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351.
Jozef Guba 《Mathematical Geology》1986,18(4):429-432
Distribution of chemical elements in nature is controlled by the general physical-chemical state of natural processes, a result of the effort to reach thermodynamic equilibrium. Natural processes, forming geologic objects (e.g., rocks, ores) usually do not reach total chemical equilibrium. This is reflected in distributions of chemical elements in nature. We recognize symmetric as well as asymmetric distributions. The question arises, what distribution in nature is most commonly followed? Evidently, this should be a distribution of chemical elements in thermodynamic equilibrium throughout the system, thus with maximum entropy. This paper notes that Gauss's normal distribution may be derived from statistic explanation of entropy as a function of contnt of chemical elements in a system with application of Einstein's formula. 相似文献
352.
Multiple regression analyses indicate that the most important factors controlling Ag, Cd, Co, Cu, Pb and Zn concentrations in the estuarine bivalve Scrobicularia plana and the polychaete Nereis diversicolor are the concentrations of these metals in surface sediments and the partitioning of sediment-bound metals between different sediment constituents. Extraction of the sediments with 1-n HCl provides more information about the bioavailability of the metals than do extractions with five other techniques. Biologically available Cd and Co in solution contribute significantly to Cd and Co concentrations in both Scrobicularia and Nereis. Concentrations of Ag in Scrobicularia are reduced where Cu concentrations in sediments are high. An unexplained increase in concentrations of Cu in Scrobicularia at specific stations in six estuaries suggests that under certain very anoxic conditions the availability of copper may be exceptionally high. 相似文献
353.
Marc Stoffyn 《Estuarine, Coastal and Shelf Science》1984,18(4):433-445
Concentrations of the trace elements Fe, Al, Mn, Cu, Cd, Zn and Ni were measured in shallow vertical profiles (maximum depth 500 m) off the Scotian Shelf in the western North Atlantic. The distributions of the trace elements show variations with depth, the most consistent of which are for Fe and Zn. A minimum concentration near the surface followed by an increase with depth is attributed to in situ mechanisms. 相似文献
354.
The computer program PHREEQC was used to determined the distribution, chemical speciation and mineral saturation indices in a fresh groundwater environment with limited mining activities in the adjoining areas. The aim was mainly to determine the potential risk of a coastal plain aquifer contamination by some potentially toxic elements. The results show that the elements Ba, Cd, Cu, Fe, Mn, Ni, Rb, Sr, and Zn are distributed as free metal ions. Arsenic is in the neutral form of H3AsO3
o, while three species of aluminium [Al3+, AlOH2, Al(OH)2 +] dominate. The major species of uranium include UO2CO3, UO22++, UO2+, and UO2OH+,
respectively, in order of abundance. The groundwater is saturated with respect to alunite [KAl3
(SO4)2
(OH)6], basaluminite [Al4
(OH)10 SO4], boehmite [Al(OH)], Cu metal (Cu), cuprous ferrite (CuFeO2), diaspore [AlO(OH)], gibbsite [Al(OH)3], goethite (FeOOH), hematite (Fe2O3), magnetite (Fe3O4) and uraninite (UO2). Most of the species are not mobile under the prevailing pH (3.3 to 5.9) and Eh (7 to 158 mV) conditions. The mobile ones are very low in concentration and will be immobilized by precipitation of mineral phases. The study concludes that presently these species do not pose any risk to the aquifer. 相似文献
355.
Medium-temperature thermal waters in the Mura basin occur in hydrogeological systems different in age, burial depth, temperature, porosity and permeability, and the presence of free carbon dioxide which penetrates through the fractures from pre-Tertiary basement. The waters commonly belong to sodium-bicarbonate hydrogeochemical facies, but may have significantly different amounts of total dissolved solids, including trace elements. Thermal waters occurring in low-permeable, well-compacted and moderately fractured Tertiary sediments older than Upper Pliocene are the richest in trace elements, although their abundance may be very variable from one aquifer to another. The ratios of major alkaline and alkaline earth elements (Na, K, Ca) and trace elements (Li, Rb, Cs, Ba, Sr) commonly show relative enrichment in highly mineralised waters with respect to the waters with lower mineralisation. Rare earth elements (REEs) and Y show only minor fractionation in the highly mineralised waters, whereas in the waters with lower mineralisation strong fractionation of heavy rare earth elements (HREEs) over light rare earth elements (LREEs) occurs, along with a pronounced positive europium anomaly. Positive Th/U ratios are commonly observed, although both actinide elements occur in the range of some hundredths of ppb to some ppb. Trace elements were particularly useful in the study of well cycling in two hydraulically interconnected geothermal wells in the town of Murska Sobota, which produce a mixture of low- and high-mineralised waters. 相似文献
356.
WANG Yuwang WANG Jingbin WANG Lijuan WANG Yong TU Caineng Beijing Institute of Geology for Mineral Resources Beijing Key Laboratory of Mineral Resources Research Institute of Geology Geophysics Chinese Academy of Sciences Beijing Xinjiang Kalatongke Cu-Ni Mine Fuyun Xinjiang 《《地质学报》英文版》2004,78(2):396-403
On the basis of the study on the REE geochemistry of the ore minerals and host rocks of the Kalatongke Cu-Ni deposit, Xinjiang, it is indicated that the major ore minerals, sulfides, were sourced from the host mafic-ultramafic magma. Characterized by low REE content of sulfide, such a Cu-Ni sulfide deposit occurring in the orogen is obviously different from that on the margin of the craton. Because the mafic-ultramafic rocks from the Cu-Ni sulfide deposit occurring in the orogen is water-rich and the REEs of some sulfides show a particular "multiple-bending" pattern, which suggests coexistence of multiple liquid phases (fluid and melt), the sulfide melt possibly contains a great deal of hydrothermal fluids and increasingly developed gases and liquid-rich ore-forming fluids after the main metallogenic epoch (magmatic segregation stage). 相似文献
357.
Joseph A. Shacat William J. Green Eric H. Decarlo Silvia Newell 《Aquatic Geochemistry》2004,10(3-4):325-352
Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3 O4 ). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters. 相似文献
358.
Geochemical Constraints on the Origin of Volcanic Rocks from the Andean Northern Volcanic Zone, Ecuador 总被引:2,自引:0,他引:2
BRYANT J. A.; YOGODZINSKI G. M.; HALL M. L.; LEWICKI J. L.; BAILEY D. G. 《Journal of Petrology》2006,47(6):1147-1175
Whole-rock geochemical data on basaltic to rhyolitic samplesfrom 12 volcanic centers are used to constrain the role of continentalcrust in the genesis of magmas formed beneath the anomalouslywide subduction-related volcanic arc in Ecuador. Relativelyhomogeneous, mantle-like, isotopic compositions across the arcimply that the parental magmas in Ecuador were produced largelywithin the mantle wedge above the subduction zone and not byextensive melting of crustal rocks similar to those upon whichthe volcanoes were built. Cross-arc changes in 143Nd/144Nd and7/4Pb are interpreted to result from assimilation of geochemicallymature continental crust, especially in the main arc area, 330360km from the trench. Mixing calculations limit the quantity ofassimilated crust to less than 10%. Most andesites and dacitesin Ecuador have adakite-like trace element characteristics (e.g.Y <18 ppm, Yb <2 ppm, La/Yb >20, Sr/Y >40). Availablewhole-rock data do not provide a clear basis for distinguishingbetween slab-melting and deep crustal fractionation models forthe genesis of Ecuador adakites; published data highlightinggeochemical evolution within individual volcanoes, and in magmaticrocks produced throughout Ecuador since the Eocene, appear tosupport the deep fractionation model for the genesis of mostevolved Ecuadoran lavas. A subset of andesites, which displaya combination of high Sr (>900 ppm), Nd >4·1 and7/4Pb <6·0, appear to be the best candidates amongEcuador lavas for slab-melts associated with the subductionof the relatively young, over-thickened, oceanic crust of theCarnegie Ridge. KEY WORDS: andesite; Ecuador; trace elements; isotopes; adakite 相似文献
359.
360.