Dissociation of the benzene molecule by ultraviolet and soft X-rays in circumstellar environment

Benzene molecules, present in the proto-planetary nebula CRL 618, are ionized and dissociated by ultraviolet (UV) and X-ray photons originated from the hot central star and by its fast wind. Ionic species and free radicals produced by these processes can lead to the formation of new organic molecules. The aim of this work is to study the photoionization and photodissociation processes of the benzene molecule, using synchrotron radiation and time-of-flight mass spectrometry. Mass spectra were recorded at different energies corresponding to the vacuum UV (21.21 eV) and soft X-ray (282–310 eV) spectral regions. The production of ions from the benzene dissociative photoionization is here quantified, indicating that C₆H₆ is more efficiently fragmented by soft X-ray than UV radiation, where 50 per cent of the ionized benzene molecules survive to UV dissociation while only about 4 per cent resist to X-rays. Partial ion yields of H⁺ and small hydrocarbons, such as  C₂H⁺₂, C₃H⁺₃, C₄H⁺₂  , are determined as a function of photon energy. Absolute photoionization and dissociative photoionization cross-sections have also been determined. From these values, half-life of benzene molecule due to UV and X-ray photon fluxes in CRL 618 was obtained.     

Formation of H2 on an olivine surface: a computational study

The formation of H₂ on a pristine olivine surface [forsterite (010)] is investigated computationally. Calculations show that the forsterite surface catalyzes H₂ formation by providing chemisorption sites for H atoms. The chemisorption route allows for stepwise release of the reaction exothermicity and stronger coupling to the surface, which increases the efficiency of energy dissipation. This suggests that H₂ formed on a pristine olivine surface should be much less rovibrationally excited than H₂ formed on a graphite surface. Gas-phase H atoms impinging on the surface will first physisorb relatively strongly  ( E _phys= 1240 K)  . The H atom can then migrate via desorption and re-adsorption, with a barrier equal to the adsorption energy. The barrier for a physisorbed H atom to become chemisorbed is equal to the physisorption energy, therefore there is almost no gas-phase barrier to chemisorption. An impinging gas-phase H atom can easily chemisorb  ( E _chem= 12 200 K)  , creating a defect where a silicate O atom is protonated and a single electron resides on the surface above the adjacent magnesium ion. This defect directs any subsequent impinging H atoms to chemisorb strongly (39 800 K) on the surface electron site. The two adjacent chemisorbed atoms can subsequently recombine to form H₂ via a barrier (5610 K) that is lower than the chemisorption energy of the second H atom. Alternatively, the adsorbed surface species can react with another incoming H atom to yield H₂ and regenerate the surface electron site. This double chemisorption 'relay mechanism' catalyzes H₂ formation on the olivine surface and is expected to attenuate the rovibrational excitation of H₂ thus formed.     

Distribution of the Molecular Gas Around SN 1572

The early-stage structure and evolution of a supernova remnant (SNR) depends largely on its ambient interstellar medium, so the interstellar medium becomes the valid probe for investigating the evolution of SNRs. We have observed the ¹²CO (J = 1 − 0) line emission around the remnant of SN 1572 with the 13.7m millimeter-wave telescope at the Qinghai Station of PMO, in order to investigate the distribution of the CO molecular gas around SN 1572 and provide some observational basis for studying the relationship of SN 1572 with its ambient molecular gas and the evolution of this SNR. The observed result indicates that the molecular gas in the velocity range of V_LSR = −69∼ −58 km/s is associated with SN 1572, and this velocity component comes from a large-scale molecular cloud. The molecular gas is distributed along the periphery of the radio shell, continually but not uniformly, and forms a semi-closed molecular shell around the SNR. The enhanced emission exists in its whole eastern half, especially the CO emission is strongest on the northeastern edge. At the emission peak position, the spectral line exhibits a broadened velocity feature (>5 km/s). Combining with available observations in the optical, infrared, X-ray and other wavebands, it is demonstrated that the fast shock wave and ejecta are expanding into the molecular gas on the northeastern edge, and interacting with the dense gas. This interaction will have an important influence on the future evolution of SN 1572.     

Three-dimensional simulations of molecular cloud fragmentation regulated by magnetic fields and ambipolar diffusion

We employ the first fully three-dimensional simulation to study the role of magnetic fields and ion–neutral friction in regulating gravitationally driven fragmentation of molecular clouds. The cores in an initially subcritical cloud develop gradually over an ambipolar diffusion time while the cores in an initially supercritical cloud develop in a dynamical time. The infalling speeds on to cores are subsonic in the case of an initially subcritical cloud, while an extended (≳0.1 pc) region of supersonic infall exists in the case of an initially supercritical cloud. These results are consistent with previous two-dimensional simulations. We also found that a snapshot of the relation between density (ρ) and the strength of the magnetic field ( B ) at different spatial points of the cloud coincides with the evolutionary track of an individual core. When the density becomes large, both the relations tend to   B ∝ρ^0.5  .     

A comprehensive search for extragalactic 6.7-GHz methanol masers

We have used the Australia Telescope Compact Array (ATCA) to search for 6.7-GHz methanol maser emission towards 87 galaxies. We chose the target sources using several criteria, including far-IR luminosities and the presence of known OH megamasers. In addition, we searched for methanol masers in the nearby starburst galaxy NGC 253, making a full spectral-line synthesis image. No emission was detected in any of the galaxies, with detection limits ranging from 25 to 75 mJy. This is surprising, given the close association of OH and methanol masers in Galactic star formation regions, and significantly constrains models of OH megamaser emission. This absence of maser emission may be a result of low methanol abundances in molecular clouds in starburst galaxies.     

The high-velocity molecular stream in W51B: a ring structure with compact H ii regions

We present ¹³ CO J  = 1 − 0 line observations of the H  ii region complex W51B located in the high-velocity (HV) stream. These observations reveal a filamentary and clumpy structure in the molecular gas. The mean local standard of rest (LSR) velocity ∼ + 65 km s⁻¹ of the molecular gas in this region is greater than the maximum velocities allowed by kinematic Galactic rotation curves. The size and mass of the molecular clouds are ∼ 48 × 17 pc² and ∼ 2.4 × 10⁵ M⊙ respectively. In a position–velocity diagram, molecular gas in the southern part comprises a redshifted ring structure with v _LSR=+ 60 to +73 km s⁻¹. The velocity gradient of this ring is ∼ 0.5 km s⁻¹ pc⁻¹, and the mass is ∼ 6.2 × 10⁴ M⊙. If we assume that the ring is expanding with a uniform velocity, the expansion velocity, radius and kinetic energy are ∼ 7 km s⁻¹, ∼ 13 pc and ∼ 3.0 × 10 ⁴⁹ erg respectively. The kinetic energy and mass spectrum of the ring could be explained by an expanding cylindrical cloud with a centrally condensed mass distribution. The locations of two compact H  ii regions, G49.0−0.3 and G48.9−0.3, coincide with the two molecular clumps in this ring. We discuss star formation, and the mechanism that produced the ring structure.     

The 10-μm profile of molecular-cloud and diffuse ISM silicate dust

High signal-to-noise ratio spectra are presented of the 10-μm silicate absorption feature in lines of sight towards Elias 16 and 18 in the Taurus dark cloud, and towards the heavily reddened supergiant Cyg OB2 no. 12. The observations are fitted with laboratory and astronomical spectra to produce intrinsic absorption profiles. These features, which represent molecular-cloud and diffuse ISM dust respectively, are better fitted with emissivity spectra of the Trapezium and μ Cephei than they are with those of laboratory, terrestrial, or other observations of circumstellar silicates. The difference in width between the silicate band in the two environments can be almost entirely ascribed to a broad excess absorption in the long-wavelength wing of the profiles, which is much stronger in the molecular-cloud lines of sight, and possibly reflects grain growth in the denser environment. Limits are placed on the strength of fine spectral structure; if there is a crystalline silicate component in these spectra, it is most likely to be serpentine. Column-density upper limits for methanol and the photolysis product hexamethylenetetramine (HMT) are less than a few per cent of those of water ice and silicates.