Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.     

絮凝法强化大生活用海水一级处理研究

研究了无机絮凝剂石灰、硫酸铝、聚合氯化铝、聚合硫酸铁和氯化铁单独使用及其与有机高分子絮凝剂聚丙烯酰胺（PAM）配合使用时强化大生活用海水一级处理的效果，结果表明，无机絮凝剂与有机絮凝剂配合使用时有很好的强化效果，COD去除率最高达61%，且对SS和BOD也有一定的去除效果。     

天津港南部海区水体富营养化水平评价

根据2006年3月和7月的调查数据,对天津港南部海区海水的营养水平及动态变化进行了评价。考虑到水质状况和水体营养水平是水体中多项指标分析评价的综合结果.本文先通过单项指标评价法和营养指数法进行评价。然后又通过集对分析方法,选择化学需氧量(COD)、无机磷(DIP)、无机氮(DIN)、叶绿素a(Ch1—a)等作为评价指标,对该区海水富营养化水平进行了综合评价。评价结果表明集对分析方法更能反映海水的实际富营养化状况,计算结果显示天津港南部海域两期调查中除21,26.27和29站位在7月呈富营养化状态其余站位海水均在中营养(Ⅳ)及以下水平状况,未达到富营养化水平,水质状况较好。     

海州湾淤泥质海滩剖面堆积过程的计算模式

分别于1986年12月和1985年3月1日—1987年3月1日在海州湾进行了波浪和含沙量观测，运用所获资料以及本区长期水文、地形资料，采用流体力学、沉积学和泥沙运动力学相结合的研究方法，建立了海州湾淤泥质海滩剖面堆积过程的二维计算模式。结果表明，在堆积型淤泥质海滩，由于浮泥的经常性存在，使波浪急剧衰减，其对岸滩的作用甚为微弱，潮流成为塑造淤泥质海滩的主要动力，岸滩在淤涨过程中，在平均高潮位厂沿和平均低潮位附近出现两个凸点，上一个凸点外推速率大于下一个凸点，潮下带变化缓慢。     

长江口海水的密度

为了核对1980年国际海水状态方程应用于中国近岸海水的可靠性,高精度的磁力浮沉子密度计在15—25℃,盐度5—35,一个大气压条件下,测量了长江口附近海水及其人工稀释海水的相对密度。结果表明,海水密度直接测量值系统地偏高于状态方程计算值,二者之间的偏差随水样盐度值降低而增大,且与海水[Ca~(2+))/s比值成明显正相关关系。经计算机拟合,导出了长江口附近海水及其稀释海水的状态方程,该方程计算值与实验值的平均标准偏差为±3.9×10~(-3)kg/m~3。     

胜利二号极浅海步行坐底式钻井平台防腐措施研究

本文根据胜利二号极浅海步行坐底钻井平台的作业和工作环境特点，进行了防腐措施研究，设计了切合实际的防腐措施。该平台在海上作业近四年进坞修理，经观测防腐情况良好。     

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

解决山东水资源短缺的对策

分析了山东省水资源现状和存在的主要问题，针对山东省水资源的严重短缺，提出了在传统用水、治水的基础上，实施人工增雨工程，直接利用海水和海水淡化与节约用水，建立节水型社会，调整水源结构，更新用水观念，开发新水源，综合用水，综合治水的路子，只有这样才能长久解决水危机。     

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c     

基于MAPGIS的县级土地利用数据库建设及探讨——以大同市新荣区为例

本文体现了3S技术在县级土地更新调查中的重要性。重点介绍了在MAPGIS土地利用数据库系统中通过专题数据建立土地利用现状数据库,从内业判读,到外业调查,然后进行数据入库前的检查,分析数据的精度,入库后的相关处理和检查,最后建立新荣区1:1万土地利用数据库。通过建立的数据库,进行统计和汇总,输出各种专题图表,供土地部门进行合理规划和决策。