where k (M− 2 s− 1) can be determined from the
in the pH range 2 to 5, from 5 to 40 °C and 0.01 to 1 M.The effect of pH and ionic strength on the reaction suggest that the rates are due to
where H2A = H2CrO4, HA = HCrO4, H2B = H2SO3 and HB = HSO3. The overall rate expression over the investigated pH range can be determined from
k=kH2A–H2B(αH2A)(αH2B)2+kHA–H2B(αHA)(αH2B)2+kH2A–HB(αH2A)(αHB)2
with kH2A−H2B = 5.0 × 107, kHA–H2B = 1.5 × 106 and kH2A–HB = 6.7 × 107.Fe(III) in the range 1.5 to 20 μM exerts a small catalytic effect on the reaction and significantly lowers the initial concentration of Cr(VI) compared to the nominal value. Contrary to Fe(III), formaldehyde (20 to 200 μM) reacts with S(IV) to form the hydroxymethanesulfonate adduct (CH2OHSO3), which does not react with Cr(VI). Major cations Mg2+ and some minor elements such as Ba2+ and Cu2+ did not affect the rates. The application of this rate law to environmental conditions suggest that this reaction may have a role in acidic solutions (aerosols and fog droplets). This reaction becomes more important in the presence of high Fe(III) and low HMS concentrations, contributing to affect the atmospheric transport of chromium species and the distribution of redox species of chromium, which reach surface water from atmospheric depositions.  相似文献   
74.
基于大数据的生活圈范围与服务设施空间匹配研究——以北京为例   总被引:3,自引:2,他引:1  
赵鹏军  罗佳  胡昊宇 《地理科学进展》2021,40(4):541-553
生活圈建设是新时代国土空间规划的关键内容之一,生活圈内服务设施配置是做好生活圈规划的首要基础,居民生活圈与服务设施的空间匹配关系也是地理学“人地关系”在城市社区尺度的重要体现.学术界对生活圈与服务设施的匹配关系已有研究,但主要采用问卷调查数据,该类数据存在样本量少、地域覆盖范围小等不足.论文将采用手机信令数据和POI(...  相似文献   
75.
关于南海北部滨海断裂带的研究   总被引:6,自引:1,他引:5  
徐杰  张进  周本刚  陈国光 《华南地震》2006,26(4):8-13
南海北部的滨海断裂带是位于南澳岛之东粤东南滨海地区的一条北东东走向的构造带。由于其所处的构造位置而一直被地球科学工作者所关注,并从不同角度作了不少研究。在广泛收集有关断裂带的资料和研究成果的基础上,对前人关于断裂带存在的依据、断裂带发育的时代、断裂带的构造属性和第四纪活动情况的认识作了简要归纳,并就断裂带的分布、构造属性等作了初步分析。  相似文献   
76.
Clinoform growth and sediment flux into late Cenozoic Qiongdongnan shelf margin,South China Sea     
Si Chen  Ronald Steel  Hua Wang  Rui Zhao  Cornel Olariu 《Basin Research》2020,32(2):302-319
The South China Sea continental margin in the Qiongdongnan Basin (QDNB) area has incrementally prograded since 10.5 Ma generating a margin sediment prism more than 4km-thick and 150–200 km wide above the well-dated T40 stratigraphic surface. Core and well log data, as well as clinoform morphology and growth patterns along 28 2D seismic reflection lines, illustrate the evolving architecture and margin morphology; through five main seismic-stratigraphic surfaces (T40, T30, T27, T20 and T0) frame 15 clinothems in the southwest that reduce over some 200 km to 8 clinoforms in the northeast. The overall margin geometry shows a remarkable change from sigmoidal, strongly progradational and aggradational in the west to weakly progradational in the east. Vertical sediment accumulation rate increased significantly across the entire margin after 2.4 Ma, with a marked increase in mud content in the succession. Furthermore, an estimate of sediment flux across successive clinoforms on each of the three selected seismic cross sections indicate an overall decrease in sediment discharge west to east, away from the Red River depocenter, as well as a decrease in the percentage of total discharge crossing the shelf break in this same direction. The QDNB Late Cenozoic continental margin growth, with its overall increased sediment flux, responded to the climate-induced, gradual cooling and falling global sea level during this icehouse period.  相似文献   
77.
社区生活圈的新时间地理学研究框架   总被引:5,自引:5,他引:0  
柴彦威  李春江  张艳 《地理科学进展》2020,39(12):1961-1971
社区生活圈从居民日常活动及行为视角考察城市社区,是城市地理学和城市相关学科的研究前沿,也是中国国土空间规划体系创新的重要组成部分,以及中国城市社会可持续发展的重要抓手。伴随着流动性和信息化的不断深入,社区生活圈的主体日益多元化、社区活动和居民时空行为日益多样化、社区空间的功能与意义日益丰富化,亟需城市地理学的研究创新与实践引导。时间地理学是理解人与环境关系的社会—技术—生态综合方法,为早期基于时空行为与生活空间的社区生活圈研究提供了重要基础。新时间地理学重视家庭及其他组织企划的交互与时空组合,可为社区生活圈内个体—家庭—社区之间的复杂互动关系研究、时空行为的社会文化制约与多情境分析及模拟提供重要支撑。论文基于新时间地理学方法,从理论、方法和实证3个维度提出社区生活圈的新时间地理学研究框架,具体包括构建社区生活圈的时空行为理论,揭示社区生活圈的时空间结构;创新社区生活圈的时空行为分析和模拟方法;从社区生活圈时空行为优化、社区交往生活圈、社区安全生活圈等方面创新中国城市规划与管理等研究内容。  相似文献   
78.
Analysis of Safe Span Length and Fatigue Life of Submarine Pipelines     
HE Zhang-feng  WEI Yuan  LIU Shu-lin 《中国海洋工程》2020,(1):119-130
Owing to the complex environmental conditions, suspension could induce complicated forces on submarine pipelines and even cause vortex-induced vibration, resulting in fatigue damage of pipelines. Through aiming at the 28-inch submarine pipeline in the East China Sea, the pipeline was segmented according to the similarity, considering the factors of pipe assembly, typhoon, current, wave and seabed topography. The effects of span length on natural frequency in each section of submarine pipeline were analyzed by finite element model. The maximum safe span length allowed by each pipeline section was verified by fatigue cumulative damage theory, and the fatigue life of each pipeline section were predicted. The results showed that each order natural frequency of the pipeline decreased with the increase of span length. The calculated results of empirical formulas were much smaller than those of the FEM analysis. The increase of the gap between the suspended pipeline and the seabed was beneficial to enhance the fatigue life of the suspended pipeline.  相似文献   
79.
城市公共服务设施与人口是否匹配?——基于社区生活圈的评估   总被引:1,自引:0,他引:1  
常飞  王录仓  马玥  严翠霞  刘海洋 《地理科学进展》2021,40(4):607-619
公共服务设施是城市社会服务最基本的承载体,公共服务设施分配的公平与否,事关城市健康发展和社会公正运行.目前由于城市微观尺度人口数据的缺失,鲜有研究将供给侧(公共服务设施)与需求侧(人口)统一起来.鉴于此,论文以互联网地图API为支撑,建立了5min、10 min、15min三个层级的社区生活圈,并模拟了高分辨率、高精度...  相似文献   
80.
Clinoform architecture and along‐strike facies variability through an exhumed erosional to accretionary basin margin transition     
Miquel Poyatos‐Mor  George D. Jones  Rufus L. Brunt  Daniel E. Tek  David M. Hodgson  Stephen S. Flint 《Basin Research》2019,31(5):920-947
Exhumed basin margin‐scale clinothems provide important archives for understanding process interactions and reconstructing the physiography of sedimentary basins. However, studies of coeval shelf through slope to basin‐floor deposits are rarely documented, mainly due to outcrop or subsurface dataset limitations. Unit G from the Laingsburg depocentre (Karoo Basin, South Africa) is a rare example of a complete basin margin scale clinothem (>60 km long, 200 m‐high), with >10 km of depositional strike control, which allows a quasi‐3D study of a preserved shelf‐slope‐basin floor transition over a ca. 1,200 km2 area. Sand‐prone, wave‐influenced topset deposits close to the shelf‐edge rollover zone can be physically mapped down dip for ca. 10 km as they thicken and transition into heterolithic foreset/slope deposits. These deposits progressively fine and thin over tens of km farther down dip into sand‐starved bottomset/basin‐floor deposits. Only a few km along strike, the coeval foreset/slope deposits are bypass‐dominated with incisional features interpreted as minor slope conduits/gullies. The margin here is steeper, more channelized and records a stepped profile with evidence of sand‐filled intraslope topography, a preserved base‐of‐slope transition zone and sand‐rich bottomset/basin‐floor deposits. Unit G is interpreted as part of a composite depositional sequence that records a change in basin margin style from an underlying incised slope with large sand‐rich basin‐floor fans to an overlying accretion‐dominated shelf with limited sand supply to the slope and basin floor. The change in margin style is accompanied with decreased clinoform height/slope and increased shelf width. This is interpreted to reflect a transition in subsidence style from regional sag, driven by dynamic topography/inherited basement configuration, to early foreland basin flexural loading. Results of this study caution against reconstructing basin margin successions from partial datasets without accounting for temporal and spatial physiographic changes, with potential implications on predictive basin evolution models.  相似文献   
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71.
李春  沈立娜 《探矿工程》2018,45(2):56-60
为提高“松科二井”在深井硬岩钻进中的寿命与效率,选用了高性能胎体材料、高强度焊接材料,并采用了合理的钻头结构与水路结构设计,研制的φ216/124 mm金刚石取心钻头在“松科二井”取得了良好的效果,本文介绍了适用于深井硬岩的金刚石钻头的设计及应用效果。  相似文献   
72.
《Sedimentology》2018,65(3):809-841
Degradation of basin‐margin clinothems around the shelf‐edge rollover zone may lead to the generation of conduits through which gravity flows transport sediment downslope. Many studies from seismic‐reflection data sets show these features, but they lack small‐scale (centimetre to metre) sedimentary and stratigraphic observations on process interactions. Exhumed basin‐margin clinothems in the Tanqua depocentre (Karoo Basin) provide seismic‐reflection‐scale geometries and internal details of architecture with depositional dip and strike control. At the Geelhoek locality, clinothem parasequences comprise siltstone‐rich offshore deposits overlain by heterolithic prodelta facies and sandstone‐dominated deformed mouth bars. Three of these parasequences are truncated by a steep (6 to 22°), 100 m deep and 1·5 km wide asymmetrical composite erosion surface that delineates a shelf‐incised canyon. The fill, from base to top comprises: (i) thick‐bedded sandstone with intrabasinal clasts and multiple erosion surfaces; (ii) scour‐based interbedded sandstone and siltstone with tractional structures; and (iii) inverse‐graded to normal‐graded siltstone beds. An overlying 55 m thick coarsening‐upward parasequence fills the upper section of the canyon and extends across its interfluves. Younger parasequences display progressively shallower gradients during progradation and healing of the local accommodation. The incision surface resulted from initial oversteepening and high sediment supply triggering deformation and collapse at the shelf edge, enhanced by a relative sea‐level fall that did not result in subaerial exposure of the shelf edge. Previous work identified an underlying highly incised, sandstone‐rich shelf‐edge rollover zone across‐margin strike, suggesting that there was migration in the zone of shelf edge to upper‐slope incision over time. This study provides an unusual example of clinothem degradation and readjustment with three‐dimensional control in an exhumed basin‐margin succession. The work demonstrates that large‐scale erosion surfaces can develop and migrate due to a combination of factors at the shelf‐edge rollover zone and proposes additional criteria to predict clinothem incision and differential sediment bypass in consistently progradational systems.  相似文献   
73.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2
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