利用高频地震波检测混凝土构件完整性的方法

大型混凝土构件（如高层建筑基础的地梁,桩承台等）在施工过程中可能造成局部松散,空洞,蜂窝或离析等质量问题。为检测混凝土构件的的完整性,采用地震勘探方法中的地震映象法（又称地震共偏移距法）。通过在模拟裂缝,空洞模型上的试验,获得了存在异常体时,地震映象时间剖面的波形特征;测得偏移距,点距等参数变化时,对地震映象时间剖面的影响。模型实验和实测工作证明;在合理选择震源各种测量参数条件下,高频地震映象方法可有效检测混凝土构件完整怀,实现对混凝土构件质量新的监测。     

土壤污染地球化学标准及等级划分问题讨论

全国多目标区域地球化学调查发现有害元素广泛分布引起极大关注。土壤污染将长期危及生态系统和人类生存安全。制定土壤污染等级标准十分重要。国家土壤环境保护标准体系中,土壤污染等级标准是针对调查发现的污染进行量度划分,土壤环境质量标准是依据污染对环境影响程度确定临界值,土壤污染评价标准是针对存在问题进行科学研究的指标。土壤污染等级采用统一的分级标准,划分为国家级、流域级、省级和地市级。标准制定是一个由局部到全局的认识,又由全局到局部的决策过程。在多目标区域地球化学调查基础上首先制定土壤污染标准及划分污染等级是笔者的主导思想。     

视觉测量中相机外参数近似值的快速求解

提出了利用3个不共线的控制点对相机外参数近似值进行快速求解的一种方法.利用3个控制点与其像坐标间的几何关系求得3个控制点在摄站坐标系下的坐标;由控制点的已知控制坐标与求得的摄站坐标系下的坐标,进一步求得两坐标系的转换参数的初值;通过解析法或光束法对相机外参数用初值进行精确标定.并通过一组模拟数据验证了该方法的正确性.     

视觉测量中相机外参数近似值的快速求解

提出了利用3个不共线的控制点对相机外参数近似值进行快速求解的一种方法。利用3个控制点与其像坐标间的几何关系求得3个控制点在摄站坐标系下的坐标;由控制点的已知控制坐标与求得的摄站坐标系下的坐标,进一步求得两坐标系的转换参数的初值;通过解析法或光束法对相机外参数用初值进行精确标定。并通过一组模拟数据验证了该方法的正确性。     

Research on the Effects of the Contents of Radioactive Elements on Granularity and Climate Change： An Example of SZK1 and SZK2 Drill Holes Strata in the Fuzhou Basin

INTRODUCTIONFuzhou basin is a faulted basin developed during the mid-late Quaternary,filled with marine ,terrestrial and alternating marine-terrestrial facies sediments (Lin,1979 ;Lan,et al .,1986 ; Han,etal .,1992 ;Ding,et al .,1992 ; Wang,et al .,2000 ; Wang,et al .,2002) .Inthe basin,concealedfaults are distributed. With the support of a project entitled“Testing exploration of active fault inurban area”of the National Development and ReformCommission,two drill holes (SZK1 and S…     

贵州大方煤田主采煤层的矿物学异常及其对元素地球化学的影响

运用电感耦合等离子体质谱(ICP-MS)、X射线荧光光谱(XRF)、带能谱仪的扫描电镜(SEM-EDX)、逐级化学提取(SCEP)和光学显微镜等方法,对贵州大方煤田11号煤层的地球化学和矿物学进行了研究。结果表明,大方煤田11号煤层中有高含量的脉状石英(11.4%)和脉状铁白云石(10.2%),铁白云石周边常被针铁矿所包裹,在脉状石英中发现有热液成因的黄铜矿、闪锌矿和硒方铅矿,此外,还有少量高岭石充填在脉中,这7种矿物常常同脉共存。脉状石英和脉状铁白云石分别来源于硅质和富铁的钙质低温热液流体,形成温度分别为180℃和85℃。脉状石英早于脉状铁白云石形成。根据Ca/Sr和Fe/Mn值,确定出铁白云石的形成至少经历了3个时期。这7种矿物按照从早到晚的生成顺序为硫化物、石英、高岭石、铁白云石和针铁矿。铁白云石是煤中Mn、Cu、Ni、Pb和Zn富集的主要原因,这5种微量元素的含量分别为0.09%、74.0μg/g、33.6μg/g、185μg/g和289μg/g。脉状石英是煤中铂族元素Pd、Pt和Ir的主要载体,它们在煤中的含量分别为1.57μg/g、0.15μg/g和0.007μg/g。另外,黄铜矿、闪锌矿和硒方铅矿亦是11号煤层中Cu、Zn和Pb的重要载体。     

Biomediation of calcrete at the gold anomaly of the Barns prospect,Gawler Craton,South Australia

Anomalously high Au concentrations (2.5 to 50 ppb) in regolith carbonate accumulations, such as calcrete and calcareous sands in aeolian sand dunes overlying Au mineralisation of the Gawler Craton, South Australia, show a marked covariance of Au with K, Mg and most notably Ca. This relationship appears to be linked to the authigenic formation of smectites and carbonates within the aeolian dunes in the region. However, little is known about the processes involved in the formation of carbonates under semi-arid and arid conditions. In this study the geochemical properties of aeolian dunes along several depth profiles of 2 to 4 m are investigated in order to assess the relationship between Au mobility and calcrete formation. In the profiles a strongly systematic relationship between Au and the increasing Ca–Mg contents at depth highlights the close association between the enrichment of Au in the calcrete and the underlying hydrothermal mineralisation. Intense calcrete formation and concurrent Au enrichment also occurs in the vicinity of roots penetrating the dune. Thin section petrography and cathodoluminescence show that most of the calcrete in the regolith profiles is micritic; some sparic crystallites have also been identified. To demonstrate the presence of microbial processes that may mediate the formation of calcrete, samples from a depth profile in the dune were taken under sterile conditions. After amendment with urea and incubation of up to 24 h, up to 18 mg/l of NH₄⁺ were detected in near surface samples. At depth of 2.3 m 1 mg/l NH₄⁺ were detected compared to a control that contained below 0.05 mg/l NH₄⁺. These results suggest that the genesis of calcrete and pedogenic carbonate in the area may be partly biologically mediated via processes such as the metabolic breakdown of urea by resident microbiota which generates a pH and pCO₂ environment conducive to the precipitation of carbonate. In the process of urea breakdown organic Au complexes such as Au-amino acid complexes may become destabilised in solution and Au may be co-precipitated, resulting in the fine, non-particulate distribution of Au throughout the micritic calcrete carbonate. In conclusion, this study suggests a coupled mechanism of biologically mediated and inorganic mechanisms that lead to the formation of Au-in-calcrete anomalies.     

Cenozoic volcanic rocks in the Belog Co area, Qiangtang, northern Tibet, China： Petrochemical evidence for partial melting of the mantle-crust transition zone

Neogene volcanic rocks in the Belog Co area, Qiangtang, northern Tibet, are represented by a typical intermediate-basic and intermediate alkaline rock association, with latite-trachyte as the main rock type. The results of chemical analysis are: SiO2=52%–62%, Al2O3>15%, Na2O/K2O>1 and MgO<3.30%. In addition, the volcanic rocks are LREE-enriched with LREE/HREE=10–13, (La/Yb)N=15–19, and show a weak negative Eu anomaly with δEu=0.71–0.89. The close relationship between Mg# and SiO2 and the co-variation of the magmatophile elements and ultra-magmatophile elements such as La/Sm-La and Cr-Tb indicate that this association of volcanic rocks is the product of comagmatic fractional crystallization. The rock association type and lower Sm/Yb values (Sm/Yb=3.23–3.97) imply that this association of volcanic rocks should have originated from partial melting of spinel lherzolite in the lithospheric mantle. On the other hand, the weak negative Eu anomaly and relative depletion in Nb, Ta and Ti reflect the features of terrigenous magma. So the Neogene Belog Co alkaline volcanic rocks should be the result of partial melting of the special crust-mantle transition zone on the Qinghai-Tibet Plateau.     

内蒙古巴彦温多尔金矿元素组合特征及地质意义

通过因子分析、相关分析和聚类分析，研究了巴彦温多尔金矿矿石和围岩样品12种元素的组合特征。结果显示，矿石中金与其他11种元素的相关程度很低，而围岩中金与银有较强的相关性。围岩和矿石的元素组合也有明显差别，围岩样品代表控矿构造带的矿化背景，矿石样品代表成矿时的元素组合。     

铂族元素稀释剂溶液的制备及标定

采用高温高压酸溶，同位素稀释电感耦合等离子体质谱法，以铂族多元素标准溶液和铂族单元素标准溶液标定了^99Ru、^105Pd、^191Ir、^198Pt稀释剂溶液的浓度。根据最佳稀释比和最佳测量比，配制了三组待标定稀释剂溶液，所得浓度结果不确定度在1％左右。建立了一套溶解金属Ru、Ir的方法，同时确定了测量Ru、Pd、Ir、Pt时检测器死时间。用标准溶液测得各元素的多组同位素比值和质量数，拟合出Ru、Pd、Pt的分馏系数方程，通过分馏系数校正丰度测量中的质量分馏。