章丘大葱特征元素农业地球化学研究

以章丘大葱产区生态地球化学调查为基础,采集了表层土壤、大葱、根系土及出露的代表性岩石样品,实测了大量和微量营养元素的含量,查明了研究区土壤地球化学背景。通过计算大葱对土壤营养元素的吸收率及大葱品质与营养元素的相关性分析,查明了大葱生长的特征营养元素为N,K2O,Zn,B,P,Cu,Mn。在岩石-土壤-大葱这一生态体系中,营养元素在土壤中保持一定的储备和积累,为大葱的生长提供了有利的农业地球化学环境。     

滇西马厂箐铜钼多金属矿床成矿流体来源及演化过程——来自石榴子石原位微量元素及H- O同位素组成的限定

滇西马厂箐铜钼多金属矿床位于三江特提斯成矿域,是一个与喜马拉雅期富碱斑岩侵入有关的多金属矿床。前人研究表明,马厂箐铜钼多金属矿床形成于斑岩-矽卡岩成矿系统,但由于缺乏系统矿物学研究,目前对矽卡岩矿化过程和成矿效应仍不清楚,限制了对该矿床成矿过程的全面认识。因此,本文以马厂箐矿床矽卡岩型矿化中的石榴子石为研究对象,利用H-O同位素、电子探针(EPMA)以及LA-ICP-MS原位微区技术开展了同位素及成分分析,限定成矿流体来源以及反演成矿流体演化过程。石榴子石可分为早期自形石榴子石(Grt I)和晚期他形石榴子石(Grt II)。Grt I与辉石共生,并伴有黄铁矿、黄铜矿等金属矿物组合,属于钙铝-钙铁榴石固溶体(And_{49.37～99.58}Gro_0～49.79);Grt II更富Fe,属钙铁榴石系列(And_{67.50～99.85}Gro_0～31.84)。两期石榴子石均富含Th、U、Nd,亏损Ba、Sr、Hf、Nb,富轻稀土。基于石榴子石矿物化学特征认为,Grt I可能是在弱酸性、氧化、低水岩比(W/R)条...     

The PISA grammar decodes diverse human–environment approaches

Human–environment interactions are studied by several groups of scholars who have elaborated different approaches to describe, analyze, and explain these interactions, and eventually propose paths for management. The SETER project (Socio-Ecological Theories and Empirical Research) analyzed and compared how “flag-holders” of distinct school of thought in human–environment scholarship approached a number of empirical problems of environmental management. This paper presents the findings from this experiment by concentrating on how representatives of four schools of thought approached one of these case studies: the plant health crisis in greenhouse tomato production in south of France. Our analysis suggests that these approaches share a common conceptual vocabulary composed of four explanatory elements of change (Power, Incentives, System and Adaptation-PISA). We argue that what distinguishes these schools from one another is the syntax—the “rules” by which researchers in each of the sub-disciplines tend to organize the components of this shared conceptual vocabulary. In other words, the schools under scrutiny are differentiated not so much by what they speak of, but rather in what order, or hierarchy, do they tend to rank the importance and/or the sequence of each of these concepts in human–environment explanations. The results of our experiment support the view that communication and cooperation across the diverse human–environment traditions is possible and productive. At the same time, however, we argue that it is the distinctiveness of the claims yielded by these different schools of thought that augment our collective understanding of complex socio-ecological problems. Attempts to integrate these perspectives in one unitary approach would undermine the intellectual wealth necessary to meet the challenges of the Anthropocene.     

Stable Isotopes and Halogen Geochemistry of the Huayuan Carbonate-hosted Pb-Zn Ore District, South China: Implications for the Salt Source of Ore-forming Fluids

The Huayuan Pb-Zn ore district in China, located in western Hunan Province, is a giant carbonate-hosted Pb-Zn ore district. The source of ore-forming brines in this ore district remains poorly constrained. Whether the highly saline brines are derived from evaporated seawater or dissolved evaporates continues to be intensely debated. Carbonate minerals associated with Pb-Zn mineralization have δ13CV-PDB and δ18OV-SMOW values ranging from ?5.55‰ to +1.35‰ (mean value of ?0.69‰; n = 14) and +16.28‰ to +25.05‰ (mean value of +20.22‰; n = 14), respectively. This indicates that carbonate minerals are dominantly formed from dissolved ore-hosted carbonate rocks. The δ34S values of sulfides range from +20.2‰ to +36.8‰, with an average value of +30.0‰ (n = 27). These results suggest that sulfur is predominantly derived from the thermochemical sulfate reduction of marine sulfate. The crush-leach analyzed solute data of fluid inclusions in sphalerite show the ore-forming fluids have Cl/Br molar ratios range from 118 to 384, and Na/Br molar ratios from 39 to 160 (n = 8). These Cl/Br ratios of hydrothermal fluid are much lower than those of seawater (657 to 564), but are consistent with bittern brines through early halite precipitation. We propose that ore-forming fluids are mainly derived from evaporitic basin brines, which leached base metals from the basement and/or country rocks. The brine then migrated to the basin margins through clastic rocks of basement and then precipitated sul?des by thermochemical sulfate reduction.     

地壳全元素探测——构建“化学地球”

地壳物质探测是地壳探测工程的重要组成部分。化学元素是地球物质组成的最基本单位,被称为地球的基因。矿产资源是由化学元素组成的,环境是受化学元素行为制约的,因此,对地壳中所有元素精确含量和分布的探测,对解决人类所面临的资源和环境问题具有重大意义。地壳全元素探测项目拟发展4种地球化学探测技术,包括地壳中所有天然元素的精确分析技术,中下地壳物质成分识别技术,穿透性地球化学探测技术,海量地球化学数据和图形显示技术。建立1个覆盖全国的地球化学基准网,系统采集代表性岩石样品10000件,疏松物样品6000件,按标准化的方法分析其主量元素和微量元素含量(包含78种元素),建立中国大陆地球化学基准值,为研究化学元素的分布、演化和成矿物质背景提供基准参考数据。进行总长度3300km的3条地球化学走廊带的实验与示范,采集各类代表性岩石样品5000件,进行元素和同位素测定,构建走廊带地壳地球化学模型、跨越不同大地构造单元的元素空间变化和大型矿集区成矿物质背景。为开展全国地壳探测工程奠定基础,并为最终建立"化学地球"进行技术准备和先导性实验。     

基于Mohr-Coulomb准则的喷粉桩静载实验与三维数值模拟

在土建、交通、水利等工程建设中利用喷粉桩来处理软弱地基,被称为是经济、快速、有效实用的方法。结合南京四桥桩基施工工程,对工程中所用到的喷粉桩进行静荷载试验,并采用三维有限元数值模拟的方法对单桩复合地基进行数值计算,所得计算结果与实验数据基本吻合。     

A practical co-simulation approach for multiscale analysis of geotechnical systems

The particulate nature of granular soils can be accurately simulated at a microscale level. However, due to the huge spatial extent of geotechnical systems, a model fully constructed at such a scale is almost impossible with current computing technologies. Hence, continuum-based approaches are considered as the practical scale for modeling the majority of problems. Combining both scales enables benefiting from the advantages of both techniques while trying to overcome their drawbacks. Although a significant number of publications have addressed coupling both scales, only a few provide information regarding implementing the proposed procedures. In this study, an efficient co-simulation framework for conducting multiscale analysis is introduced. The framework is based on integrating existing continuum and micromechanical modeling software packages and therefore benefitting from already existing codes. A computational simulation of a rigid pile in contact with granular soil demonstrating the capabilities of such technique is presented. The near-field zone surrounding the pile is modeled using DEM whereas FEM is utilized to model far-field zones that are not affected by the presence of the pile. Results of conducted simulations resemble those obtained from experimental results. The proposed approach appears to be a very effective and promising tool to model boundary value problems of geotechnical systems.     

Selenium and other trace element in phosphorites: A comparison between those of the Bayovar-Sechura and other provenances

Data of trace element composition of phosphorites are scarce and incomplete. Phosphorites of different origins can vary substantially in trace element contents. In this paper 20 trace element concentrations of 35 sample phosphorites are reported. The geographical provenance is: Bayovar-Sechura (Peru), Khouribga, Youssoufia and Boucraa (Morocco), Gafsa (Tunisia), Florida (USA), Idaho and Phosphoria Formation (USA), North Carolina (USA), Algeria, Israel, Senegal, Syria and Togo. Aqua regia extracts were used to estimate the “pseudototal” values, following standard procedures (ISO 11466, 2002) and measured by ICP-AES and ICP-MS.     

The chemistry of bottled mineral and spring waters from Norway,Sweden, Finland and Iceland

Twenty-two bottled mineral and spring waters from Norway, Sweden, Finland and Iceland have been analysed for 71 inorganic chemical parameters with low detection limits as a subset of a large European survey of bottled groundwater chemistry (N = 884). The Nordic bottled groundwaters comprise mainly Ca–Na–HCO₃–Cl water types, but more distinct Ca–HCO₃, Na HCO₃ and Na–Cl water types are also offered. The distributions for most elements fall between groundwater from Fennoscandian Quaternary unconsolidated aquifers and groundwater from Norwegian crystalline bedrock boreholes. Treated tap waters have slightly lower median values for many parameters, but elements associated with plumbing have significantly higher concentrations in tap waters than in bottled waters. The small dataset is able to show that excessive fluoride and uranium contents are potential drinking water problems in Fennoscandia. Nitrate and arsenic displayed low to moderate concentrations, but the number of samples from Finland and Northern Sweden was too low to detect that elevated concentrations of arsenic occur in bedrock boreholes in some regions. The data shows clearly that water sold in plastic bottles is contaminated with antimony. Antimony is toxic and suspected to be carcinogenic, but the levels are well below the EU drinking water limit. The study does not provide any health-based arguments for buying bottled mineral and spring waters for those who are served with drinking water from public waterworks. Drinking water from crystalline bedrock aquifers should be analysed. In case of elevated concentrations of fluoride, uranium or arsenic, most bottled waters, but not all, will be better alternatives when treatment of the well water is not practicable.     

Chemical composition of bottled mineral waters in Estonia

Five commercially available in Estonia brands of bottled water have been analysed for 59 chemical elements by ICP-QMS and ICP-AES techniques to assess the quality of domestic mineral waters in scope of the European Groundwater Geochemistry Project initiated by the Geochemistry Expert Group of EuroGeoSurveys. Contents of 9 cations and anions, pH and electrical conductivity (EC) were measured in the bottled mineral waters by IC, titration and photometric methods. The data showed a significant difference between natural undiluted mineral water (Värska Originaal) characterised by the highest values of pH, EC and majority of trace elements studied, and other domestic waters sold in Estonia.