烟台、威海南部近岸海域物理自净能力研究——Ⅱ.拉格朗日余流模型

在该海域潮流计算的基础上,利用有限元法建立了二维的拉格朗日余流模型,得出了威海及烟台南部海域的拉格朗日余流分布。跟踪了文登、乳山、海阳、莱阳近岸主要排污口的污水输运轨迹,为沿岸县市污水排放的选址提供理论依据。     

Ecotoxicological evaluation of sewage sludge using bioluminescent marine bacteria and rotifer

Bioassay using the marine bacteria,Vibrio fischeri and rotifer,Brachionus plicatilis, and chemical analyses were conducted to assess the toxicity of the various sewage sludges, one of the major ocean dumped materials in the Yellow Sea of Korea. Sludge elutriates extracted by filtered seawater were used to estimate the ecotoxicity of the sludge. Chemical characterization included the analyses of organic contents, heavy metals, and persistent organic pollutants in sludge. Bacterial bioluminescent inhibition (15 min), rotifer mortality (24 hr) and rotifer population growth inhibition (48 hr) assay were conducted to estimate the sludge toxicity. EC50 15 min (inhibition concentration of bioluminescence after 15 minutes exposed) values by Microtox® bioassay clearly revealed different toxicity levels depending on the sludge sources. Highest toxicity for the bacteria was found with the sludge extract from dyeing waste and followed by industrial waste, livestock waste, and leather processing waste. Clear toxic effects on the bacteria were not found in the sludge extract from filtration bed sludge and rural sewage sludge. Consistent with Microtox® results, rotifer neonate mortality and population growth inhibition test also showed highest toxicity in dyeing waste and low in filtration bed and rural sewage sludge. High concentrations of persistent organic pollutants (POPs) and heavy metals were measured in the samples from the industrial wastes, leather processing plant waste sludge, and urban sewage sludge. However, there was no significant correlation between pollutant concentration levels and the toxicity values of the sludge. This suggests that the ecotoxicity in addition to the chemical analyses of various sludge samples must be estimated before release of potential harmful waste in the natural environment as part of an ecological risk assessment.     

麦饭石促进异养反硝化去除水中硝酸盐的研究

微生物异养反硝化技术是市政污水处理中广泛应用的技术,但在实际应用中,微生物活性易受冲击负荷、重金属胁迫等环境条件影响,使出水效果不稳定。麦饭石作为一种天然硅酸盐矿物,能有效提高微生物活性及对环境胁迫的抗性,可以将其应用于微生物污染治理领域。通过批实验研究麦饭石的剂量、处理方式对异养反硝化的促进作用并探究麦饭石作用于微生物的机理。结果表明,麦饭石的投加剂量和处理方式均显著影响了微生物对硝酸盐的去除效果。硝酸盐去除率与麦饭石投加量呈正相关,麦饭石投加量为350 g/L时硝酸盐去除率可达96%,未添加麦饭石的空白组硝酸盐去除率仅为25%;处理方式会影响麦饭石对反硝化过程的强化作用,研磨后过200目筛的麦饭石在投加量<150 g/L时具有优势,投加量继续增大后,未经处理的麦饭石表现出更强的反硝化促进作用。进一步采用未经处理的麦饭石、研磨后过200目筛麦饭石及球磨麦饭石浸出液进行反硝化的促进实验及微生物毒性实验探究麦饭石作用于微生物的机理。实验结果表明,麦饭石浸出液能够提高微生物的活性及对环境胁迫的抗性,影响麦饭石生物促进作用的主要因素为其溶出微量元素的成分及浓度。本研究为天然矿物麦饭石应用于微生物污染治理提供理论依据和实际应用价值。     

北京市杨镇一中人工湿地设计及污水处理效果

针对北京市农村地区居民居住相对分散、生活污水集中处理难度大的状况,在北京市杨镇一中,建立了经济且简便易行的用于处理污水的人工湿地。该人工湿地由地埋式一体化预处理、多级复合式人工湿地系统、景观湿地系统三部分组成。通过单元实验,对人工湿地的填料结构、植物选择、布水设计、水位调节、湿地防堵系统设计、预处理系统设计进行了创新,研究了1d、2d和3d水力停留时间对污水中有机物处理效应的影响,并开展了人工湿地基质堵塞实验、冬季保温措施研究以及人工湿地脱氮除磷效果研究。结果表明,比较而言,1d和3d的水力停留时间不利于有机物的去除,2d的水力停留时间有利于有机物的去除;人工湿地0～10m的水平距离内,0～5cm、30～35cm、60～65cm深度的基质的堵塞差异显著(n=10,p<0.05),从水平上看,在0m、2m、4m处基质的堵塞最为明显,因此,在更换人工湿地基质时,只需更换0～4m内的基质;棚膜+蒲席覆盖系统去除污水中总氮的效果要优于结冰盖系统,更适宜于北方使用;预处理系统、人工湿地系统、景观湿地系统三部分共同处理污水,优势互补,能使处理后的出水符合北京市水污染排放标准一级B限值。     

聚甲醛污水处理技术总结

作者阐述了聚甲醛污水的水质特点,提出了聚甲醛污水工程的设计要点,介绍了两个聚甲醛污水工程实例,并对已实施的工程进行了总结。     

盐度对废水生物处理的影响

研究了废水中不同含盐量对生化处理效果以及生物学变化规律的影响。在废水含盐量低于22g／L时,废水生化处理系统对COD的去除率可稳定在70％左右,污泥活性良好;随着进水盐浓度的增加,含盐量达到22g／L时,污泥活性开始受到抑制,COD去除率急剧下降到50％左右;当废水含盐量达到31g／L时,污泥活性明显受到抑制,污泥絮体开始部分解体,COD去除率下降到40％左右。     

Exploitation of gold in an historic sewage sludge stockpile, Werribee, Australia: resource evaluation, chemical extraction and subsequent utilisation sludge

Sewage sludges are potential targets for economic extraction of Au because of the documented Au content of sewage sludges worldwide, which are of the order of some ore deposits currently mined for Au. The sewage of Melbourne, Australia, was stockpiled in large, closed, lagoonal tanks from 1898 until 1980. Reeves, Plimer and Foster, 1999, have conducted, and published, an extensive and exhaustive study of the Werribee sewage reserves utilising RNAA, INAA, GFAAS, ICPMS, and FLAAS to determine 31 elements, including Au, Ag, Sb, As, Cd, Hg, Zn, Cu, and Pb. The study was initiated to determine Au, Ag and other metal variations in both space and time and to investigate the economics of chemical extraction of the precious metals. A total of 149 samples from over 50 hand-auger drillholes to a depth up to 4m were analysed from the stockpiles, with Au assays yielding remarkably consistent results. Average grades of 0.77 g/t Au and 18.8 g/t Ag have been documented for a measured resource of 770,000 m³. Laboratory-based extractive metallurgy of the Werribee sludges has demonstrated that Au, Ag, and Zn can be removed with relative ease by heap-leaching using modified conventional technology, albeit with prohibitive reagent consumption. The extraction of the precious metals also results in the variable removal of contaminant metals such as Cd, As, Sb, Hg and Cr which may render the sludges fit for sale as agricultural fertiliser, provided organic pollutants and pathogenic organisms are below governmental environmental protection limits.     

Relationship of chemical fractions of heavy metals with microbial and enzyme activities in sludge and ash-amended acid lateritic soil from India

The influence of metals, Cd, Cr, Cu, Ni, Pb and Zn, on the microbial biomass and enzyme activities of an amended acid lateritic soil were investigated under field conditions receiving a one-time application of 52 t ha^–1 of sludge, coal ash and their mixtures at 1:3, 1:1 and 3:1 proportions, and including control and chemical fertilizer treatment at crop-specific recommended doses. Paddies and peanuts were grown in the experimental plots and soil was sampled twice after 6 months and 1 year after amendment application. The heavy metals in the soil were fractionated using sequential extraction and the increments in their concentrations in amended soil with respect to the control were determined. Concentrations of Cd, Ni and Zn were determined to have increased in their mobile fractions and were more pronounced in soil collected during the second sampling, which was associated with a decrease in soil organic carbon. The size of the microbial biomass carbon and the soil enzyme activities increased with the addition of an amendment and was highest at equal proportions of coal ash and sludge. Further increase in the proportion of sludge resulted in a significant decrease in biomass carbon. Simple correlation revealed significant and strong negative relations of mobile fractions of Cd and Ni with the ratio between microbial biomass C and organic carbon in soil, while the organic carbon content and the pH were positively correlated. The microbial activities were determined to be sensitive to the concentrations of some heavy metals in mobile fractions and therefore indicated possibilities of being useful as indicators for evaluation of toxic effects of sludge-borne metals on soil organisms.