用X射线荧光光谱法测定Cl、S等31个元素

采用硼酸镶边垫底的粉末样品压片制样,用ARL ADVANT′XP＋型X射线荧光光谱仪对土壤和水系沉积物样品中Na、Mg、Al、Si、P、S、Cl等31个组分进行测定。重点研究了Cl和S等元素的测定条件、痕量元素的背景选择和谱线重叠校正问题。使用经验系数法和康普敦散射作内标校正基体效应。经标准物质校验,结果与标准值吻合。方法的检出限、精密度和准确度能满足多目标地球化学调查样品的分析要求。     

跨国公司地区总部职能与亚洲地区总部的区位研究

跨国公司建立地区总部制度是跨国公司应对经营“全球化”和“本地化”的要求而进行的一项组织变革。由于跨国公司地区总部承担着制定区域性经营战略和协调区域内众多子公司生产、销售、物流、研究与开发、资金筹供、人力资源培养等经营活动的职能，它的区位对东道国及其所在城市经济带来广泛影响。本文从跨国公司和地区总部职能特点入手，分析了该职能的区位因素，并探讨了跨国公司亚洲地区总部的区位特点，最后对中国大陆的国际商务职能建设提出了若干建议。     

火山岩与地形联合约束下海岛土壤稀土元素地球化学空间分布异质性——以广西涠洲岛为例

海岛土壤地球化学特征的研究对于认识海岛表生地质环境有重要意义。本研究以我国最大的第四纪火山海岛——涠洲岛为案例,重点研究亚热带海岛环境下火山岩风化土壤的稀土元素（REE）地球化学特征,并探讨影响其空间分布的关键因素。结果表明,涠洲岛土壤REE总量（ΣREE）自然变化范围较大,介于59.07~575.30 mg/kg,平均值为285.53 mg/kg,高于中国大陆土壤背景值（163.86 mg/kg）,指示火山岩风化海岛具有较高的土壤REE丰度。反距离权重插值法（IDW）分析指示,岛内土壤的REE含量高低变化呈现出以带状和斑块状为主体形态的空间分布不均一性,推断其成因与母质岩石类型和地形位置等因素密切相关。3种不同岩性的成土母岩的ΣREE含量变化序列为：玄武岩（236.66 mg/kg）>火山碎屑岩（215.58 mg/kg）>含生物碎屑海滩沉积物（18.99 mg/kg）,对应的土壤ΣREE含量具有类似变化规律,即玄武岩土壤（307.20 mg/kg）>火山碎屑岩土壤（297.46 mg/kg）>含生物碎屑海滩沉积物土壤（89.73 mg/kg）。该证据指示母岩是控制岛内土壤REE含量变化的首位因素,玄武岩整体上易形成具有较高REE丰度的土壤,火山碎屑岩次之,而含生物碎屑海滩沉积物反之。此外,本研究还发现火山碎屑岩单一岩性区内,发育的土壤REE含量也会随地形地貌差异而出现显著变化,其原因是地形地貌制约了土壤矿物和化学风化程度,海蚀丘陵比海积平原更利于海岛土壤中REE次生富集作用的发生。

     

辽宁锦州市地质遗迹资源禀赋及保护性利用

地质遗迹资源是提高人类当前和将来生活质量最珍贵的、不可再生的自然遗产,其保护、利用与管理是地质遗迹可持续性发展的前提和基础。辽宁省锦州市地跨燕山余脉和辽西中生代盆地,长期的地质演化留下了丰富的地质遗迹资源,其中尤以典型地层剖面、古生物化石、花岗岩地貌、河流地貌景观和海岸线最具特色,典型地质遗迹特征是对重要地质事件与人类活动历史的响应。通过锦州地质遗迹资源专项调查,从遗迹特征、成因等角度,将锦州市地质遗迹资源分为两大类、七小类、十一亚类,共计238处,整体上类型多样、内涵独特、分布范围广。然而,由于基础数据不清、保护意识淡薄、投入资金有限、管理机制不健全等原因,锦州市内的地质遗迹正遭受或面临严重破坏。针对锦州市"山、海、城"旅游产业空间布局、打造精品旅游目的地、宜居城市、生态文明、乡村振兴建设与地质遗迹保护性利用中存在的问题,建立地质遗迹资源保护名录、科普基地、特色风景廊道、风景旅游区、特色小镇及地质文化村,形成多层次、多样化的保护性利用路径。     

近6 ka以来科尔沁沙地东部气候变化记录

 根据科尔沁沙地东部TL剖面磁化率、有机质、化学元素等气候代用指标的变化特征和14C测年结果,分析和讨论了科尔沁沙地6 ka BP以来的气候变化过程。实验数据显示,高频磁化率、低频磁化率、有机质、Al2O3含量变化趋势基本一致,且峰值段对应古土壤层,谷值段对应风成砂层。依据气候代用指标的变化将6 ka BP以来科尔沁沙地气候变化分为3个阶段：Ⅰ.6.0～4.2 ka BP,气候暖湿,夏季风逐渐增强,并占主导,冬季风较弱,与全新世大暖期对应,但存在百年尺度的气候波动,其中：6.0～5.6 ka BP,5.6～5.4 ka BP,4.9～4.2 ka BP气候暖湿;5.6～5.5 ka BP,5.4～4.9 ka BP气候相对冷干。Ⅱ.4.2～1.3 ka BP,气候相对暖湿,与上一阶段相比夏季风有所减弱,但仍强于冬季风,其间也存在次一级波动,3.7～3.6 ka BP,3.4～1.3 ka BP,气候相对暖湿,4.2～3.7 ka BP,3.6～3.4 ka BP气候相对干冷。Ⅲ.1.3～0.65 ka BP以来,气候波动频繁,后期有向暖湿发展的趋势。总体而言,区域气候变化与全球具有较好的一致性。     

Migration and enrichment of trace elements of Lower Palaeozoic carbonate rock strata in Beijing

Analyses of trace elements of the Lower Palaeozoic carbonate rock strata in Beijing show that the contents of As, Hg, F increase from primary carbonate rocks to weathered carbonate rocks and from primary carbonate rocks to the soil coexisting with carbonate rocks, but the distribution regularity of S is not obvious. In the whole weathered stages, the sorption of As is mainly affected by Fe2O3. In soil Fe2O3 is also the main affecting factor of Hg enrichment. The main existing forms of Hg in primary carbonate rocks should simply be physical adsorption, coprecipitation and false isomorphous form between surface of carbonate rock and Hg. In soil the enrichment of F has little relationship with sul-fides and Fe2O3. In primary carbonate rocks, F is mainly absorbed by sulfides and clay minerals, etc. Weathered samples have closer genetic relationships with primary carbonate rocks. This also implies that weathered carbonate rocks have the close existing forms to that of primary carbonate rocks. In primary carbonate rocks FeS2 and FeS are the main forms of S, and sulfides have fixation effect on some heavy metals, whereas in weathered carbonate rocks and soil the fixation effect is weakened.     

北京市大兴区大气降尘环境磁学特征及其环境意义

应用环境磁学方法对北京市大兴区大气降尘环境磁学特征进行了系统研究,并通过与北京市朝阳区、兰州市大气降尘环境磁学特征的对比,对环境磁学在污染物来源解析及扩散条件研究中的应用机理进行了探讨。结果表明,大兴区大气降尘磁性矿物含量明显高于本区表土,人为源影响显著;降尘样品磁学特征主要受磁铁矿控制,并含有一定数量的磁赤铁矿,磁性矿物为准单畴和多畴颗粒;大兴区降尘样品的磁性矿物含量明显低于朝阳区,且样品颗粒相对较细,表明人口密度、车流量、城市发达度对大气污染程度存在显著影响;大兴区与兰州市大气降尘磁性矿物含量的季节变化差异表明,燃煤取暖对北京大气质量的影响显著减弱,燃煤锅炉改造是大气污染防治的重要措施之一。气象因素对大气颗粒物浓度变化有重要影响,降水、低气压和高风速利于大气颗粒物的清除和扩散,低气温对大气颗粒物污染的负面影响显著。     

Field determination for roughness length above the different non-erodible surfaces

Non-erodible elements, for its disturbance to the near-surface airflow, have been widely used in arid and semi-arid regions to protect the surface from wind erosion. Roughness length was usually used to evaluate the protection effect of non-erodible elements from wind erosion. In this study, the wind profiles above five types of non-erodible surfaces including gravel, wheat straw checkerboard barriers, cotton stem checkerboard barriers, shrubs, and herbs were measured and analyzed. The wind velocities above these surfaces increased with height approximately in logarithmic functions. The roughness length of different non-erodible surfaces was calculated by the functions of wind profiles. The results reveal that:(1) Roughness length increased with wind velocity in given wind velocity ranges. (2) On vegetative surfaces, wind did not effectively bend the stems. The threshold wind velocity for bending the stems of Achnatherum splendens was 4 m/s, 10 m/s for Agropyron cristatum, and for Artemisia ordosica, no obvious bending of stems even for wind velocity reaching 12 m/s. (3) Correlation analysis results show that the vegetation''s coverage and frontal area affect the roughness length more significantly than the other parameters. (4) The protective results of these non-erodible elements were evaluated. The checkerboard sand barriers made of cotton stem could provide more effective protection than that made of wheat straw. In the same coverage conditions, vegetation could provide more effective protection from wind erosion than gravel, and the blending of different non-erodible elements especially the combination of blending of vegeation and checkerboard sand barriers could provide more effective protection to the surface.     

Comparative Analysis of Seismic Response Characteristics of Pile-Soil-Stnicture Interaction System

The study on the earthquake-resistant performance of a pile-soil-structure interaction system is a relatively complicated and primarily important issue in civil engineering practice. In this paper, a computational model and computation procedures for pile-supported structures, which can duly consider the pile-soil interaction effect, are established by the finite element method. Numerical implementation is made in the time domain. A simplified approximation for the seismic response analysis of pile-soil-structure systems is briefly presented. Then a comparative study is performed for an engineering example with numerical results computed respectively by the finite element method and the simplified method. Through comparative analysis, it is shown that the results obtained by the simplified method well agree with those achieved by the finite element method. The numerical results and findings will offer instructive guidelines for earthquake-resistant analysis and design of pile-supported structures.     

生物生态防治虾病研究

本文探索虾病防治新途径,采用低值海藻江蓠和对虾混养的生态学方法,江蓠吸收水中二氧化碳进行光合作用,产生大量氧气;同时吸收有机物的分解物 NH_3—N,加速有机物分解。减少 H_2S 积累;从而消除水中紧迫因子威胁,大大减少池水自污及病害,起到抑菌、抑虫、净化水质作用,提高成活率,试验圹对虾成活率达95.1%,对照圹56.6%。试验结果表明,虾病防治效果显著,经济效益明显。