气相色谱-质谱法同时测定河流沉积物中多环芳烃和有机氯农药

建立了用加速溶剂萃取,气相色谱-质谱法同时测定河流沉积物中16种多环芳烃和19种有机氯农药的分析方法,优化了萃取溶剂、萃取温度和时间、凝胶渗透色谱收集时间、固相萃取洗脱溶剂和洗脱体积等条件。16种多环芳烃的方法检出限在0.15~0.59 ng/g,加标回收率为82%~102%,相对标准偏差(RSD,n=5)为1.1%~4.5%。19种有机氯农药的方法检出限在0.14~2.23 ng/g,加标回收率为71%~108%,相对标准偏差(RSD,n=5)为1.0%~4.5%。实际样品的测定结果表明,该方法分离效果较好,能够满足沉积物样品中多环芳烃和有机氯农药的分析要求。     

Bedload transport and bed resistance associated with density and turbidity currents

Turbidity currents in the ocean are driven by suspended sediment. Yet results from surveys of the modern sea floor and turbidite outcrops indicate that they are capable of transporting as bedload and depositing particles as coarse as cobble sizes. While bedload cannot drive turbidity currents, it can strongly influence the nature of the deposits they emplace. This paper reports on the first set of experiments which focus on bedload transport of granular material by density underflows. These underflows include saline density flows, hybrid saline/turbidity currents and a pure turbidity current. The use of dissolved salt is a surrogate for suspended mud which is so fine that it does not settle out readily. Thus, all the currents can be considered to be model turbidity currents. The data cover four bed conditions: plane bed, dunes, upstream‐migrating antidunes and downstream‐migrating antidunes. The bedload transport relation obtained from the data is very similar to those obtained for open‐channel flows and, in fact, is fitted well by an existing relation determined for open‐channel flows. In the case of dunes and downstream‐migrating antidunes, for which flow separation on the lee sides was observed, form drag falls in a range that is similar to that due to dunes in sand‐bed rivers. This form drag can be removed from the total bed shear stress using an existing relation developed for rivers. Once this form drag is subtracted, the bedload data for these cases collapse to follow the same relation as for plane beds and upstream‐migrating antidunes, for which no flow separation was observed. A relation for flow resistance developed for open‐channel flows agrees well with the data when adapted to density underflows. Comparison of the data with a regime diagram for field‐scale sand‐bed rivers at bankfull flow and field‐scale measurements of turbidity currents at Monterey Submarine Canyon, together with Shields number and densimetric Froude number similarity analyses, provide strong evidence that the experimental relations apply at field scale as well.     

Late Ordovician climbing‐dune cross‐stratification: a signature of outburst floods in proglacial outwash environments?

Climbing dune‐scale cross‐statification is described from Late Ordovician paraglacial successions of the Murzuq Basin (SW Libya). This depositional facies is comprised of medium‐grained to coarse‐grained sandstones that typically involve 0·3 to 1 m high, 3 to 5 m in wavelength, asymmetrical laminations. Most often stoss‐depositional structures have been generated, with preservation of the topographies of formative bedforms. Climbing‐dune cross‐stratification related to the migration of lower‐flow regime dune trains is thus identified. Related architecture and facies sequences are described from two case studies: (i) erosion‐based sandstone sheets; and (ii) a deeply incised channel. The former characterized the distal outwash plain and the fluvial/subaqueous transition of related deltaic wedges, while the latter formed in an ice‐proximal segment of the outwash plain. In erosion‐based sand sheets, climbing‐dune cross‐stratification results from unconfined mouth‐bar deposition related to expanding, sediment‐laden flows entering a water body. Within incised channels, climbing‐dune cross‐stratification formed over eddy‐related side bars reflecting deposition under recirculating flow conditions generated at channel bends. Associated facies sequences record glacier outburst floods that occurred during early stages of deglaciation and were temporally and spatially linked with subglacial drainage events involving tunnel valleys. The primary control on the formation of climbing‐dune cross‐stratification is a combination between high‐magnitude flows and sediment supply limitations, which lead to the generation of sediment‐charged stream flows characterized by a significant, relatively coarse‐grained, sand‐sized suspension‐load concentration, with a virtual absence of very coarse to gravelly bedload. The high rate of coarse‐grained sand fallout in sediment‐laden flows following flow expansion throughout mouth bars or in eddy‐related side bars resulted in high rates of transfer of sands from suspension to the bed, net deposition on bedform stoss‐sides and generation of widespread climbing‐dune cross‐stratification. The later structure has no equivalent in the glacial record, either in the ancient or in the Quaternary literature, but analogues are recognized in some flood‐dominated depositional systems of foreland basins.     

南海北部深水西区中中新世混合沉积模式及控制因素

以新采集的地震资料为基础,对南海北部深水西区的混合沉积作了初步研究。混合沉积在地震剖面上表现为平行—亚平行,振幅强—中,频率中等及连续性中等的反射特征。混合沉积分布在研究区地震资料覆盖范围的西北角,发育规模较大,最大长度达44.7km,最大宽度33.2km,面积1084km2,最大厚度为138m,纵向上分布在中中新统梅山组。综合南海北部构造演化、地震勘探等研究成果,建立了混合沉积模式。该混合沉积分布于半深海沉积区,由其南东东方向的西沙—广乐台地提供碳酸盐岩碎屑(同时也提供部分硅质碎屑),由其西侧的中南半岛提供主要的硅质碎屑。在南海北部深水西区,控制混合沉积分布的主要因素为构造作用(包括海平面变化)、物源供给及水动力条件等三个方面,这三者之间又具有密切的内在联系。     

Extraction and spatiotemporal evolution analysis of tidal flats in the Bohai Rim during 1984-2019 based on remote sensing

Tidal flats, a precious resource that provides ecological services and land space for coastal zones, are facing threats from human activities and climate change. In this study, a robust decision tree for tidal flat extraction was developed to analyse spatiotemporal variations in the Bohai Rim region during 1984-2019 based on 9539 Landsat TM/OLI surface reflection images and the Google Earth Engine (GEE) cloud platform. The area of tidal flats significantly fluctuated downwards from 3551.22 to 1712.36 km² in the Bohai Rim region during 1984-2019, and 51.31% of tidal flats were distributed near the Yellow River Delta and Liaohe River Delta during 2017-2019. There occurred a drastic spatial transition of tidal flats with coastline migration towards the ocean. Low-stability tidal flats were mainly distributed in reclamation regions, deltas, and bays near the estuary during 1984-2019. The main factors of tidal flat evolution in the Bohai Rim region included the direct impact of land cover changes in reclamation regions, the continuous impact of a weakening sediment supply, and the potential impact of a deteriorating sediment storage capability. The extraction process and maps herein could provide a reference for the sustainable development and conservation of coastal resources.     

陕西柞水地区金盆梁金矿区水系沉积物地球化学特征与找矿方向

对陕西柞水地区金盆梁金矿区1∶50 000水系沉积物样品中微量元素含量,元素分布、分配、共生组合特征以及主要元素地球化学异常特征进行综合研究,进一步确定该区找矿方向。结果表明:Au是金盆梁金矿区内主要的成矿元素,Ag为主要伴生元素,As、Sb为远程指示元素;泥盆系上统桐峪寺组第五岩性段上亚段是金矿富集的有利层位;石炭系下统二峪河组下亚组下段、泥盆系上统第四岩性段上亚段、泥盆系上统桐峪寺组第五岩性段上亚段为金成矿有利岩性段;矿区经历了至少两期热液活动,金矿体的形成受低级区域变质作用的影响,与岩浆热液活动有关;以Au为主成矿元素圈定的4个综合异常区与地层展布方向一致。位于玄檀沟附近的综合异常区处在金矿富集有利层位,次级构造发育,指示元素异常套合较好,浓集中心明显,Au异常强度高且规模大,并在异常内发现金矿体,因此,位于玄檀沟附近的综合异常区具有很好的找矿前景。     

Formation and evolution of sand deserts in Xinjiang,Northwest China：Ⅰ. Provenances of desert sands

Sandy desert landscape is a geological product of arid climate and abundant sand materials supply in natural conditions, therefore the formation of sandy desert is an ideal studying object for understanding the interaction between various stratigraphic/epigenetic spheres of the earth system. However, until now, the knowledge about the provenance and formation of these deserts in Xinjiang, Central Asia is diverse and inconsistent, a systematic review is necessary. Ancient aeolian sand sediments in the internal areas of these deserts and their twin dust deposits in the Cenozoic strata surrounding the Xinjiang deserts are direct and indirect clues reflecting the provenance of sand materials and the formation and evolution of deserts. Based on the geochemical, mineralogical and isotopic evidences of desert sands and relevant deposits in the peripheral regions, this paper reviews the research progress on the development of the sandy deserts in Xinjiang, Northwest China. Many proofs proposed that desert sands in Xinjiang were mainly sourced from the ancient pluvial, alluvial and fluvial sediments and were eventually achieved because of the local sand supply. It pointed out that the settings of tectonic structure in Xinjiang had made sediments both in the Tarim Basin and the Junggar Basin being influenced greatly by regional hydrological system and aeolian processes originated from the planetary wind system of westerly, the East Asian winter monsoon and the topographical mountain-valley winds. However, the directions of transportation paths are different between the hydrological dynamics and the aeolian dynamics, which are decided by the slantwise structures of the basins tectonics and the regional atmospheric circulation routes, respectively, and have determined anisotropies of the transport pathway of these sediments delivered by different agents. This results in a geological cycle of detrital sediment transportation in the two large basins and thus largely increases the degree of sediment mixing, alternation and recycle between younger and older sediment sources, as well as the complexity and diversity of sand provenances.     

Geomorphological analysis of the morphometric characteristics that determine the volume of sediment yield of Wadi Al-Arja,South Jordan

This study addresses the morphometric variables that determine the sediment yield in Wadi Al-Arja through the analysis of the impact of different morphometric characteristics along the course of the valley on its sediment yield, as well as the analysis of spatial and formal dimensions and morphologies of the basin and its relationship to the sediment yield. The study also addresses the size of variation in the volume of sediment yield of the river tributaries that make up the water network of the valley under the differences of its morphometric and hydrological characteristics. The study found several results, most notably: The classification of Wadi Al-Arja basin according to the hypsometric integral value (72.1%) within an uneven topography, which increases the force of the erosive activity and the size of the sediment yield if the basin was exposed to moist climatic periods. The study also showed the presence of convergence in the intra-spaces between the river tributaries in the water network. This increases the volume of water flows when these tributaries meet with each other and thus increasing their erosive ability and sediment yield.The study also showed the presence of marked variation in the sediment yield of the river tributaries depending on the differences in its morphometric characteristics. The results of the step-wise regression analysis confirmed the importance of the morphometric and hydrological variables, and plant coverage in interpreting the variation in the size of the sediment yield of the river tributaries of different stream order in Wadi Al-Arja basin, where these variables interpreted 43% of the total variation, with statistical significance less than 0.05.     

哈拉湖岩芯XRF扫描元素统计分析及其环境意义

青藏高原东北缘高山湖泊哈拉湖是位于季风与西风影响的交汇带的封闭深水湖泊,是区域环境和气候变化的良好记录载体。目前对该湖的研究还较少,缺乏对沉积物中元素环境意义的系统认识。通过高分辨率XRF岩芯扫描,用相关、聚类和因子分析的方法对哈拉湖沉积岩芯地球化学元素进行分析。结果显示Ti、K、Si、Al、Fe、Mn等元素变化一致,相关性高,归为同一类,即径流输入的陆源碎屑组分,反映了流域水文状况如径流量的变化。Sr、Zr元素相关性高,为赋存在粗颗粒沉积物中的元素,根据哈拉湖实际,应为冬季湖泊冰面风力搬运,反映了湖区冬季风力强度的变化。Ca元素既与径流输入元素总体变化一致,也与Sr、Zr元素显著相关,且在第一和第二主成分(径流和风力)上的载荷相当,表明哈拉湖沉积物中的碳酸盐既有粗颗粒的外源碎屑,也有湖泊自生的组分,这在利用碳酸盐进行地球化学研究时应重视,注意去除外源碎屑碳酸盐的影响。可溶元素S和Cl可能反映了入湖水量与蒸发对比情况,与湖泊盐度有关。     

黄河银川平原段河岸摆动速率变化及其影响因素(英文)

It is important to examine the lateral shift rate variation of river banks in different periods. One of the challenges in this regard is how to obtain the shift rate of river banks, as gauging stations are deficient for the study of river reaches. The present study selected the Yinchuan Plain reach of the Yellow River with a length of 196 km as a case study, and searched each point of intersection of 153 cross-sections(interval between two adjacent cross-sections was 1.3 km) and river banks in 1975, 1990, 2010 and 2011, which were plotted according to remote sensing images in those years. Then the shift rates for the points of intersection during 1975–1990, 1990–2010 and 2010–2011 were calculated, as well as the average shift rates for different sections and different periods. The results show that the left bank of the river reach shifts mostly to the right, with the average shift rates being 36.5 m/a, 27.8 m/a and 61.5 m/a in the three periods, respectively. Contemporarily, the right bank shifts mostly to the right in the first period, while it shifts to the left in the second and third periods, with the average shift rates being 31.7 m/a, 23.1 m/a and 50.8 m/a in the three periods, respectively. The average shift rates for the left and right banks during the period 1975–2011 are 22.3 m/a and 14.8 m/a, respectively. The bank shift rates for sections A, B and C are different. The shift rate ratio of the left bank in the three sections is 1:7.6:4.6 for shift to the left and 1:1.7:3.8 for shift to the right, while that of the right bank is 1:1.8:1.2 for shift to the left and 1:5.6:17.7 for shift to the right during the period 1975–2011. Obviously, the average shift rate is the least in section A, while it is maximum in section B for shift to the left and in section C for shift to the right. The temporal variation of the shift rate is influenced by human activities, while the spatial variation is controlled by the local difference in bank materials.