塔里木盆地柯坪地区中寒武统准同生白云岩孔洞充填物期次、地化特征及形成条件*

对塔里木盆地柯坪地区蓬莱坝剖面中寒武统沙依里克组萨布哈白云岩及其溶孔中的多期次充填物进行了岩石学和地球化学分析,以对其沉淀时的流体环境进行恢复。孔洞中的环带状充填物可分为4期,由白云岩向内依次为：（1）乳白色粒状方解石;（2）铁质浸染的杂色柱状方解石;（3）无色透明的石英;（4）紫色粒状萤石。碳氧同位素、微量元素及稀土元素分析结果表明：白云岩具有高的Sr/Ba值5.47,低的U/Th值0.2954（明显小于0.7）,高的Zr/Hf值36.86,相对高的稀土总量,相对高的 δ¹⁸O值-7.444‰,盐度指数Z值为120.56,表明它形成于相对低温、富氧和盐度相对较高的流体环境,进一步证实其是形成于蒸发环境的准同生白云岩。第1期方解石具有低的Sr/Ba值2.33,相对高的U/Th值1.3,低的Zr/Hf值20.857,相对居中的稀土总量,相对低的δ¹⁸O值-13.758‰,盐度指数Z值为105.35（小于120）,表明它形成于温度相对较高、缺氧、盐度较低的流体条件下。第2期方解石具有具有相对低的Sr/Ba值2.77,相对高的U/Th值1,相对低的Zr/Hf值32.08,相对居中的稀土总量,相对低的 δ¹⁸O值-11.344‰,盐度指数Z值为116.51,表明其形成于温度相对较高、贫氧、盐度较低的流体条件下。萤石具有居中的Sr/Ba值3.15,相对高的U/Th值0.8666,相对低的Zr/Hf值31.875,相对低的稀土总量,其配分模式与岩浆成因萤石较为接近,表明其形成于温度相对较高、缺氧、低盐度的流体条件下。这些特征反映该套地层经历了准同生期白云岩化后的埋藏-抬升-再埋藏-最终抬升至地表的过程。     

一种基于直线特征的影像外方位元素解算理论与方法

与点特征相比,影像上的线特征,特别是直线特征,具有识别相对容易、使用灵活等优点,因此对直线摄影测量的研究已成为目前摄影测量的一个重要研究方向。依据空间直线在航空影像上的投影仍然是直线,并结合共线条件方程,通过线性化,推导了基于直线特征计算像片外方位元素的误差方程;并且给出了计算过程。最后,通过实验验证了基于线特征计算像片外方位元素理论与方法的可行性和可靠性。同其他方法相比,该方法具有易于理解、便于计算、实用性强、易于实现影像自动外部定向等特点。     

半方差函数与Moran’s I在土壤微量元素空间分布研究中的应用——以寿光市为例

利用半方差函数与Moran’s I两种空间分析方法,研究了山东省寿光市土壤中微量元素的空间分布特征,以探讨不同空间分析方法的差异性与准确性。结果表明,无论表层土壤还是深层土壤,半方差函数分析得到的土壤微量元素的空间相关距离大约为20~60 km,而空间自相关图获得的正自相关距离为20~25km,负自相关距离为25~55 km。除深层土壤中的Zn元素外,其他元素均达到了显著的自相关水平。空间自相关方法对土壤微量元素空间相关性的判断要优于半方差函数法。     

北京快速更新循环预报系统（BJ-RUC）要素预报质量评估

使用自动站观测资料对BJ-RUC系统预报的北京15个观测站的逐时2 m温度、相对湿度、1小时降水量和风速等地面要素质量进行检验评估。结果表明：BJ-RUC系统预报的2 m温度、相对湿度和风速与实况具有一致的变化趋势,但各要素的预报性能不尽相同。结果表明：（1）对于2 m温度的预报,±1℃误差的准确率为0.2～0.5,±2℃误差的准确率更高;预报性能与预报时效无明显关系;温度预报准确性与季节和日变化有关,春、秋季优于冬、夏季,夜间优于白天。（2）对相对湿度的预报整体偏低,夏季白天偏低、冬季白天偏高。（3）对1小时降水的预报,无论全年还是夏季,晴雨预报准确率很高;对0.1 mm降水的TS评分在0.2左右。（4）对不同站点的预报性能存在明显差异。对平原地区,即海拔高度较低的站点预报性能相对较好,15个站点中,对北京的代表站点（南郊观象台）的预报最为准确;对山区站点的预报性能相对较差,对海拔最高的延庆站的预报性能最差。总体来说,BJ RUC对站点要素预报的变化趋势较好,预报准确率较高,具有很好的参考价值,但要素预报与季节、日变化及海拔高度等因素有关.具体应用时还需做适当订正。     

Trace element and REE geochemistry of fine- and coarse-grained sands in the Ordos deserts and links with sediments in surrounding areas

In addition to mineral analyses, REE and trace element geochemical characteristics of fine- and coarse-grained sands in the Ordos deserts and other sediments in surrounding areas are investigated.Commonly the samples consist of quartz, feldspar and muscovite and less clinochlore, dolomite and ankerite. In few samples muscovite is absent.REE and trace compositions are spatially uniform for the same grain-size sands, suggesting that they could have the same sources or/and were well homogenized. However, fine- and coarse-grained sands in the Ordos deserts show different REE and trace element compositions. Fine-grained sands show higher contents of REE and trace elements than those of coarse-grained sands. They differ in Eu anomalies and (La/Yb)_N ratios although both fractions are characterized by the steep LREE and smooth HREE patterns. The fine- and coarse-grained sands are also distinct in some characteristic element ratios (e.g., Th/Co, La/Sc, Th/Sc and Y/Ni).REE and trace element patterns of the two different grain-size fractions are closely associated with geological properties of individual sources rather than the mineralogical differentiation induced by wind sorting. The coarse-grained sands mainly resulted from sandstone weathering in the Ordos deserts and movements of coarse particles by wind. REE and trace element patterns of fine-grained sands in the Ordos deserts differ from those of sandstones in the Ordos deserts, the alluvial sands in the surrounding mountains and the coarse fluvial sands in the Yellow River. They resemble the fine fluvial sands in the Yellow River. In addition, arid areas of Northwest China such as the Tarim Basin and the Alxa Plateau should not be ruled out as the source of the fine-grained sands in the Ordos deserts because these arid areas reserve plenty of fine-grained sediments and also located in the upwind directions of the Ordos deserts.     

Accuracy of numerical simulations of contaminant transport in heterogeneous aquifers: A comparative study

This work deals with a comparison of different numerical schemes for the simulation of contaminant transport in heterogeneous porous media. The numerical methods under consideration are Galerkin finite element (GFE), finite volume (FV), and mixed hybrid finite element (MHFE). Concerning the GFE we use linear and quadratic finite elements with and without upwind stabilization. Besides the classical MHFE a new and an upwind scheme are tested. We consider higher order finite volume schemes as well as two time discretization methods: backward Euler (BE) and the second order backward differentiation formula BDF (2). It is well known that numerical (or artificial) diffusion may cause large errors. Moreover, when the Péclet number is large, a numerical code without some stabilising techniques produces oscillating solutions. Upwind schemes increase the stability but show more numerical diffusion. In this paper we quantify the numerical diffusion for the different discretization schemes and its dependency on the Péclet number. We consider an academic example and a realistic simulation of solute transport in heterogeneous aquifer. In the latter case, the stochastic estimates used as reference were obtained with global random walk (GRW) simulations, free of numerical diffusion. The results presented can be used by researchers to test their numerical schemes and stabilization techniques for simulation of contaminant transport in groundwater.     

Patterns of rare earth and other trace elements in different size fractions of clays of Campanian–Maastrichtian deposits from the Portuguese western margin (Aveiro and Taveiro Formations)

The Upper Cretaceous (Campanian–Maastrichtian) Taveiro and Aveiro Formations belong to the northern sector of the Lusitanian basin (Portuguese western margin). The Taveiro Formation was deposited in alluvial fans, including mud flow beds, lakes and sinuous rivers. The Aveiro Formation was deposited in a flat region with low hydrodynamics channels, with the formation of a barrier island-tidal system. The reconstruction of this sedimentary basin may be difficult due to its complex architecture. This work aims a methodology to be used in the reconstruction of Cretaceous sedimentary environments of the Lusitanian basin, through the establishment of geochemical patterns of different size fractions of those deposits. Chemical analysis was performed by instrumental neutron activation analysis (INAA), and the mineralogical composition obtained by X-ray diffractometry (XRD). The whole rock and different size fractions (? ≥ 125 μm, 63–125 μm, 20–63 μm, 2–20 μm and ? < 2 μm) of selected samples were studied aiming the rare earth elements (REE) and other trace elements distribution and its correlation with the grain size and mineralogy.The results obtained for the studied Cretaceous sediments showed that REE patterns and other trace elements distribution in the different size fractions may be used as a tool to differentiate deposits within and between sedimentary formations. Within the Taveiro Formation, REE are concentrated in the silt fractions (20–63 μm and 2–20 μm) of the Reveles deposit, and in the clay size fraction of S. Pedro deposit, which is richer in kaolinite. The 1st transition elements, particularly Zn, are correlated with the presence of smectite in the clay fraction of Reveles deposit. In the sand and silt size fractions (>2 μm) of samples from Taveiro Formation correlations were found between: Ga and 1st transition elements, and phyllosilicates; Cs and mica; and Rb and Ba, and K–feldspars.The Bustos deposit (Aveiro Formation) samples are very fine-grained and with a high proportion of the fine silt fraction where REE are concentrated, especially the heavy ones. Incorporation of MREE, Co and U in carbonates of the coarser fraction appears to occur. The abundances of the 1st transition elements, Ga and As, are correlated with phyllosilicates.Significant differences were found in the trace elements patterns of the various analysed size fractions of the Lusitanian basin of Cretaceous sediments, between and even within formations, which can be used as a methodological approach for a fine paleogeographic reconstruction.     

碳酸盐沉积物的成岩作用

化学沉淀碳酸盐矿物在沉积后很容易受到各种作用的影响,其中最重要的是其在成岩阶段所经历的成岩作用.碳酸盐沉积物在成岩过程中主要受大气降水、海水和埋藏过程中孔隙流体的控制,经历一系列压实、溶解、矿物的多相转变、重结晶、胶结等成岩作用,逐渐转变为固结的岩石.在成岩过程中,由于孔隙流体与沉积流体之间的异同以及温度的变化,碳酸盐沉积物的原始矿物成分、地球化学特征可能会很好的保存下来,但在许多情况下,也可能会改变,从而使我们无法准确反演碳酸盐沉积物在沉积时水体的特征.因此,我们在应用碳酸盐岩重建相关古环境和古气候变化的时候,必须要通过有效的方法来对碳酸盐岩是否受到成岩作用的影响进行鉴定.     

宁夏中奥陶统香山群徐家圈组大地构造环境分析

宁夏香山群为一套遭受轻微区域变质的陆源碎屑岩,并夹有少量碳酸盐岩和硅质岩,属于深水浊流沉积,从下到上可分为徐家圈组、狼嘴子组和磨盘井组。长期以来对香山群的研究主要集中在时代探讨上,而在其他方面较薄弱。本文以徐家圈组为主要研究对象,从浊积砂岩的碎屑颗粒类型百分含量、常量元素和微量元素等方面对其沉积时的大地构造环境进行了综合研究。结果表明:碎屑颗粒类型显示出典型的被动大陆边缘;常量元素的判别则出现了不确定性;微量元素则显示出了过渡性质。因此,香山群徐家圈组沉积时大地构造环境可能不是简单的被动大陆边缘,其物源极有可能来自被动大陆边缘、活动大陆边缘和大陆岛弧之间的带有过渡性质的源区。     

中国南方地区水系沉积物中元素丰度

从中国南方12个省自治区230万km2面积上所采集的水系沉积物中按每1∶5万图幅一个组合样的密度组合成5 244件组合样,采用以ICP-MS、ICP-AES和XRF为主的先进的分析测试方法和严格的质量控制方法,准确测试了其中的76种元素。统计计算了中国南方地区76种元素的平均值,给出了中国南方地区水系沉积物中76种元素...