小振幅海洋内波的演变、破碎和所致混合

利用基于谱方法和MPI并行运算的数值模式SpectralModel,直接数值模拟了三维小振幅海洋内波的演变、破碎和所致湍流混合,指出导致其不稳定而破碎的为PSI(parametric subharmonic instability)机制;对于内波破碎所致的湍流混合过程,分析了跨等密度面扩散系数kρ、混合效率γ、浮力通量谱、动能谱以及势能谱等统计性质:内波破碎前,kρ和γ保持低值水平,浮力通量谱值为负,且集中在低波数段;内波破碎后,kρ和γ迅速增大,最大值分别约为0.9×103m2/s和0.18,浮力通量谱值在低波数段为负值,在高波数段为正值,这是因为层化湍流中势能向小尺度运动传递和动能向小尺度运动传递相比更为有效。在内波破碎、强湍流混合阶段,势能谱存在一谱段满足kz3律,P(kz)=0.2N2kz3。此外,与二维模拟结果相比较,导致内波不稳定而破碎的均为PSI机制,kρ、浮力通量谱、势能谱变化趋势大体一致;但三维数值实验中,内波破碎时间提前,湍流衰减加快;KE谱在高波数部分下降速度相对减小,更接近于kz3。     

boldmath Investigation of inter-molecular hydrogen bonding in the binary mixture (acetone + water) by concentration dependent Raman study and ab initio calculations

This paper reports that vibrational spectroscopic analysis on hydrogen-bonding between acetone and water comprises both experimental Raman spectra and ab initio calculations on structures of various acetone/water complexes with changing water concentrations. The optimised geometries and wavenumbers of the neat acetone molecule and its complexes are calculated by using ab initio method at the MP2 level with 6-311+G(d,p) basis set. Changes in wavenumber position and linewidth (fullwidth at half maximum) have been explained for neat as well as binary mixtures with different mole fractions of the reference system, acetone, in terms of intermolecular hydrogen bonding. The combination of experimental Raman data with ab initio calculation leads to a better knowledge of the concentration dependent changes in the spectral features in terms of hydrogen bonding.     

Dominant climate factors influencing the Arctic runoff and association between the Arctic runoff and sea ice

介绍了星载雷达波谱仪的观测原理及误差分析模型,并在Hauser等提出的SWIM(sea wave investigation and monitoring by satellite)的基础上分析了波谱仪反演海浪谱的波长分辨率和角度分辨率。为了减小反演调制谱的波动,在数据处理过程中时域和波数域相邻单元的平均个数分别为10和8个。系统在不同的模式下工作,为了获取20°的角度分辨率,对调制谱平均次数分别取3次(模式1)、7次(模式2)、10次(模式3)。使用解析法和仿真法分析了SWIM工作在模式2时海浪谱观测的能量误差,两种方法的结果一致。对于给定的海浪条件,能量误差小于20%。     

Computation of wind-wave spectra in coastal waters with SWAN on unstructured grids

An unstructured-grid procedure for SWAN is presented. It is a vertex-based, fully implicit, finite difference method which can accommodate unstructured meshes with a high variability in geographic resolution suitable for representing complicated bottom topography in shallow areas and irregular shoreline. The numerical solution is found by means of a point-to-point multi-directional Gauss–Seidel iteration method requiring a number of sweeps through the grid. The approach is stable for any time step while permitting local mesh refinements in areas of interest. A number of applications are shown to verify the correctness and numerical accuracy of the unstructured version of SWAN.     

Second-Oorder Analytic Solutions of Nonlinear Interactions of Edge Waves on A Plane Sloping Bottom

Based on the full water-wave equation, a second-order analytic solution for nonlinear interaction of short edge waves on a constant plane sloping bottom is presented in this paper. For special case of slope angle b=p/2, this solution can be reduced to the same order solution of deep water gravity surface waves traveling along parallel coastline. Interactions between two edge waves including progressive, standing and partially reflected standing waves were also discussed. The unified analytic expressions with transfer functions for kinematic-dynamic elements of edge waves were also discussed. The random model of the unified wave motion processes for linear and nonlinear irregular edge waves is formulated, and the corresponding theoretical autocorrelation and spectral density functions of the first and second orders are derived. The boundary conditions for the determining determination of the parameters of short edge wave are suggested, that may be seen as one special simple edge wave excitation mechanism and an extension to the sea wave refraction theory. Finally some computation results are demonstrated.     

南海北部陆坡海域内波谱特征

本文对1998年南海季风实验中定点观测的声学多普勒流速剖面仪（Acoustic Doppler Current Profiler,ADCP）海流数据进行频谱分析,结果表明南海北部地区内波之间的非线性作用的强弱影响着该海域的内波谱特征。在季节性温跃层（水深22m和58m）中,由于存在着强的非线性作用,内波带的谱斜率趋于σ^-1和σ^-2之间,而且较高能量的潮谐波频率的峰值随着频率呈现少见的一。递减。在季节性温跃层（水深130m）以下,内波非线性相互作用较弱,观测的内波带谱特征与标准Garrett-Munk内波谱相似,均显示了σ^-2的谱斜率。     

Estimation of the Land Surface Emissivity in the Hinterland of Taklimakan Desert

An accurate accounting of land surface emissivity(ε) is important both for the retrieval of surface temperatures and the calculation of the longwave surface energy budgets.Since ε is one of the important parameterizations in land surface models(LSMs),accurate accounting also improves the accuracy of surface temperatures and sensible heat fluxes simulated by LSMs.In order to obtain an accurate emissivity,this paper focuses on estimating ε from data collected in the hinterland of Taklimakan Desert by two different methods.In the first method,ε was derived from the surface broadband emissivity in the 8–14 μm thermal infrared atmospheric window,which was determined from spectral radiances observed by field measurements using a portable Fourier transform infrared spectrometer,the mean ε being 0.9051.The second method compared the observed and calculated heat fluxes under nearneutral atmospheric stability and estimated ε indirectly by minimizing the root-mean-square difference between them.The result of the second method found a mean value of 0.9042,which is consistent with the result by the first method.Although the two methods recover ε from different field experiments and data,the difference of meanvalues is 0.0009.The first method is superior to the indirect method,and is also more convenient.     

深海热液区主要成分的高温高压拉曼光谱分析

模拟深海热液口环境(最高压力40 MPa,最高温度350℃),对深海热液区的主要成分CO2、CH4及其混合物的水溶液在不同压力和温度条件下的拉曼光谱进行探测和分析,结果显示:常温低压下CO2水溶液的Fermi双峰分别位于1 384.9 cm-1和1 278.3 cm-1处,CH4的水溶液拉曼峰υ1位于2 912.1 cm-1处,均比其气相的拉曼频移小;常温下CO2和CH4水溶液的拉曼特征峰随压力(≤40 MPa)的变化均不明显;在40 MPa的压力下随着温度的升高(≤350℃),CO2水溶液的Fermi双峰分别向高波数区移动了约3.4 cm-1和7.0 cm-1,而CH4水溶液的拉曼峰υ1向低波数区移动了约3.1cm-1;混合后升温过程中CO2的双峰分别向高波数区移动了约4.3 cm-1和3.8 cm-1,CH4的特征峰υ1向低波数区移动了4.5 cm-1。说明在室温到350℃范围内温度的变化对CO2和CH4水溶液拉曼频移有影响,频移量与温度线性相关,而压力在≤40 MPa范围内的改变对拉曼频移影响不明显。     

一种基于多源遥感影像的亚端元光谱提取方法

提出一种利用多源影像来提取低分辨影像亚端元光谱的方法,该方法利用高分辨分类得到的组分与低分辨的光谱之间的线性混合关系,建立了反演出低分辨影像的亚端元光谱的线性模型,并提出一种快速鲁棒反演亚端元光谱的提取方法。利用IKONOS和ETM数据验证了本文提出方法,实验结果表明了该方法的有效性。     

迁安紫苏花岗岩的~(40)Ar/~(39)Ar年龄谱

对采自河北省迁安县水厂地区的紫苏花岗岩中的黑云母和紫苏辉石进行了~(40)Ar/~(39)Ar年龄测定,分别给出了18.7亿年和19.6亿年的~(40)Ar保存年龄。这两种矿物的年龄谱的视年龄的梯度变化表明,紫苏花岗岩形成后是缓慢冷却的。3.9亿年左右的一次热事件,造成了放射成因~(40)Ar的丢失。根据热历史和封闭温度的研究,从27亿年(侵入到该区紫花岗岩中的花岗闪长岩的锆石U-Pb年龄)到19.6亿年,紫苏花岗岩岩体的抬升速率为6.5m/Ma,但从19.6亿年到18.7亿年,其抬升速率高达111m/Ma,具有明显的构造抬升作用。