纳米碳管分离提纯技术

较详细地介绍了当前国内外纳米碳管分离提纯的最新技术 ,并分别对各种可能具有应用价值的分离方法进行了评述。在综合分析目前国际上研究纳米碳管两大类截然不同的分离技术———化学提纯法和物理提纯法———的基础上 ,提出这方面研究应该综合利用物理分离和化学分离方法 ,达到既能得到高纯度纳米碳管 ,又能减少对纳米碳管的结构破坏的最终目的。最后 ,对各国的纳米碳管分离研究现状进行了进一步的讨论。     

Purification, characterization and ELISA of metallothionein from red scorponifish, Sebastiscus marmoratus

INTRODUCTIONATislowKWCys-rich(aboutonethird)metal-bindingprotein,lackofaromaticaminoacidresidues.AThasbeenfoundinkidneysandliversofmanymammals,andalsoininvertebrates,microorganismsandplants.ThepresenceofanAT-likeproteinhasbeenfoundinanumberofaquaticorganisms,includingtheplaice(Overnelletal.,1977),rock-fish(Olafsonetal.,1974),goldfish(Marafant,1976),andcrabandshrimp(Olafsonetal.,1979).AThasbecomethesubjectofgreatInterestinrecentyearsduetotheirwideexistenceandmetalaffinity.Scientistsha…     

硅肥对水稻镉吸收影响初探

试验表明：用炼铁水淬渣为主要原料生产的硅肥,能够抑制水稻对镉吸收。在本试验条件下,施硅肥后糙米镉含量相对下降９２％以上,稻草镉含量下降９４％。随着硅肥施用量的增加,抑制作用有增强的趋势,作者认为在镉污染不太严重的地区,施用硅肥可以防止重金属污染。     

养殖水体营养状态及自净能力的分析

本文根据１９９７年２～１２月间对对虾 养殖水全的监测结果,应用营养指数法进行养殖水体的营养水平评价,结合自养指数对水体的自净能力进行分析。结果表明,养殖水体内具有较高的ＤＩＰ和ＣＯＤ是造成水体富营养化的主要因素。较高的Ｃｈｌ－ａ含量则是富营养化水体的表现。养殖池内水质状况同养殖周期和季节变更密切相关。养殖水体浮游值物和微生物的代谢偶联,是反映水体自净能力,保持水体稳定的基础。     

Research on purification and modification of I/S bentonite

Analyzing raw material's structure and performance of bentonite from Panzhihua in Sichuan, the authors think that it is adequate for agglomerant of iron smelting. According to its composition and property we have researched the purification and modification of I/S bentonite under conditions of different dispersants and sodium agent. XRD test result reveals that the essential minerals of Panzhihua bentonite are I/S mixed-layer ones, and FTIR analysis shows that when adding 1 5% sodium pyrophosphate to the bentonite slurry during purification, the composition of quartz in bentonite decreases to less than 4% and I/S is more than 90%. The optimized modification technic conditions are Na2CO3 (4%) and CMC-Na (3%) as modified agents, the clay and water are 10 vs. 1, and the temperature is 75℃. It is 40 min for stirring time and reacting time is 4 h. Under the conditions we can get the modified I/S bentonite with colloid index more than 500 ml/15 g.     

Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.     

由膨润土提铝残渣直接合成五配位体有机硅化合物

研究了以膨润土提铝残渣为原料，采用低温加热法直接合成有机硅化合物新方法。由实验确定了最佳的合成条件。用红外光谱法和X射线衍射法分析了合成产物的结构。结果表明，当以碱金属氢氧化物为介质时，合成的产物为五配位体有机硅化合物；在最佳合成条件下，钠盐和锂盐的收率分别为63．0％和44．9％。     

漂浮植物修复技术净化城市河湖水体试验研究

阐述了漂浮栽培植物修复系统的技术原理、特点与系统组成, 研究了在该系统中种植美人 蕉和旱伞草2 种植物的生长状况以及这些植物对城市河湖水体中氮、磷等的净化效果。尝试了将 漂浮栽培植物与生物接触氧化技术结合起来, 并研究了植物与生物填料的组合系统对水质的改 善效果。结果表明, 美人蕉和风车草在漂浮植物修复系统对氨氮的去除率均在90%以上, 漂浮栽 培植物与软性填料的组合系统对水中COD_Mn 的去除率达46%以上。     

两株南极枝孢霉属真菌Cladosporium sp.NJF4和NJF6的次级代谢产物研究

南极因其独特的自然环境成为潜在、重要的微生物资源库,是产生新型生物活性物质和先导化合物菌株的潜在种源地,南极微生物正在成为创新药物研究新的重要资源。虽然近年来对南极微生物次级代谢产物的研究逐渐增加,但与温带和热带微生物研究相比仍处于初级阶段。对从南极普里兹湾海洋沉积物中获得的两株枝孢霉属真菌Cladosporium sp. NJF4和NJF6进行次级代谢产物分离及结构鉴定,获得20个化合物。化合物结构类型包括甾醇(1)、倍半萜类(7—8)、生物碱类(9—14)、二酮哌嗪(2—5、15—17)、芳香酸(6、18—19)等,其中倍半萜类(7—8)为首次从枝孢霉属真菌中分离得到,以上研究将为丰富南极微生物次级代谢产物库奠定一定的研究基础。     

荣成大疃刘家铍矿矿物赋存状态

大疃刘家铍矿铍元素主要以羟硅铍石单矿物赋存在矿石中。以羟硅铍石单矿物存在的BeO占79．45％;少部分分散在其他矿物中,以赤铁矿、褐铁矿中 BeO 含量较高,其次是绢云母、重晶石等。BeO 呈分散状态占20．55％,主要集中在绢云母中,这是由于矿石中绢云母含量高所致,分散状态的BeO无法回收。根据矿石中有用矿物和脉石矿物组合,矿石类型为羟硅铍石绢云母碳酸盐岩长石石英型铍矿石。