悬浮液进样氢化物发生原子荧光法测定海洋沉积物样品中痕量砷

人类对砷的认识已有很长的历史,近几十年来关于砷对环境的污染以及对人体健康的影响日益受到人们的关注.砷是海洋沉积物中常见的主要环境污染元素之一,目前测定它的常用方法有砷钼酸-结晶紫分光光度法[1]、氢化物-原子吸收分光光度法[1]、催化极谱法[1]、氢化物-原子荧光光谱法[2],但是这些方法需将样品制备成溶液,处理过程冗长,易引起操作沾污和待测成分损失,而且试剂消耗量大,同时产生的酸气对操作人员的身体健康非常有害,为此分析工作者一直在寻求一些新的前处理技术.     

1950～2000年黄河入海水沙的逐日变化及其影响因素

对 195 0～ 2 0 0 0年的 5 1年黄河经利津水文站入海的逐日水沙实测资料进行统计分析 ,展示了黄河入海水沙的极端情况 ,如洪峰和沙峰等逐渐变少到消失的过程及逐日入海水沙量的变化规律 ,并对其影响因素进行了初步分析。结果显示 :在黄河年均入海水沙锐减的背景下 ,2 0世纪 90年代日均流量 <5 0 0m3 /s的天数增加到了是 2 0世纪 5 0年代的 3倍多 ;>2 0 0 0m3 /s的洪季流量由初期频发至 1997年消失 ;>40 0 0m3 /s的洪峰流量自 1989年以后消失 ;>60 0 0m3 /s的洪峰流量从 1986年就不再发生。 >5 0 0t/s的日均输沙率 (4 3 .2× 10 6t/d的沙峰 )都出现在 1989年以前 ;>70 0t/s的日均输沙率 (60 .5× 10 6t/d的沙峰 )出现在 1977年以前 ;含沙量 >80kg/m3 的历时和可能产生异重流的含沙量天数都逐步减少。进入 2 0世纪 90年代以来基本不存在大洪灾及由沙峰造成的河口河道快速堆积而使河流改道现象 ,引起这些变化的因素除降雨外主要为流域耗水量不断增加及大中型水库的建成运用等 ,黄河入海水沙的这种锐减及水沙峰的极端情况都会对河口演变和河口区的生态环境产生重要的影响。     

南海北部底层沉积物捕获器中海雪和生物粪粒组成及来源探究

Sediment traps are an important tool for studying the source, composition and sedimentation processes of sinking particulate matter in the ocean. An in situ observational mooring(TJ-A-1) is located in the northern South China Sea(20.05°N, 117.42°E) at a water depth of 2 100 m and equipped with two sediment traps deployed at 500 m and 1 950 m. Samples were collected at 18-day intervals, and 20 samples were obtained at both depths from May 2014 to May 2015. Large amounts of fecal matter and marine snow were collected in the lower trap. The fluxes of marine snow and fecal pellets exhibited a fluctuating decrease between May 2014 and early August 2014 and then stabilized at a relatively low level. Scanning electron microscopy observations revealed that the main components of the marine snow and fecal pellets were diatoms, coccolithophores, radiolarians, and other debris, all of which are planktons mostly produced in photic zone. Used in conjunction with the particle collection range estimates from the lower trap and data on ocean surface chlorophyll, these marine snow and fecal pellets were related to the lateral transport of deep water and not vertical migrations from overlying water column. Moreover, the source area might be southwest of Taiwan.     

莺歌海盆地莺东斜坡带隐蔽油气藏类型及成藏主控因素

莺东斜坡带具有“两脊一洼”分段式展布之特殊区域地质构造格局,且自北而南“两脊一洼”三段式分布具有明显不同的构造及断裂活动特征与油气运聚规律,故不同区域区带隐蔽油气藏类型及成藏主控因素差异明显,其中,北段(即北延伸脊)成藏主控因素主要取决于烃源及油气运聚输导系统;中段(一洼即岭头断阶区)成藏主控因素则受控于烃源与岩性圈闭的有效性;南段(南延伸脊)成藏主控因素主要取决于地层岩性复合圈闭的有效性。根据不同类型隐蔽油气藏的成藏主控因素及分布规律,即可采取不同的研究方法及勘探技术对策,以期获得油气勘探的突破。     

潮致泥沙全沙净输运解析模式

泥沙运动作为水流和底床相互作用的纽带,是河流、河口及海岸工程研究的重要内容。在潮波作用明显的河口、海岸地区,周期性的动力作用下的泥沙运动具有往复和可逆的特征,因此研究这类水域的泥沙的净输运更具有实际的意义。基于泥沙输运和流速呈指数关系假设,建立潮流环境下的泥沙全沙净输运的解析解公式,并对该公式的计算结果和数值计算以及数学模型的结果进行了检验和验证,结果表明本研究提出的公式能较好地反应潮流环境下的泥沙净输运。由此,基于本公式采用潮流分潮调和常数可计算得到全沙净输运,并可以分析各分潮流及其相互作用与泥沙净输运的关系。研究结果显示,在受径流影响较大的半日潮河口,S2、MS4、M2三潮相互作用对全沙净输运的贡献显著高于通常的潮流不对称作用,即M2、M4的相互作用。此外,河口区域径流导致的余流对泥沙净输运的贡献不可忽略,特别是在洪季,大径流量条件下往往导致余流较大,其对泥沙净输运的贡献所占比例较大。     

Recent sediment transport and accumulation on the NW Iberian margin

Five transects across the NW Iberian margin were studied in the framework of the EU-funded Ocean Margin EXchange II (OMEX II) project, to determine and establish recent sediment and organic carbon transport and accumulation processes and fluxes.On the Galician shelf and shelf edge, resuspension of sediments resulting in well-developed bottom nepheloid layers was observed at all stations, but transport of suspended sediment appears largely confined to the shelf. On the continental slope, only very dilute bottom nepheloid layers were present, and intermediate nepheloid layers were only occasionally seen. This suggests that cross-slope transfer of particles is limited by the prevailing northerly directed shelf and slope currents.Optical backscatter and ADCP current measurements by the BOBO lander, deployed at 2152 m depth on the Galician slope, indicated that particles in the bottom boundary layer were kept in suspension by tidal currents with highest speeds between 15–25 cm s⁻¹. Net currents during the recording period August 6th–September 10th 1998, were initially directed along-slope toward the NNW, but later turned off-slope toward the SW.The separation of the water masses on the slope from the sediment-laden shelf water by the along-slope current regime is reflected in the recent sedimentary deposits of the Galician shelf and slope. Apart from compositional differences, shelf deposits differ from those on the slope by their higher flux of excess ²¹⁰Pb (0.57–5.37 dpm cm⁻²y⁻¹ versus 0.11–3.00 dpm cm⁻²y⁻¹), a much higher sediment accumulation rate (315.6–2295.9 g m⁻²y⁻¹ versus 10.9–124.7 g m⁻²y⁻¹) and organic carbon burial rate (1.01–34.30 g m⁻²y⁻¹ versus 0.01–0.69 g m⁻²y⁻¹).In contrast to the observations on the Galician margin, pronounced nepheloid layers occurred in the Nazaré Canyon, which extended to considerably greater water depths. This indicates that significantly greater transport of fine-grained particles in both the INL and the BNL was occurring within the canyon, as reflected in the exceptionally high ²¹⁰Pb excess flux (up to 34.09 dpm cm⁻²y⁻¹), mass accumulation rates (maximum 9623.1 g m⁻²y⁻¹) and carbon burial fluxes (up to 180.91 g m⁻²y⁻¹) in the sediment. However, radioisotope fluxes in the lower canyon were only slightly higher than at comparable depths on the Galician margin. This suggests that transport and rapid accumulation is focused on the upper and middle part of the canyon, from where it is episodically released to the deep sea. Compared to the Galician margin, the Nazaré Canyon may be considered as an important organic carbon depocenter on short time-scales, and a major conduit for particulate matter transport to the deep sea on >100 y time-scales.     

滩海油田泥沙运移控制初步方案及试验研究

为了降低成本,维持滩海油田的开敞式开发,提出了滩海油田泥沙运移控制初步方案,并进行了物模试验验证。该方案充分利用自然力,通过人工干预促使防护区外泥沙起动,借助海上潮流使高含沙海水流经防护区,实现岸滩蚀退的快速防护,对滩海油田的防护具有指导意义。     

泉州湾泥沙运移特征的初步研究

泉州湾属于潮流、径流和波浪综合作用下的山地海湾,根据两次(1994年6月和2001年12月)水文泥沙实测资料,分析泉州湾悬浮泥沙和沉积物分布特征,研究其沉积物来源,并探讨北水道的沉积速率。悬浮泥沙含量自河口(湾顶)-湾口-外海逐渐降低。高值区出现在水道和河口,冬季高于夏季,大、中潮高于小潮。泉州湾沉积物分布与水动力强弱环境呈很好的对应关系。晋江携带入海的泥沙是研究区的主要物源：海岸侵蚀来沙与湾外来沙也提供了部分物源。南、北水道分别属于落潮槽与涨潮槽两种不同性质的水道。北水道沉积物较细,以沉积作用为主,其入口处淤积程度较轻,而在上游淤积程度相对较重;南水道流速较大,沉积物较粗,是泥沙输运主要通道,地形变化不明显。     

黄海沉积物标准物质研制

报道了中国黄海海洋标准物质的研制过程,其中包括样品的采集、制备,均匀性检验、稳定性考察以及定值分析方法,并对数据进行了数理统计,给出了标准物质的定值数据。最后确定标准值45个,参考值8个,信息值11个,共计测定元素64个。     

The intertidal erosion rate of cohesive sediment: a case study from Long Island Sound

Over the past decades, many attempts have been made to generate useful bottom erosion models for the study of cohesive sediment movement. This study addresses some of the key questions involved in determining the functional relationship between erosion rate and bottom shear stress. Current, wave, and turbidity data were collected from a bottom mounted instrument array in a moderately energetic estuarine environment. The bottom shear stress was calculated from a wave–current interaction model. The erosion rate was derived from the observed sediment concentration using a vertical mixing model. Examination of the relationship between erosion rate and bottom stress showed that the erosion rate varied at intertidal frequency. When averaged over the tidal fluctuation, the erosion rate remained approximately constant at low stress, but increased sharply when the shear stress rose above a critical value. This suggests two-stage erosion. The bed has a layered structure, in which a thin layer of loose, high water content material overlies a more consolidated bed. The top layer of high water content material (fluff) was easily disturbed and re-suspended by tidal currents, but the consolidated bottom layer was eroded only under conditions of high shear stress.