碳酸盐岩岩溶作用的元素地球化学表征--以塔河1号的S60井为例

通过对塔河地区奥陶系碳酸盐岩及其胶结物方解石的化学成分及方解石晶体微形貌研究后认为 :塔河一号S6 0井埋深 5 433.2 0～ 5 435m发育的岩溶角砾灰岩,属于高度大于 2m的大型古岩溶洞穴沉积;而埋深 5 435m中晶洞中的方解石是地表岩溶带的早中期的淡水与海水的混合带的产物。在本文中,作者指出碳酸盐岩矿物学及地球化学可有效地应用于表生岩溶作用中的深度、强度、期次以及成岩序列及古沉积环境判别等项研究中。     

遗传算法在边坡数值计算中的应用

改进了进化方向的遗传算法与有限元数值法，结合并研制了相应的软件。应用该软件对多类型岩土边坡进行弹性模量、内聚力、内摩擦角等参数反演分析，显示误差很小，收敛速度也很快，这说明改进进化方向遗传算法这种新型的优化算法在多类型岩土参数优化估计中具有独特的优势。     

湘中锑(金)矿床成矿物质来源——Ⅰ.微量元素及其实验地球化学证据

为了查明湘中盆地中-低温梯（金）矿床的成矿物质来源，文章应用高分辨率ICP-MS、ICP-AES等方法对岩石与矿石进行了系统测定，并结合作者以往分析数据和实验地球化学结果，对该区盆地及周边基底地层与矿床中的微量元素分布特征及其水/岩反应效应进行了综合分析和系统研究。结果表明：Sb、Au等成矿元素在元古界基底碎屑岩中具有高的背景含量，在近似成矿条件下的水/岩反应实验中，成矿元素的淋出率达20%～90%，元古界基底碎屑岩中的金（锑、钨）矿床的周围蚀变围岩中出现明显的金负异常区。而盆地内泥盆系统地层中的高锑含量仅局限于锑矿床（化）及其蚀变围岩中；湘中锑（金）矿床中的矿石与基底碎屑岩具有相似的稀土元素球粒陨石标准化配分曲线特征，以上微量元素地球化学特征充分证明该区锑（金）矿床锑、金等成矿物质主要来源于元古界底碎屑岩。     

Numerical Analysis of Space–Time Finite Element Formulations for Miscible Displacements

A finite element formulation is proposed to approximate a nonlinear system of partial differential equations, composed by an elliptic subsystem for the pressure–velocity and a transport equation (convection–diffusion) for the concentration, which models the incompressible miscible displacement of one fluid by another in a rigid porous media. The pressure is approximated by the classical Galerkin method and the velocity is calculated by a post-processing technique. Then, the concentration is obtained by a Galerkin/least-squares space–time (GLS/ST) finite element method. A numerical analysis is developed for the concentration approximation. Then, stability, convergence and numerical results are presented confirming the a priori error estimates.     

GEOCHEMICAL EFFECTS OF MAJOR ELEMENTS DURING FLUID-ROCKS INTERACTION IN MARINWOBO FAULT IN THE SOUTH MARGIN AREAS OF ALTAI MOUNTAINS

There are four types of metamorphic rocks in the Marinwobo fault, i. e, cataclasite, mylonite,mictosite and migmatitic granite, and the formation of these rocks is due to the progressive metamorphism of the pyroclastics. The fluids play a very important role in the metamorphic process of these rocks in the Marinwobo fault, the most important feature is that the fluids not only result in the migration of the major elements of the deformation rocks, but also result in the volume loss of the deformation rocks in the deformation process. Thus the migration laws of the major elements in different stages of the progressive metamorphic process are discussed according to mass balance equations. Finally, the quantitative analysis of the mass loss and volume loss of the different rocks the in Marinwobo fault is discussed in this paper.     

Trace Element Analysis of NIST SRM 614 and 616 Glass Reference Materials by Laser Ablation Microprobe-Inductively Coupled Plasma-Mass Spectrometry

Fifty elements in NIST SRM 614 and 616 glass reference materials were determined by laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS). The values determined for NIST SRM 614 agreed well with the NIST-certified and information values (mean relative difference ± 3.6%), except for B, Sc and Sb. The values determined for NIST SRM 616 agreed with the NIST-certified and information values within a mean relative difference of ± 1.5%, except for B, Sc and Ga. In addition, at an 80 μm sampling scale, NIST SRM 614 and 616 glass discs were homogeneous for trace elements within the observed precisions of 5 and 15% (mean), respectively. Detection limits were in the range 0.01 - 0.3 μg g⁻¹ for elements of lower mass numbers (amu < 80) and 1 - 10 ng g⁻¹ for heavy elements (amu > 80). Detection at the sub ng g⁻¹ level is possible for most of the heavy elements by using an ablation pit size larger than 10 0 μm.     

Recycling in the Puerto Rican mantle wedge, Greater Antilles Island Arc

Abstract The initial volcanic phase of Cretaceous island arc strata in central Puerto Rico, at the eastern end of the extinct Greater Antilles Arc, comprises a 6‐km thick pile of lava and volcanic breccia (Río Majada Group). Preserved within the sequence is a conspicuous shift in absolute abundances of the more incompatible elements, including Th, Nb, and the light rare earth elements (LREE: La, Ce, Pr and Nd). The compositional shift is marked by a decrease in La/Sm from averages of 2.11 in the lowest third of the pile (Formation A) to 1.48 at the top (Formation C), and by a distinctive flattening of LREE segments of chondrite‐normalized REE patterns. i⁸⁷Sr/⁸⁶Sr and ?_Nd average about 0.7035 and 8.2, respectively, in early Formation A basalts. These ranges normally overlap samples from later Formations B and C. Isotope compositions of the latter group are more variable, however, and several samples are considerably more radiogenic than Formation A basalts, such that i⁸⁷Sr/⁸⁶Sr averages almost 0.7042 while ?_Nd‐values decrease to 7.5 in Formation B and C basalts. Theoretical models of non‐modal melting processes in both amphibole peridotite and spinel lherzolite sources provide insight into the origin of depleted Th, Nb, and LREE abundances in Puerto Rican basalts. Low Nb concentrations less than normal mid‐oceanic ridge basalts in Formation A basalts indicate the wedge was slightly depleted by low‐volume decompression fusion due to induced convection in the back‐arc region prior to entry of the source into the arc melting zone. However, depleted patterns in Formation C basalts cannot be generated by relatively greater degrees of decompression fusion in the back‐arc, because addition of the La‐enriched slab‐derived component to more depleted source material invariably produces elevated rather than decreased La/Sm. Refluxing of Formation A harzburgitic residua is similarly precluded. In contrast, the observed patterns are readily reproduced by multistage melting models involving hybridized sources containing normal Formation A lherzolite source material blended with recycled, unrefluxed harzburgite residua. Successful models require hybrid sources containing large volumes of recycled harzburgite (up to 50%) during generation of Formation C basalts. Slightly elevated radiometric Sr and Nd isotopes in a few flows from Formation C are attributed to partial refluxing of the hybrid sources within the wedge.     

Effective stress analyses of liquefaction-induced deformation in river dikes

A series of effective stress analyses is carried out on the seismic performance of river dikes based on the case histories during the 1993 Hokkaido-Nansei-oki and 1995 Hyogoken-Nambu earthquakes in Japan. Seven case histories selected for the analyses involve a crest settlement ranging from none to 2.7 m in the dikes 3–6 m high with evidence of liquefaction at foundation soil. The effective stress model used is based on a multiple shear mechanism and was developed by one of the authors. The soil parameters are evaluated based on the site investigation and laboratory test results. The results of the analyses are basically consistent with the observed performance of the river dikes. In particular, the effective stress model shows a reasonable capability to reproduce the varying degree of settlements depending on the geotechnical conditions of foundation soils beneath the dikes. The analyses also indicate that the effect of a cohesive soil layer mixed with the liquefiable sand layers beneath the dikes can be a primary factor for reducing the liquefaction-induced deformation of dikes.     

Seismic analysis of base-isolated liquid storage tanks using the BE–FE–BE coupling technique

A three-dimensional soil–structure–liquid interaction problem is numerically simulated in order to analyze the dynamic behavior of a base-isolated liquid storage tank subjected to seismic ground motion. A dynamic analysis of a liquid storage tank is carried out using a hybrid formulation, which combines the finite shell elements for structures and the boundary elements for liquid and soil. The system is composed of three parts: the liquid–structure interaction part, the soil–foundation interaction part, and the base-isolation part. In the liquid–structure interaction part, the tank structure is modeled using the finite elements and the liquid is modeled using the internal boundary elements, which satisfy the free surface boundary condition. In the soil–foundation interaction part, the foundation is modeled using the finite elements and the half-space soil media are modeled using the external boundary elements, which satisfy the radiation condition in the infinite domain. Finally, above two parts are connected with the base-isolation system to solve the system's behavior. Numerical examples are presented to demonstrate the accuracy of the developed method, and an earthquake response analysis is carried out to demonstrate the applicability of the developed technique. The properties of a real LNG tank located in the west coast of Korea are used. The effects of the ground and the base-isolation system on the behavior of the tank are analyzed.     

钢筋砼摩擦耗能支撑框架结构的单元刚度和力学模型分析

为研究钢筋砼摩擦耗能支撑框架结构的动力反应性能 ,对其中的摩擦耗能器单元和框架杆单元的单元刚度和力学模型做了分析。钢筋砼摩擦耗能支撑单元由支撑杆单元和钢板—橡胶摩擦耗能器单元组成 ,支撑单元可取空间杆单元 ,摩擦耗能器单元为平面应力矩形单元。摩擦耗能器单元的剪切恢复力曲线为理想的弹塑性曲线 ,根据耗能器单元的力学模型 ,可确定其在每一时刻的刚度 ;框架结构空间杆单元的恢复力模型采用双线型模型 ,根据杆单元的力学模型 ,可确定其在每一时刻的刚度。并利用所编制的程序对十层单榀两跨空间普通框架和摩擦耗能支撑框架在地震作用下进行了弹塑性反应时程分析 ,结果表明耗能支撑框架的顶层最大位移明显小于普通框架