Statistical approach to determine the salinized ground water flow path and hydrogeochemical features around the underground LPG cavern,Korea

The ground water flow path of the coastal area in the Yellow Sea, Korea, was interpreted using both the cross‐correlation analysis of hydraulic properties and the principal component analysis (PCA) of ground water chemistry. Data was obtained from observation wells in the underground liquefied petroleum gas (LPG) cavern constructed in the coastal area of Pyeongtaek. Cross‐correlation results showed that the operating pressure became more influenced on artificial factors for the variation of the groundwater level of the study area (45–66% of correlation coefficient) even though its affecting area was limited to the region with fractures or faults, and also showed that the delay time from the variation of operating pressure to the fluctuation of ground water level were relatively long periods (28–31 days). Three hydrogeochemical events (encrusted cement dissolution, host rock dissolution, and seawater intrusion), which were dominantly influenced on ground water quality, could be induced from the result of PCA. Quantitative evaluation for these events using the mixed equation with principal component scores suggest that the dissolution of encrusted cement materials was the predominant factor (39·0% of the total mixed proportion) to change the chemical composition of the seepage water during the ground water flow from the observation wells to the cavern. Integration of the statistical results also imply that ground water flow and hydrogeochemistry were predominantly affected by artificial factors such as cavern operation pressure and dissolution of encrusted cement materials, which were interdependent factors on the observation wells with high cross‐correlation coefficients and pH. Copyright © 2007 John Wiley & Sons, Ltd.     

Kinetics of phosphate adsorption by iron oxyhydroxides in aqueous systems

The rate of uptake of phosphate onto synthetic Fe(III)- and Fe(II)-derived oxyhydroxides has been studied using reaction conditions similar to those encountered in natural waters. Kinetic analyses were carried out on the adsorption profiles and both first-order and second-order conditional rate constants were obtained. The temperature dependence of some of the rate constants was investigated and corresponding apparent activation energies calculated. Similar experiments and analyses were undertaken using Fe from natural sources and in general the conditional rate constants obtained in seawater were in agreement with the synthetic ones. The results of this study are of value when comparing the time scales of adsorption processes in natural waters with the time scales of mixing and advection.     

细基江篱繁枝变种在不同水层中的栽培试验

本文报道了为改变我国华南沿海目前在半咸淡水塘中进行地播式裁培细基江篱繁枝变种单产低的状况而进行的不同水层夹苗栽培和施肥增产试验,证明了越靠近水面江篱藻体生长越快,越接近底部藻钵生长越差,提出如果在水塘中单纯裁培江篱则水塘深度应保持20～30厘米,如果水深超过1米以上,则应采用浮筏式夹苗栽培,并在水中混养鱼虾等。浸泡施肥试验证明,在短短的40天裁培过程施肥藻体比不施肥藻体增产23％,说明了施肥的重要性。     

Use of microelectrodes for electrochemical measurement of nitric oxide in natural seawater

In this paper, the application of a homemade Nation and Co(Salen) modified platinum microelectrode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nation and Co(Salen) modified platinum microelectrode.     

Observations and modelling of the travel time delay and leading negative phase of the 16 September 2015 Illapel,Chile tsunami

The systematic discrepancies in both tsunami arrival time and leading negative phase (LNP) were identified for the recent transoceanic tsunami on 16 September 2015 in Illapel, Chile by examining the wave characteristics from the tsunami records at 21 Deep-ocean Assessment and Reporting of Tsunami (DART) sites and 29 coastal tide gauge stations. The results revealed systematic travel time delay of as much as 22 min (approximately 1.7％ of the total travel time) relative to the simulated long waves from the 2015 Chilean tsunami. The delay discrepancy was found to increase with travel time. It was difficult to identify the LNP from the near-shore observation system due to the strong background noise, but the initial negative phase feature became more obvious as the tsunami propagated away from the source area in the deep ocean. We determined that the LNP for the Chilean tsunami had an average duration of 33 min, which was close to the dominant period of the tsunami source. Most of the amplitude ratios to the first elevation phase were approximately 40％, with the largest equivalent to the first positive phase amplitude. We performed numerical analyses by applying the corrected long wave model, which accounted for the effects of seawater density stratification due to compressibility, self-attraction and loading (SAL) of the earth, and wave dispersion compared with observed tsunami waveforms. We attempted to accurately calculate the arrival time and LNP, and to understand how much of a role the physical mechanism played in the discrepancies for the moderate transoceanic tsunami event. The mainly focus of the study is to quantitatively evaluate the contribution of each secondary physical effect to the systematic discrepancies using the corrected shallow water model. Taking all of these effects into consideration, our results demonstrated good agreement between the observed and simulated waveforms. We can conclude that the corrected shallow water model can reduce the tsunami propagation speed and reproduce the LNP, which is observed for tsunamis that have propagated over long distances frequently. The travel time delay between the observed and corrected simulated waveforms is reduced to <8 min and the amplitude discrepancy between them was also markedly diminished. The incorporated effects amounted to approximately 78％ of the travel time delay correction, with seawater density stratification, SAL, and Boussinesq dispersion contributing approximately 39％, 21％, and 18％, respectively. The simulated results showed that the elastic loading and Boussinesq dispersion not only affected travel time but also changed the simulated waveforms for this event. In contrast, the seawater stratification only reduced the tsunami speed, whereas the earth's elasticity loading was responsible for LNP due to the depression of the seafloor surrounding additional tsunami loading at far-field stations. This study revealed that the traditional shallow water model has inherent defects in estimating tsunami arrival, and the leading negative phase of a tsunami is a typical recognizable feature of a moderately strong transoceanic tsunami. These results also support previous theory and can help to explain the observed discrepancies.     

Sea‐level rise impact on fresh groundwater lenses in two‐layer small islands

The fresh groundwater lenses (FGLs) of small islands can be highly vulnerable to climate change impacts, including sea‐level rise (SLR). Many real cases of atoll or sandy islands involve two‐layer hydrogeological conceptualizations. In this paper, the influential factors that affect FGLs in two‐layer small islands subject to SLR are investigated. An analytical solution describing FGLs in circular islands, composed of two geological layers, is developed for the simplified case of steady‐state and sharp‐interface conditions. An application of the developed model is demonstrated to estimate the FGL thickness of some real‐world islands by comparison with existing FGL thickness data. Furthermore, numerical modelling is applied to extend the analysis to consider dispersion effects and to confirm comparable results for both cases. Sensitivity analyses are used to assess the importance of land‐surface inundation caused by SLR, relative to other parameters (i.e. thickness of aquifer layers, hydraulic conductivity, recharge rate and land‐surface slope) that influence the FGL. Dimensionless parameters are used to generalize the findings. The results demonstrate that land‐surface inundation has a considerable impact on a FGL influenced by SLR, as expected, although the FGL volume is more sensitive to recharge, aquifer thickness and hydraulic conductivity than SLR impacts, considering typical parameter ranges. The methodology presented in this study provides water resource managers with a rapid‐assessment tool for evaluating the likely impacts of SLR and accompanying LSI on FGLs.     

基于GIS建模的海水环境质量可变模糊识别评价

基于对立统一与质量互变定理的可变模糊评价方法引入海水水质综合评价,构建基于对立统一与质量互变定理的海洋环境质量可变模糊评价模型,首先分析可变模糊评价方法的原理和方法,然后结合GIS栅格数据在表达空间信息方面具有的独特优势,以栅格数据为基础,利用地理信息系统空间叠置分析、地理信息系统空间建模等计算,建立基于多源栅格数据的海水环境可变模糊综合评价模型,得到莱州湾2004~2010年海水环境空间分布图。实践证明,该模型应用于海水水质综合评价是完全可行的,为海洋环境领域的多目标综合评价与决策提供了新的思路与方法。     

海水中碳酸根与固体粒子的相互作用

本文研究了海水中碳酸根在固体粒子上的吸附。碳酸根在各种因素颗粒物上的吸附程度上大小顺序为：赤铁矿〉δ－ＭｎＯ２〉水锰矿〉ＳｉＯ２,最大吸附量可达到约２ｍｇＣ／ｇ吸附剂,且最大吸附值均在天然海水ｐＨ（ｐＨ８）左右。在低ＰＨ时,碳酸根对ＮａＣｌ介质中砷酸根的吸附没有影响,在高ｐＨ时,则降低了砷酸根在固体颗粒物上的吸附量,因此碳酸根的存在对其他阴离子的吸附会产生竞争作用。     

Influence of m-cresol purple indicator additions on the pH of seawater samples: correction factors evaluated from a chemical speciation model

The perturbation of the indicator m-cresol purple on the pH in seawater is illustrated in diagrams, representing measurements in 1-cm and 5-cm cells. The diagrams apply to a measured pH interval of 7.4–8.4 using a 2-mM stock solution of m-cresol purple sodium salt dissolved in seawater. The magnitude of the perturbation is described as correction values, i.e., the change in seawater pH caused by the indicator. The diagrams are based on calculations made by using the equilibrium speciation programme, MARINHALT. From these calculations, and least squares fitting methods, pH correction values are described in terms of the pH difference between each seawater sample and the pH of an indicator stock solution. Calculations are performed for a typical high latitude water and a north Pacific deep water. Diagrams are presented for a salinity of 35 and a temperature of 15°C. Responses to salinities between 32 and 36 and temperatures 15–25°C are illustrated as well. A ±0.05 pH difference between a seawater sample and an indicator stock solution gives a correction of less than 0.001 pH unit for a 1-cm cell. For a 5-cm cell, pH differences between the indicator stock solution and a seawater sample as large as ±0.3 cause corrections smaller than ±0.001 pH unit. Calculations demonstrate that the five-fold lower indicator concentration used with 5-cm cells decreases the perturbation effect by approximately a factor of five relative to 1-cm cells.     

珠江口海水密度的研究

用磁力浮沉子密度测量装置,在１５ ～２５ ℃之间的三个温度下测定了珠江口２０ 个水样的密度。结果表明,测定值皆高于相应条件下国际标准海水状态方程的计算值,在海水盐度范围０．０８～３３ ．４４６ ,密度平均偏差范围为２ ．４ ～５４．０ ×１０ － ３ｋｇ／ｍ３ 。测定密度和计算密度的偏差随盐度的降低而增大,与盐度的变化成直线相关：与（Ｃａ２ ＋ ）／Ｓ、ＳＯ４２ － ／Ｓ比和比碱度之间皆呈指数曲线相关。珠江口水样（Ｃａ２ ＋ ）／Ｃ１ 、ＳＯ４２ － ／Ｃ１ 和比碱度平均值分别超出大洋水平均值１７ ．８ ％ 、８ ．２１ ％ 和１５２ ％ ,其余的Ｎａ ＋ ／Ｃ１、Ｋ＋ ／Ｃ１ 和Ｓｒ２ ＋ ／Ｃ１ 比值与大洋水无明显差别,基本类同。珠江口海水的高碱度、高（Ｃａ２ ＋ ）／Ｃ１ 和高ＳＯ４２ － ／Ｃ１ 是造成其海水密度正偏差的主要因素。经计算机拟合,首次导出了珠江口海水密度的状态方程,该方程计算值与实验值的平均标准偏差为±２．５×１０－ ３ｋｇ／ｍ３ 。