Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.     

Geophysical methods applied to fault characterization and earthquake potential assessment in the Lower Tagus Valley, Portugal

The study region is located in the Lower Tagus Valley, central Portugal, and includes a large portion of the densely populated area of Lisbon. It is characterized by a moderate seismicity with a diffuse pattern, with historical earthquakes causing many casualties, serious damage and economic losses. Occurrence of earthquakes in the area indicates the presence of seismogenic structures at depth that are deficiently known due to a thick Cenozoic sedimentary cover. The hidden character of many of the faults in the Lower Tagus Valley requires the use of indirect methodologies for their study. This paper focuses on the application of high-resolution seismic reflection method for the detection of near-surface faulting on two major tectonic structures that are hidden under the recent alluvial cover of the Tagus Valley, and that have been recognized on deep oil-industry seismic reflection profiles and/or inferred from the surface geology. These are a WNW–ESE-trending fault zone located within the Lower Tagus Cenozoic basin, across the Tagus River estuary (Porto Alto fault), and a NNE–SSW-trending reverse fault zone that borders the Cenozoic Basin at the W (Vila Franca de Xira–Lisbon fault). Vertical electrical soundings were also acquired over the seismic profiles and the refraction interpretation of the reflection data was carried out. According to the interpretation of the collected data, a complex fault pattern disrupts the near surface (first 400 m) at Porto Alto, affecting the Upper Neogene and (at least for one fault) the Quaternary, with a normal offset component. The consistency with the previous oil-industry profiles interpretation supports the location and geometry of this fault zone. Concerning the second structure, two major faults were detected north of Vila Franca de Xira, supporting the extension of the Vila Franca de Xira–Lisbon fault zone northwards. One of these faults presents a reverse geometry apparently displacing Holocene alluvium. Vertical offsets of the Holocene sediments detected in the studied geophysical data of Porto Alto and Vila Franca de Xira–Lisbon faults imply minimum slip rates of 0.15–0.30 mm/year, three times larger than previously inferred for active faults in the Lower Tagus Valley and maximum estimates of average return periods of 2000–5000 years for M 6.5–7 co-seismic ruptures.     

Deep seismic reflection study over the Vindhyans of Rajasthan: Implications for geophysical setting of the basin

This paper presents results of high-resolution deep seismic reflection profiling of the Proterozoic Vindhyan basin of the Rajasthan area along the Chandli-Bundi-Kota-Kunjer profile. Seismic images have been used to estimate the thickness of Vindhyan strata as well as to understand the tectonic framework of the basin. The results are constrained by gravity, magnetic and magnetotelluric data. The study reveals gentle SE-dipping reflection bands representing the Vindhyan strata. The seismic sections depict gradual thickening of the Vindhyan succession towards southeast from Bundi. The velocities of the upper and lower Vindhyans are identified as 4.6-4.8 km/s and 5.1-5.3 km/s. The NW limit of the Vindhyan basin is demarcated by the Great Boundary Fault (GBF) that manifests as a 30 km wide NW dipping thrust fault extending to a depth of 30 km.     

Crustal structure across the Grand Banks–Newfoundland Basin Continental Margin – II. Results from a seismic reflection profile

New multichannel seismic reflection data were collected over a 565 km transect covering the non-volcanic rifted margin of the central eastern Grand Banks and the Newfoundland Basin in the northwestern Atlantic. Three major crustal zones are interpreted from west to east over the seaward 350 km of the profile: (1) continental crust; (2) transitional basement and (3) oceanic crust. Continental crust thins over a wide zone (∼160 km) by forming a large rift basin (Carson Basin) and seaward fault block, together with a series of smaller fault blocks eastwards beneath the Salar and Newfoundland basins. Analysis of selected previous reflection profiles (Lithoprobe 85-4, 85-2 and Conrad NB-1) indicates that prominent landward-dipping reflections observed under the continental slope are a regional phenomenon. They define the landward edge of a deep serpentinized mantle layer, which underlies both extended continental crust and transitional basement. The 80-km-wide transitional basement is defined landwards by a basement high that may consist of serpentinized peridotite and seawards by a pair of basement highs of unknown crustal origin. Flat and unreflective transitional basement most likely is exhumed, serpentinized mantle, although our results do not exclude the possibility of anomalously thinned oceanic crust. A Moho reflection below interpreted oceanic crust is first observed landwards of magnetic anomaly M4, 230 km from the shelf break. Extrapolation of ages from chron M0 to the edge of interpreted oceanic crust suggests that the onset of seafloor spreading was ∼138 Ma (Valanginian) in the south (southern Newfoundland Basin) to ∼125 Ma (Barremian–Aptian boundary) in the north (Flemish Cap), comparable to those proposed for the conjugate margins.     

Spectral Simulation and Conditioning to Local Continuity Trends in Geologic Modeling

Spectral simulation has gained application in building geologic models due to the advantage of better honoring the spatial continuity of petrophysical properties, such as reservoir porosity and shale volume. Distinct from sequential simulation methods, spectral simulation is a global algorithm in the sense that a global density spectrum is calculated once and the inverse Fourier transform is performed on the Fourier coefficient also only once to generate a simulation realization. The generated realizations honor the spatial continuity structure globally over the whole field instead of only within a search neighborhood, as with sequential simulation algorithms. However, the disadvantage of global spectral simulation is that it traditionally cannot account for the local information such as the local continuity trends, which are often observed in reservoirs and hence are important to be accounted for in geologic models. This disadvantage has limited wider application of spectral simulation in building geologic models. In this paper, we present ways of conditioning geologic models to the relevant local information. To account for the local continuity trends, we first scale different frequency components of the original model with local-amplitude spectrum ratios that are specific to the local trend. The sum of these scaled frequency components renders a new model that displays the desired local continuity trend. The implementation details of this new method are discussed and examples are provided to illustrate the algorithm.     

探地雷达(GPR)在海南岛东北部海岸带调查中的应用 *

对海南岛东北部海岸带调查采用了探地雷达(GPR)研究海岸带沙体的结构、展布和沉积序列,取得了很好的效果。文章通过和有限的露头资料对比以及对反射波形态、结构的研究,确定了海滩脊、海岸沙丘的反射特征以及潜水面的位置。雷达图像显示五龙港古海滩脊由亚水平、不连续、高振幅和透镜状反射波组成;木兰头海岸沙丘已受到人类活动的扰动,短的、陡倾斜反射可能代表未受扰动的海岸风成沙的前积层。研究表明探地雷达是一种可靠、快速和经济的地球物理方法,在砂砾质海岸可产生高质量、高分辨率和连续的反射剖面,值得加以推广。     

大别山造山带前陆深地震反射剖面

在大别山南部和扬子地块前陆实施的深地震反射剖面(140 km)揭示出大别山造山带前陆地壳的精细结构。总体北倾的地壳内部结构与向北缓倾的叠瓦状莫霍面反射揭示出扬子陆块向北俯冲的行迹。莫霍面向北插入大别山造山带下与南大别山地壳内南倾反射震相叠置,构成交叉反射图像,刻画出扬子前陆与大别山造山带的碰撞构造面貌。     

隧道锚杆锚固质量无损检测技术

采用声波检测仪,应用声频应力波在不同波阻抗面反射的能量和相位的变化原理,对隧道的锚杆锚固质量进行了无损检测试验研究,并对检测技术进行了探讨.结果表明,作为一种工程质量管理辅助手段,采用应力波对锚杆锚固质量进行无损检测,丰富了隧道围岩锚固质量检测方法,为隧道工程建设提供更好的质量保障.