Distribution and partitioning of major and trace elements in pyrite-bearing sediments of a Mediterranean coastal lagoon

The formation of iron sulphide minerals exerts significant control on the behaviour of trace elements in sediments. In this study, three short sediment cores, retrieved from the remote Antinioti lagoon (N. Kerkyra Island, NW Greece), are investigated concerning the solid phase composition, distribution, and partitioning of major (Al, Fe) and trace elements (Cd, Cu, Mn, Pb, and Zn). According to ²¹⁰Pb, the sediments sampled correspond to depositions of the last 120 years. The high amounts of organic carbon (4.1–27.5%) result in the formation of Fe sulphides, predominantly pyrite, already at the surface sediment layers. Pyrite morphologies include monocrystals, polyframboids, and complex FeS–FeS₂ aggregates. According to synchrotron-generated micro X-ray fluorescence and X-ray absorption near-edge structure spectra, authigenically formed, Mn-containing, Fe(III) oxyhydroxides (goethite type) co-exist with pyrite in the sediments studied. Microscopic techniques evidence the formation of galena, sphalerite and CuS, whereas sequential extractions show that carbonates are important hosts for Mn, Cd, and Zn. However, significant percentages of non-lattice held elements are bound to Fe/Mn oxyhydroxides that resist reductive dissolution (on average 60% of Pb, 46% of Cd, 43% of Zn and 9% of Cu). The partitioning pattern changes drastically in the deeper part of the core that is influenced by freshwater inputs. In these sediments, the post-depositional pyritization mechanism, illustrated by overgrowths of Fe monosulphides on pre-existing pyrite grains, results in relatively high degree of pyritization that reaches 49% for Cd, 66% for Cu, 32% for Zn and 7% for Pb.     

Evaluation of the relative roles of global versus local sedimentary controls on Middle to Late Pleistocene formation of continental margin strata,Canterbury Basin,New Zealand

Determining the relative influence of eustasy versus local sedimentary processes on strata formation is a fundamental challenge in the study of continental margin stratigraphy. In this paper, the relative contribution of these factors on continental margin evolution during the Middle to Late Pleistocene is evaluated using samples from Integrated Ocean Drilling Program Expedition 317. Core‐logging, biostratigraphy and quantitative X‐ray diffraction mineralogy are used to delineate continental shelf sedimentary systems. Major lithological unconformities bound stratigraphic sequences that contain recurring compositional patterns and that resemble other examples of Middle to Upper Pleistocene sequences. However, a preliminary chronology suggests that sequence boundary formation cannot be linked ‘one to one’ with eustatic cycles and therefore these sequences can contain multiple ca 100 ka eustatic cycles. Smaller amplitude, higher frequency transitions in sediment composition are interpreted as stratigraphic sequences driven by more rapid perturbations in the interplay of accommodation and sediment supply; their stratigraphy is variable in time and across the shelf, suggesting a strong influence of local sedimentary forcing in their formation. Changes in sediment composition after the Middle Pleistocene Transition indicate that sediment transfer from onshore sources in the glaciated Southern Alps to the middle‐shelf occurred over a single 100 ka glacio‐eustatic cycle, with an additional 100 ka lag before the mineralogical signal was preserved on the outer‐shelf. This phenomenon is coincident with rapid shelf progradation in this basin, suggesting a causal relation between across‐shelf sediment transport and margin progradation. This is one of very few studies that provide insights at the core scale into the processes driving continental margin evolution during the Middle to Late Pleistocene. This work shows that compositional changes in mud‐dominated successions can lead to a sequence stratigraphic interpretation and the identification of high‐frequency sequences, which may not be possible using a conventional stratigraphic approach.     

Nature,origin and evolution of a Late Pleistocene incised valley‐fill,Sunda Shelf,Southeast Asia

Understanding the stratigraphic fill and reconstructing the palaeo‐hydrology of incised valleys can help to constrain those factors that controlled their origin, evolution and regional significance. This condition is addressed through the analysis of a large (up to 18 km wide by 80 m deep) and exceptionally well‐imaged Late Pleistocene incised valley from the Sunda Shelf (South China Sea) based on shallow three‐dimensional seismic data from a large (11 500 km²), ‘merge’ survey, supplemented with site survey data (boreholes and seismic). This approach has enabled the characterization of the planform geometry, cross‐sectional area and internal stratigraphic architecture, which together allow reconstruction of the palaeo‐hydrology. The valley‐fill displays five notable stratigraphic features: (i) it is considerably larger than other seismically resolvable channel forms and can be traced for at least 180 km along its length; (ii) it is located in the axial part of the Malay Basin; (iii) the youngest part of the valley‐fill is dominated by a large (600 m wide and 23 m deep), high‐sinuosity channel, with well‐developed lateral accretion surfaces; (iv) the immediately adjacent interfluves contain much smaller, dendritic channel systems, which resemble tributaries that drained into the larger incised valley system; and (v) a ca 16 m thick, shell‐bearing, Holocene clay caps the valley‐fill. The dimension, basin location and palaeo‐hydrology of this incised valley leads to the conclusion that it represents the trunk river, which flowed along the length of the Malay Basin; it connected the Gulf of Thailand in the north with the South China Sea in the south‐east. The length of the river system (>1200 km long) enables examination of the upstream to downstream controls on the evolution of the incised valley, including sea‐level, climate and tectonics. The valley size, orientation and palaeo‐hydrology suggest close interaction between the regional tectonic framework, low‐angle shelf physiography and a humid‐tropical climatic setting.     

High‐resolution reconstruction of a coastal barrier system: impact of Holocene sea‐level change

This study presents a detailed reconstruction of the sedimentary effects of Holocene sea‐level rise on a modern coastal barrier system. Increasing concern over the evolution of coastal barrier systems due to future accelerated rates of sea‐level rise calls for a better understanding of coastal barrier response to sea‐level changes. The complex evolution and sequence stratigraphic framework of the investigated coastal barrier system is reconstructed using facies analysis, high‐resolution optically stimulated luminescence and radiocarbon dating. During the formation of the coastal barrier system starting 8 to 7 ka rapid relative sea‐level rise outpaced sediment accumulation. Not before rates of relative sea‐level rise had decreased to ca 2 mm yr^?1 did sediment accumulation outpace sea‐level rise. From ca 5·5 ka, rates of regionally averaged sediment accumulation increased to 4·3 mm yr^?1 and the back‐barrier basin was filled in. This increase in sediment accumulation resulted from retreat of the barrier island and probably also due to formation of a tidal inlet close to the study area. Continued transgression and shoreface retreat created a distinct hiatus and wave ravinement surface in the seaward part of the coastal barrier system before the barrier shoreline stabilized between 5·0 ka and 4·5 ka. Back‐barrier shoreline erosion due to sediment starvation in the back‐barrier basin was pronounced from 4·5 to 2·5 ka but, in the last 2·5 kyr, barrier sedimentation has kept up with and outpaced sea‐level. In the last 0·4 kyr the coastal barrier system has been prograding episodically. Sediment accumulation shows considerable variation, with periods of rapid sediment deposition and periods of non‐deposition or erosion resulting in a highly punctuated sediment record. The study demonstrates how core‐based facies interpretations supported by a high‐resolution chronology and a well‐documented sea‐level history allow identification of depositional environments, erosion surfaces and hiatuses within a very homogeneous stratigraphy, and allow a detailed temporal reconstruction of a coastal barrier system in relation to sea‐level rise and sediment supply.     

长江口现代潮滩沉积物粒度特征及其在沉积相识别中的应用

本研究通过对长江口现代潮滩6个柱状样沉积物的粒度精细分析,试图提取研究区潮滩沉积相识别的粒度敏感指标,并通过对长江三角洲南部平原一个全新世钻孔(SL67孔)潮滩沉积物的粒度研究,检验现代沉积粒度敏感指标在全新世钻孔潮滩沉积相识别中的应用。研究显示,长江口现代高潮滩和中潮滩的黏性颗粒(8μm)和粗粉砂(32~63μm)含量差异显著,可以成为区分高潮滩和中潮滩的敏感组分;在开敞型的中、低潮滩之间,砂(63μm)和细粉砂含量(8~32μm)也差异明显。长江口现代潮滩沉积物的粒度频率曲线及众数值也可以有效协助区分高潮滩、中潮滩和低潮滩沉积物。利用上述粒度敏感组分和众数指标检验SL67孔全新世早中期在海平面波动控制下的潮滩演替过程,并揭示了7.5 cal ka BP前后的一次海平面加速上升事件。     

热带气旋"凤凰"（2014）的结构演变及其引起的海洋响应分析

利用日本多功能运输卫星（Multi-functional Transport Satellite,简称为MTSAT-2）逐小时云顶亮温资料、Climate Prediction Center Morphing Technique（CMORPH）逐3小时降水资料及南海北部的现场观测资料,对2014年第16号热带气旋"凤凰"的结构演变和远距离洋面上的海洋响应特征进行了研究。结果表明:高空环流形势场的变化主导了"凤凰"的移动方向,调整其云系结构;"凤凰"过境期间测站处气压和气温明显下降,风速和相对湿度有所增加,并伴随有多次阵性降雨过程,最大降雨量可达174 mm/h;"凤凰"引起的强混合的热泵作用导致测站处海洋混合层冷却加深,三个站位观测到的最大海表面降温分别为0.53 ℃（站位2）、0.50 ℃（站位4）、1.18 ℃（站位5）;"凤凰"期间海表面盐度下降,且强降盐过程与降水时段具有较好的时间一致性,降水时段内,三个站位观测到的表层最大降盐量分别为0.557 psu（站位2）、0.407 psu（站位4）、0.773 psu（站位5）。      

2020年夏季海洋天气评述

2020年夏季（6—8月）,北半球极涡呈现明显的单极型分布,极涡主体位于北极圈内,中心偏向东半球,中高纬环流呈现4波型分布。6—7月,西太平洋副热带高压较常年平均偏强,且位置偏西偏南,不利于热带气旋活动。2020年夏季共有8个热带气旋在西北太平洋和南海生成,其中7月没有热带气旋生成。除西北太平洋和南海之外,其他热带洋面另有20个热带气旋生成,其中北大西洋11个,东太平洋8个,北印度洋1个。受偏南暖湿气流的影响,我国北方海域多海雾天气。同时受入海气旋活动影响,多海上大风过程。夏季近海海域共出现了7次比较明显的海雾过程,其中6月3次,7月1次,8月3次。大风过程出现了10次, 2次由热带气旋影响,7次与入海气旋活动有关。发生2 m以上的大浪过程12次,6—8月分别出现了4次、5次和3次。     

Last Glacial Maximum Sea Surface Temperatures: A Model-Data Comparison

In this study,the authors investigated changes in Last Glacial Maximum(LGM)sea surface temperature(SST)simulated by the Paleoclimate Modelling Intercomparison Project(PMIP)multimodels and reconstructed by the Multiproxy Approach for the Reconstruction of the Glacial Ocean Surface(MARGO)project,focusing on model-data comparison.The results showed that the PMIP models produced greater ocean cooling in the North Pacific and Tropical Ocean than the MARGO,particularly in the northwestern Pacific,where the modeldata mismatch was larger.All the models failed to capture the anomalous east-west SST gradient in the North Atlantic.In addition,large discrepancies among the models were observed in the mid-latitude ocean,particularly with models in the second phase of the PMIP.Although these models showed better agreement with the MARGO,the latest models in the third phase of the PMIP did not show substantial progresses in simulating LGM ocean surface conditions.That is,improvements in the modeling community are still needed to describe SST for a better understanding of climate during the LGM.     

海表温度异常影响东亚夏季风年代际变化的数值模拟

采用1950-2000年逐月观测的不同海域(全球、热带外、热带、热带印度洋-太平洋、热带印度洋及热带太平洋)海表温度分别驱动NCAR CAM3全球大气环流模式,进行了多组长时间积分试验,对比ERA-40和NCEP/NCAR再分析资料,讨论了这些海域海表温度异常对东亚夏季风年代际变化的影响。数值试验结果表明:全球、热带、热带印度洋-太平洋和热带太平洋海表温度变化对东亚夏季风的年代际变化具有重要作用,均模拟出了东亚夏季风在20世纪70年代中后期发生的年代际减弱现象,以及强、弱夏季风年代夏季大气环流异常分布的显著不同,这与观测结果较一致,表明热带太平洋是影响东亚夏季风此次年代际变化的关键海区;利用热带印度洋海表温度驱动模式模拟出的东亚夏季风在20世纪70年代中后期发生年代际增强现象,即当热带印度洋海表温度年代际偏暖(冷)时,东亚夏季风年代际增强(减弱),与热带太平洋海表温度变化对东亚夏季风年代际变化的影响相反;热带太平洋海表温度年代际背景的变化对东亚夏季风在20世纪70年代中后期的年代际减弱有重要作用。     

Simulation of the Direct Radiative Effect of Mineral Dust and Sea Salt Aerosols in a Doubled Carbon Dioxide Climate

The authors examine the equilibrium climatic response to the direct radiative effect(DRE)of mineral dust and sea salt aerosols in a doubled-CO2climate with two-way coupling of aerosol-climate interactions.In response to the drier and windier conditions,dust emissions increase by 26%in the Sahara Desert and by 18%on the global scale relative to present day.Sea salt emissions increase in high latitudes(60°)but decrease in middle latitudes(30°–60°)of both hemispheres due to the poleward shift of westerlies,leading to a 3%decrease in global emissions.The burdens of dust and sea salt increase by 31%and 7%respectively,because reductions in rainfall over the tropical oceans increase the lifetime of particles in the warmer climate.The higher aerosol loading in the doubled-CO2climate reinforces aerosol DRE by0.2 W m 2,leading to an additional cooling of 0.1°C at the surface compared with the climatic effects of aerosols in present day.The additional cooling from changes in natural aerosols compensates for up to 15%of the regional warming induced by doubled CO2.