华北克拉通南缘石炭系本溪组铁-铝黏土矿物质来源: 以河南三门峡大安铝黏土矿床为例*

华北克拉通在中奥陶世至晚石炭世期间一直出露地表,经历了长期的风化作用,形成大规模的铁-铝黏土矿,其成矿物源一直是研究的热点,尤其是本溪组底部铁矿和铁质黏土矿与上部铝黏土矿是否为同一来源尚未查清。本研究选取克拉通南缘大安铝黏土矿床作为研究对象,展开微区矿物及元素地球化学组成分析,进一步探讨铁-铝黏土矿物质来源。大安矿床内含矿岩系自下而上包括铁质黏土岩、铝土矿、铝质黏土矿;局部喀斯特高地缺失铝土矿,铝质黏土矿直接覆盖于铁质黏土岩之上。铁质黏土岩在洼地以菱铁矿、黄铁矿和伊利石为主,在隆起区以赤铁矿、伊利石和高岭石为主。铝土矿以硬水铝石、伊利石和锐钛矿为主;铝质黏土矿主要矿物为伊利石。矿物微区分析在黏土矿底部发现大量的碳化硅和少量自然硅、硅铁矿、铬铁矿;区域对比揭示北秦岭造山带内商丹缝合带和二郎坪群中的蛇绿岩为铝黏土矿形成提供了成矿物质。本溪组底部铁质黏土与上部铝黏土矿稳定元素比率(例如Zr/TiO₂、Hf/TiO₂、Nb/TiO₂、Ta/TiO₂)存在明显差异,揭示二者为不同来源: 底部铁质黏土岩和铁矿层为底板碳酸盐岩原地风化的产物;而上部铝黏土矿是异地搬运物,北秦岭造山带在晚石炭世的整体抬升为华北铝黏土矿形成提供了重要的成矿物质。     

Distribution of platinum-group elements in the Platreef at Overysel,northern Bushveld Complex: a combined PGM and LA-ICP-MS study

Detailed mineralogical and laser ablation-inductively coupled plasma-mass spectrometry studies have revealed the physical manifestation of the platinum-group elements (PGE) within the Platreef at Overysel, northern Bushveld Complex, South Africa. The PGE in the Platreef were originally concentrated in an immiscible sulfide liquid along with semi-metals such as Bi and Te. As the sulfide liquid began to crystallize, virtually all the Os, Ir, Ru and Rh partitioned into monosulfide solid solution (mss), which on further cooling, exsolved to form pyrrhotite and pentlandite with Os, Ir and Ru remaining in solid solution in both phases with Rh prefentially partitioning into pentlandite. Platinum, some Pd and Au were concentrated in the residual sulfide liquid after mss crystallization, and were then concentrated in an immiscible late stage melt along with semi metals, which was expelled to the grain boundaries during crystallization of intermediate solid solution (iss) to form Pt and Pd tellurides and electrum around the margins of the sulfide grains. Tiny droplets of this melt trapped in the crystallizing mss and iss cooled to form Pt–Bi–Te microinclusions in all sulfide phases, whilst the excess Pd was accommodated in solid solution in pentlandite. Minor redistribution and recrystallization by hydrothermal fluids occurred around xenoliths and at the very base of the mineralized zone within the footwall, however, the overall lack of secondary alteration coupled with the volatile-poor nature of the gneissic footwall have allowed the preservation of what may be the most ‘primary’ style of Platreef mineralization. The lack of PGM inclusions within early liquidus phases suggests very early sulfur saturation in the Platreef, lending support to theories involving S saturation occurring prior to intrusion of the Platreef, possibly within a staging chamber.     

云南都龙超大型锡锌多金属矿床中闪锌矿微量及稀土元素地球化学特征

云南马关都龙锡锌多金属矿床位于滇东南老君山锡锌钨多金属成矿区南部,是我国三大锡石硫化物矿床之一,目前对其矿床成因认识存在较大分歧。本文采用ICP-MS对都龙矿床中闪锌矿微量元素及稀土元素组成进行分析,以探讨该矿床成矿作用,为甄别已有成因观点提供证据。结果表明,矿床中闪锌矿以富集Fe、Mn、In、Co、Sn和贫Cd、Ga、Ge、Ni等元素为特征,成矿温度属于中—高温,其微量元素组成与白牛厂矿床(与燕山晚期花岗岩有关的矽卡岩型矿床)中的闪锌矿非常相似,和远源矽卡岩型铅锌矿床(核桃坪和芦子园)中闪锌矿存在一定差异,明显有别于喷流沉积型铅锌矿床(云南澜沧老厂和广东大宝山)中闪锌矿。此外,该矿床闪锌矿稀土配分模式多为轻稀土元素富集中等的向右倾斜曲线,以LREE/HREE值高、Eu负异常明显和Ce异常不明显为特征,与矿区燕山晚期隐伏花岗岩稀土元素特征基本一致,成矿物质来源以矿区燕山晚期隐伏花岗岩为主。结合近期矿山开采和地质勘探所揭露的矿化和矽卡岩蚀变的垂向分带等矿床地质特征,认为云南马关都龙锡锌多金属矿床属于与燕山晚期花岗岩有关的矽卡岩型多金属矿床,其中层状矽卡岩的形成应为成矿流体顺层交代的结果,矿化类型和围岩蚀变的分带与隐伏岩体的距离有关。     

北大别白垩纪镁铁－超镁铁岩的铂族元素地球化学研究

采用镍锍火试金法结合ICP-MS分析了12个北大别白垩纪镁铁-超镁铁岩样品的Ir,Ru,Rh,Pt和Pd的含量,结果显示铂族元素（PGE）的含量较低,原始地幔标准化后的PGE分布模式呈正斜率型,PPGE相对原始地幔略微亏损,而IPGE强烈亏损,Pd/Ir值远高于相应的地幔比值。这些镁铁-超镁铁岩中PGE的强烈分异是地幔低程度的部分熔融过程中,PPGE主要受硫化物控制,而Ir则存在于非硫化物相如尖晶石,可能还有合金之中造成的。同时,铂族元素的分布特征表明这些镁铁-超镁铁岩是岩浆结晶分异的产物。     

微波等离子体原子发射光谱法测定偏远矿区海泡石中的主微量元素

海泡石是具有层状结构的含水富镁硅酸盐黏土矿物,其中无机元素含量是揭示其成矿物质来源、成矿流体性质和矿床成因的重要依据,通常采用电感耦合等离子体发射光谱/质谱法（ICP-OES/MS）进行测定,等离子体（ICP）的高温激发会产生成大量谱线干扰,维持ICP稳定工作需使用高纯氩气,持续供气对于偏远矿区海泡石的检测还将面对气体采购和运输不便的问题。本文基于微波等离子体原子发射光谱（MP-AES）的低温激发技术减少光谱干扰,建立了准确测定偏远矿区海泡石中主量元素Mg、Al、Ca、Fe、K、Na和微量元素Cu、Zn、Mn、Pb含量的分析方法。利用硝酸-盐酸-氢氟酸混合酸对海泡石进行微波消解,避免了样品处理过程中分析元素的损失,加快了样品处理速度,同时提高了样品溶液的稳定性。通过选择各元素光谱线的分析波长,并利用快速线性干扰校正（FLIC）技术校正光谱干扰,以Lu为内标元素校正基体效应,提高了灵敏度和准确度。各元素的检出限为0.19~14.6μg/L。海泡石国家标准物质（GBW07138）各元素测定值与认定值的相对误差在-5.0%~6.7%之间。本方法具有检出限低、线性范围宽、结果准确等优点;MP-AES采用自带的氮气发生器为等离子体提供氮气作为工作气,无需引入复杂气体,提高了分析效率,尤其适用于气体采购和运输不便的偏远矿区。     

新疆岩石·岩屑·水系沉积物元素背景平均值

论证了中国丰度及地壳表层物质成分研究的必要性和重要性，利用区域地球化学勘查所提供的高精度分析数据，经严格统计计算，发表新疆地区其一级构造单元表层岩石、岩屑、水系沉积物的39种元素背景平均值。     

长江经济带土壤质量评价及产地适宜性初步研究

开展土壤质量评价对科学划定永久基本农田及统筹优化农业生产布局具有重要指导意义。本文采用内梅罗综合污染指数法、分级法、累积频率法和综合判定法,参照《土壤环境质量农用地土壤污染风险管控标准》(试行)(GB 15618—2018)和《绿色食品产地环境质量》(NY/T 391—2013),对长江经济带土壤重金属污染、酸碱度、有益元素丰缺和绿色农产品产地适宜性进行评价。研究区土壤质量总体良好,清洁土壤面积34.84万km²,其重金属含量继承了自然背景特征; 三级及以下土壤面积6.94万km²,呈斑块及星点状分布于赣东北、赣南、湖南长沙—郴州一带、沿江及贵阳、昆明等地,其重金属为自然富集或受矿业开发、煤炭和石油的燃烧及工业“三废”排放的影响。酸性土壤面积33.56万km²,分布于江西、湖南、宁波—台州沿海和金华衢州盆地,碱性土壤面积15.69万km²,分布于苏北平原、环洞庭湖、成都平原以及沿长江一线,其土壤酸碱度与土壤类型有关。土壤有益元素丰缺与第四系沉积物成土母质有关,土壤有益元素适量及以上区域面积34.44万km²,分布于四川阿坝、成都盆地、环洞庭湖、环鄱阳湖、安徽沿江、苏北沿海和杭嘉湖平原; 土壤有益元素缺乏区面积13.89万km²,分布于赣南、江淮、鄂东北以及云南玉溪等地。绿色农产品产地最适宜区、适宜区和不适宜区面积分别为22.49万km²、18.78万km²和18.28万km²。依据区内绿色农产品产地适宜性、土壤环境质量和立地条件划分出7片永久农田保护建议区。     

Metamorphic zircon formation by solid-state recrystallization of protolith igneous zircon

Protolith zircon in high‐grade metagranitoids from Queensland, Australia, partially recrystallized during granulite‐grade metamorphism. We describe the zircon in detail using integrated cathodoluminescence, U–Pb isotope, trace element and electron backscatter diffraction pattern (EBSP) analyses. Primary igneous oscillatory zoning is partially modified or obliterated in areas within single crystals, but is well preserved in other areas. A variety of secondary internal structures are observed, with large areas of transgressive recrystallized zircon usually dominant. Associated with these areas are recrystallization margins, interpreted to be recrystallization fronts, that have conformable boundaries with transgressive recrystallized areas, but contrasting cathodoluminescence and trace element chemistry. Trace element analyses of primary and secondary structures provide compelling evidence for closed‐system solid‐state recrystallization. By this process, trace elements in the protolith zircon are purged during recrystallization and partitioned between the enriched recrystallization front and depleted recrystallized areas. However, recrystallization is not always efficient, often leaving a ‘memory’ of the protolith trace element and isotopic composition. This results in the measurement of ‘mixed’ U–Pb isotope ages. Nonetheless, the age of metamorphism has been determined. A correlation between apparent age and Th/U ratio is indicative of incomplete re‐setting by partial recrystallization. Recrystallization is shown to probably not significantly affect Lu–Hf ages. Recrystallization has been determined by textural and trace element analysis and EBSP data not to have proceeded by sub‐grain rotation or local dissolution/re‐precipitation, but probably by grain‐boundary migration and defect diffusion. The formation of metamorphic zircon by solid‐state recrystallization is probably common to high‐grade terranes worldwide. The recognition of this process of formation is essential for correct interpretation of zircon‐derived U–Pb ages and subsequent tectonic models.     

井冈山森林火灾与气象条件的相关分析

根据江西井冈山森林火灾资料,利用一元回归和逐步回归分析方法,对井冈山1991—2000年森林火灾发生期间的连旱日数、降水量、相对湿度、气温、风速5个主要气象指标进行分析,将各指标分别与火灾发生次数、森林受害面积进行回归计算,建立了利用连旱日数和降水量预测森林火灾受灾面积及发生次数的数学模型。模式运算结果表明,当火灾发生前15 d连旱日数增加时,火灾次数增加;当火灾发生前15 d连旱日数增加、降水量减少时,火灾面积增加。     

宜春地区三类典型天气的风廓线雷达产品特征分析

选取江西省宜春市晴空、弱降水、强降水三类天气过程个例,结合天气形势、雷达回波、气象要素等资料,对比分析了风廓线雷达产品特征。结果表明：（1）在晴空天气背景下,风廓线雷达探测高度低,水平风速小,垂直风速正负值交替出现,大气折射率结构常数（Cn2）值最小。（2）在稳定性弱降水天气背景下,大气呈稳定状态,风廓线雷达探测高度随降水的产生而逐渐抬升,高低层有明显的风速切变,850 hPa赣南至赣东北有西南急流穿过,赣北有切变线存在,利于降水产生,垂直风速因降水影响出现朝向雷达正速度,Cn2值比晴空时大。（3）在具有产生强对流天气背景下,大气中对流强烈,风廓线雷达的水平风速增大,西南急流深厚且不断下沉,850-700 hPa有强烈的垂直切变,动力条件和水汽条件利于强降水产生,垂直风速表现为更大的朝向雷达正速度,Cn2值比弱降水时的大。