)=0.1‰,δ~(18)O=2‰,是深源与浅源流体的混合。对比讨论表明,熊耳山区的早前寒武纪变质基底、熊耳群火山岩和燕山期花岗岩类的三者之一或它们的混合物,均无法提供具有早阶段流体D-O-c同位素组成(高δ~(18)O和δ~(13)C,低δD)的成矿流体,表明早阶段流体来自栾川群和管道口群的碳酸盐-页岩-硅质岩建造的变质脱水作用。矿石硫同位素组成较低,铅同位素比值较高,同样不可能来自熊耳山的主要地质体,更不可能来自其下伏的地幔和下地壳,指示成矿物质和流体应主要来自栾川群和管道口群。尽管栾川群和管道口群地层的同位素地球化学研究尚待补充,铁炉坪银矿的同位素地球化学特征似乎只能借助碰撞造山成岩成矿与流体作用模式才能合理解释。即华南与华     

催化对降水区域外效应的中尺度数值模拟

The Fifth-Generation NCAR/Penn State Mesoscale Model (MM5) has been used to investigate the extra-area effects of silver iodide (AgI) seeding on stratiform clouds performed at the supercooled layer.A bulk two-moment microphysical scheme and the new software package for silver iodide are incorporated in MM5.Extra conservation equations are applied to trace the seeding agent,which is transported along the flow field and interacts with the supercooled cloud fields.In this study,the model was run using three nested grids,with 3.3 km × 3.3 km horizontal resolution in the finest grid.The model results showed that seeding with AgI at the 5 to 15℃ levels had microphysical effects on the simulated clouds and that the simulation produced a longer-lasting seeding effect because of the transport of the seeding agent by upper-level winds.Most of the AgI particles acted as deposition nuclei,and the deposition nucleation process contributed mostly to additional cloud ice formation in this study.The results showed that more precipitation results from seeded than unseeded case,and the precipitation was redistributed downwind of the target.Augmented precipitation (varying from 5% to 25% downwind) was confined in space to within 250 km of the seeding target and in time to the 3-h period after initial seeding.