东营凹陷下第三系深部碎屑岩储层次生孔隙垂向分布及成因分析

东营凹陷下第三系埋深大于 30 0 0 m的深部碎屑岩储层普遍发育 2～ 4个次生孔隙带 ,Φ=10 %～ 30 % ,K=0 .1× 10 - 3μm2～ 30× 10 - 3μm2 ,为中孔低渗低孔低渗油气储层。综合有机质热演化过程、成岩作用和构造断裂等分析 ,认为东营凹陷埋深大于 30 0 0m碎屑岩地层中 ,第一、二个次生孔隙带埋深在 30 0 0 m～ 390 0 m之间 ,其形成主要与有机质成熟过程释放有机酸对长石等颗粒的溶解有密切关系 ,在深大断裂附近储层同时受到大气淡水的影响 ,而深陷带包裹于暗色泥岩中的浊积砂岩的次生孔隙发育情况还与泥质岩异常压力带有关 ;第三个次生孔隙带埋深一般为 390 0 m～ 430 0 m,主要成因于粘土矿物转化造成的还原环境 ,同时受到硫酸盐热化学氧化还原反应的影响。这三个次生孔隙发育带对储集油气有效。第四个孔隙发育带埋深在 470 0 m以下 ,主要是构造成因的微裂缝 ,较难成为有效的油气储层。     

pH值对长石溶解度及次生孔隙发育的影响

本文从长石溶解反应的机理及各离子形态在溶液中分布的热力学角度出发 ,论述了pH值对三个长石端员及高岭石在流体中溶解度的影响。在此基础上 ,进一步探讨了流体酸碱度对长石向高岭石转化和次生孔隙发育程度的制约 ,并提出了衡量次生孔隙发育程度的参数———转化系数D。     

南海礁栖海藻共附生真菌Pestalotiopsis neglecta SCSIO41 403次级代谢产物研究

研究南海礁栖腔节藻Coelarthrum sp.共附生真菌Pestalotiopsis neglecta SCSIO41403的次级代谢产物。采用中压正相柱层析色谱法和半制备高效液相色谱法, 对真菌发酵产物进行分离纯化, 制备获得6个次级代谢产物单体化合物, 使用核磁共振、质谱等波谱学方法, 结合其理化性质以及文献数据对比, 分别鉴定为: gamahorin (1)、microsporaline C (2)、7-hydroxy-5-methoxy-4,6-dimethylphthalidc (3)、demethyl nectriapyrone A (4)、4-hydroxybenzaldehyde (5)和4-hydroxyphenethyl acetate (6)。这6个化合物均为首次从该菌株发现, 其中化合物1、2、5和6是首次从海洋动植物共附生真菌中发现。抗菌活性筛选显示其中化合物3对白色念珠菌有明显抑制活性。     

熔融制样波长色散X射线荧光光谱法测定白云石中钙镁硅铁铝

白云石属碳酸盐矿物,应用熔融制样X射线荧光光谱法测定其中主次量组分钙、镁、硅、铁、铝时,由于白云石灼烧减量大,在试料片制备过程中,如果以干基试料制备试料片,除灼烧减量外还有少量其他组分被分解出的大量CO₂带走,导致试料损失,测定结果偏低;如果以灼烧基试料制备试料片,由于灼烧后的试料极易吸收空气中的水分和CO₂,同样使测定结果偏低。基于质量守恒原理,本文直接以灼烧减量测量后的灼烧基试料质量作为试料量(即灼烧减量测定所称量的干基试料量扣除灼烧减量的量),以四硼酸锂为熔剂,5%碘化铵溶液为脱模剂,试料与熔剂的稀释比为1:10,于1050℃熔融15 min以上制备的试料片透彻、玻璃化程度高。以白云石标准物质和标准样品作为标准试料,制作各组分的标准曲线的相关系数在0.9940~0.9994之间;方法检出限为0.011%~0.48%;标准物质和标准样品的测定值与认定值基本一致,各组分的相对标准偏差(RSD,n=11)在0.5%~1.7%之间,方法具有较好的重现性。本方法以1050℃灼烧后的试样作为试料制备XRF分析样片,最大限度地降低了灼烧减量因素(空气中的水分和CO₂)对测定结果的影响,适用于白云石及其煅烧物中钙、镁、硅、铁、铝等组分的同时测定。     

烃气测量法在辽宁白云金矿找矿潜力评价中的应用

通过对辽宁白云金矿区典型的Ⅰ-1号金矿体11线的地表及井下不同标高进行系统采样,分析各指标异常在空间上与金矿体之间的对应关系,弄清白云地区地表土壤次生晕与坑道原生晕的关联性,发现烃气测量法在辽宁景观条件下完全适用,总结出了本区进行找矿预测的地质和地球化学找矿标志。通过对姚家岭北部地区进行烃类组分及部分微量元素异常展布特征分析,并结合异常分布区的地质条件进行了综合找矿潜力评价,圈定了相关找矿有利区。     

Content Variations of Rubidium and Bromide in Sylvite Derived from Carnallite by Leaching of Magnesium Chloride

正The relationship between sylvinite and carnallite is important in the potash mine body contained carnallite,especially sylvinite overlies carnallite,the reverse of a normal depositional sequence.Trace elements are more     

Revisiting Sustainable Development of Dry Valleys in Hengduan Mountains Region

Dry valleys are a striking geographic landscape in Hengduan Mountains Region and are characterized by low rainfall, desert type of vegetation and fragile environment. Past efforts and resources have been concentrated mainly on rehabilitation of degraded ecosystem and fragile environment, particularly reforestation, while socio-economic development has been largely overlooked. Despite successes in pocket areas, the overall trend of unsustainability and environmental deterioration are continuing. It is important to understand that uplift of the Tibetan Plateau is the root cause of development of dry valleys, and development and formation of dry valleys is a natural process. Human intervention has played a secondary role in development of dry valleys and degradation of dry valleys though human intervention in many cases has speeded up environmental degradation of the dry valleys. It is important to understand that dry valleys are climatic enclaves and an integrated approach that combines rehabilitation of degraded ecosystems and socio-economic development should be adopted if the overall goal of sustainable development of dry valleys is to be achieved. Promotion of niche-based cash crops, rural energy including hydropower, solar energy, biogas and fuelwood plantation is recommended as the priority activities.     

广西岩溶区金属硫化物矿床风化与元素表生迁移特征

对广西岩溶区三个铅锌硫化物矿床风化带观测结果表明，中低山岩溶区硫化物矿床具有更强烈的风化淋滤作用，但次生晕面积较小；岩溶平原区硫化物矿床风化与元素表生迁移特征较相似于非岩溶区的情况，表现在可产生较宽的ｐＨ偏低带和较大面积的次生晕     

Paleoearthquakes in the Uimon basin (Gorny Altai)

Paleoseismological studies confirm that the Uimon basin is thrust by its northern mountain border along the active South Terekta fault. The latest motion along the fault in the 7-8th centuries AD induced an earthquake with a magnitude of M_w= 7.4-7.7 and a shaking intensity of I = 9-11 on the MSK-64 scale. The same fault generated another event (M > 7, I = 9-10), possibly, about 16 kyr ago, which triggered gravity sliding. The rockslide dammed the Uimon valley and produced a lake, where lacustrine deposition began about 14 ± 1 kyr ago, and a later M > 7 (I = 9-10) earthquake at ~ 6 ka caused the dam collapse and the lake drainage. Traces of much older earthquakes that occurred within the Uimon basin are detectable from secondary deformation structures (seismites) in soft sediments deposited during the drainage of a Late Pleistocene ice-dammed lake between 100 and 90 ka and in ~ 77 ka alluvium. The magnitude and intensity of these paleoearthquakes were at least M > 5.0-5.5 and I > 6-7.