Graptolite, Chitinozoan and Scolecodont Reflectances and Their Use as Indicators of Thermal Maturity

Based on studies of the reflectance of Ordovician and Silurian zooclasts from 11 sections around the Huangling Anticline, Hubei, China, combined with determination of the conodont colour alteration indices (CAI) and of infrared spectroscopy of dispersed organic matter from the same or adjacent horizons, it is further proved that reflectances of graptolites, chitinozoans and scolecldonts, like vitrinite and natural bitumen, increase with increasing maturation, but follow different reflectance paths. They may be used, therefore, as thermal maturation indicators. Graptolites display optically strong anisotropy. The maximum reflectance measured from graptolite on polished section cut parallel to the bedding plane is the most suitable for determination of maturation of their host rocks. In polished section chitinozoan and scolecodont show reflectance, but no bireflectance owing to their isotropy. The random reflectance of chitinozoans is higher than that of scolecodonts in the case of the same maturity. By analysing the distribution trends of graptolite, chitionzoan and scolecodont reflectances, the Ordovician and Silurian strata can be subdivided into three areas of maturation in the present region. The potential of oil or gas generation is discussed for each area. The result is basically coincident with the distribution pattern of regional organic maturation presented by CAI and infrared spectroscopic determination of organic matter.     

煤镜质组反射率各向异性特征在构造应力场分析中的应用

煤镜质组反射率各向异性分析,是研究煤田构造应力场的一种有效方法。本文阐述了镜质组反射率各向异性的成因、取样、测量以及资料的处理方法。通过洪山殿煤矿区的镜质组反射率各向异性分析,得出了本区存在多期构造应力场叠加的结论。     

河南小秦岭金矿区黄铁矿的红外光谱研究

本文主要报道了河南小秦岭金矿区的不同矿体位置的黄铁矿(FeS_2)的红外反射光谱,讨论了其声子结构及低频端Plasmon反射边的物理起源,并且用低温实验和有关光谱计算证明了有关结论,还根据所确定的Plasmon效应系数X值,发现与相应的样品中的杂质Pb,Cu,Au等元素在量值上存在一定的正相关性。     

Diagenesis and very low-grade metamorphism of volcaniclastic sandstones from contrasting geodynamic environments, North Island, New Zealand: the Murihiku and Waipapa terranes

Abstract The Mesozoic Murihiku and Waipapa terranes are two accretionary wedges of linked forearc and trench sediments, respectively, that were juxtaposed in the early Cretaceous.
Late Triassic to late Jurassic Murihiku terrane volcaniclastic sediments are folded into a regional syncline and have been diagenetically altered. There is a general relationship between zeolite occurrence, clay mineralogy, vitrinite reflectance and stratigraphic position. Youngest Jurassic sediments contain heulandite, analcime and stilbite, whereas late Triassic to mid-Jurassic sediments have laumontite and heulandite (in detail the zeolite distribution is complicated). Tuffaceous horizons on the eastern limb of the syncline are calcitized rather than zeolitized. Post-diagenetic fractures associated with uplift are laumontite-filled. The inferred geothermal gradient is c. 15° C km⁻¹.
The Waipapa terrane is an accretionary complex dominated by imbricated terrigenous sediments of Triassic and Jurassic age with enclosed Permian to Jurassic pelagic sediments and basalts. Late Jurassic sediments are massive volaniclastic sandstones. The sediments are non-foliated, and metamorphic minerals in the massive sandstones have crystallized in specific domains. The observed metamorphic succession of prehnite-pumpellyite and pumpellyite-actinolite facies assemblages was overprinted in the imbricated rocks during a thermal event that was late in the deformation sequence and broadly coincident with hydraulic fracturing and veining.
The metamorphic successions in the two terranes and their relationships to structural features are in excellent accord with accretionary complex models.     

草地光谱分类最佳时相选择分析

利用2003年5-10月在环青海湖地区获取的典型天然草地与人工草地多时相地面高分辨率光谱数据，首先分析了最大似然分类法、支持向量机分类法、光谱角分类法、最小距离分类法和人工神经网络分类法所对应的最佳光谱变换方案；通过16个时相光谱数据的分类对比实验，分别确定了天然草地与人工草地分类、人工草地分类、天然草地分类的最佳时相；最后利用TM遥感数据对地面光谱数据分析结果进行了补充验证。     

基于3D真实植被场景的全波段辐射传输模型研究

本文基于3D真实场景CLAMP模型模拟的植被冠层，对冠层在可见一近红外波段和热红外波段的辐射传输进行了综合建模。针对CLAMP模型生成场景的通用和近似特征，在可见一近红外波段，对植被和土壤的单次散射贡献利用光子逆向追踪算法进行了精确计算，多次散射的贡献则采用四流近似理论来计算，以提高运算效率。模型结果与SAILH模型结果进行了比较，具有较好的一致性，并且体现出了优于一维辐射传输模型的模拟结果。在热红外波段，采用几何光学原理，冠层方向亮度温度由可视光照叶片、遮荫叶片、光照土壤和遮荫土壤的比例与对应组分亮温乘积之和得到，模拟结果体现了合理的变化趋势。对冠层主要结构参数LAI和ALA的敏感性进行了比较分析，不同波段模型模拟的方向性辐射结果，很好地反映了结构参数对冠层辐射特性的影响。     

Numerical modelling of burial and temperature history as an approach for an alternative interpretation of the Bramsche anomaly, Lower Saxony Basin

The Lower Saxony Basin, Germany, is one of the several sedimentary basins within the Central European Basin system. In its southwestern part, anomalously high maturity of organic matter has been observed to reach 4.5% VRr in Upper Jurassic and Lower Cretaceous sedimentary rocks in an area which coincides with a magnetic and a positive gravimetric anomaly. This anomaly was often interpreted as the consequence of a deep-seated igneous intrusion, the so-called Bramsche Massif. However, results obtained from calibrated numerical modelling are not in accordance with this scenario. Instead, a burial by approximately 4 km of now-eroded Cretaceous rocks was revealed to be the probable cause for the anomaly. Data and modelling results from six boreholes and two pseudo-wells support this view.     

Visible and near infrared reflectance spectroscopy for measuring soil heavy metal content as a quick method

Conventional methods for investigating soil heavy metal contamination based on raster sampling and chemical analysis are time consuming and relatively expensive. Reflectance spectroscopy within the visible-near-infrared （VNIR） region is known for being rapid, convenient, and accurate. Due to low abundance, heavy metals in soils cannot exhibit their inherently spectral features. The objective of this study were （1） to examine the possibility of reflectance spectra as a rapid method to assess Ni, Cr, Cu, Hg, Zn, As, Pb, and Cd in soils, and （2） to explore the mechanism by which to predict spectrally featureless heavy metals. Two research areas located in the south （120 samples） and north （61 samples） of Nanjing City were researched. Reflectance spectra of the samples were recorded on a Perkin-Elmer Lambda 900 spectrophotometer. Partial least-square regression （PLSR） approach was used to develop calibration equations between the spectral data and measured values for heavy metals. The prediction results of the two areas were consistent. Except for Cd all the other elements could be successfully predicted using the reflectance spectra. The prediction accuracy for Ni, Cr, and Cu was highest, while that for Hg and Cd was lowest. In order to further explore the physicochemical mechanism behind the relations between reflectance spectra and heavy metals, one more principal component analysis （PCA） was done for nine elements （eight heavy metals and Fe）. The results of PCA for the both areas were also consistent. Loading plot of factors 1 and 2 from the results of PCA showed that Ni, Cr and Cu, the prediction accuracy of which was highest, were clustered together with Fe. For the other elements that were less correlated with Fe, their prediction accuracy was also lower than that of the three elements. Fe is spectrally active and can exhibit its absorption features. Therefore, the inter-correlation between heavy metals and spectrally active total Fe is the major mechanism by which to predict spectrally featureless trace metals. This study for the two areas showed the potential of reflectance spectra to predict microelements in soils.     

Assessment of cadmium contamination in the sediments of Changjiang （Yangtze） River by reflectance spectroscopy

The Takab area in NW of Iran is an important gold mineralized region with a long history of gold mining. In this study ASTER data is used to evaluate environmental effects of gold mining. The results show that mining activities have resulted in release of potentially toxic metals （PTMs） in the area. Principal component analysis （PCA） of ASTER data is used to map sources of PTMs and their secondary hosts （iron oxides） through alteration mapping. The results show that selective PCA is a robust yet time consuming technique for alteration mapping. A color composite is created for finding common hydrothermally altered rocks. The created color composite successfully mapped the known deposits and anomalous areas identified by geological survey of Iran. Because of the low spatial resolution of ASTER sensor, the iron oxide mapping is restricted to the wider portions of the streams. Spectral analyses confirm the presence of hematite and goethite in stream sediments. This is in accordance with measured pH values.     

From Middle Jurassic heating to Neogene cooling: The thermochronological evolution of the southern Alps

The Dolomite region is located in the Southern Alps, which were affected by Mesozoic extensional tectonics and by consequent thermal perturbations. In this work, vitrinite reflectance and apatite fission-track analysis are used to estimate the thermal evolution. These methodologies have been applied to the Permo-Mesozoic succession, which crops out along the TRANSALP seismic profile. The regional distribution of the organic matter maturity seems to be mainly controlled by different burials reached during the Norian-Liassic extensional phase, in connection with high heat flow values. The best solutions obtained from thermal modelling of both vitrinite and fission-track data suggest that peak of high heat flow occurred during Bajocian–Bathonian ages, when western Tethys was characterized by intrusions of gabbros and plagiogranites and extrusion of tholeiite basalts. This time coincides with the onset of the drifting phase and related thermal subsidence. The following thermal relaxation occurred during continuous sedimentation and the maximum burial does not coincide with peak temperatures. Cooling history has been carefully analysed through apatite fission-track data on samples collected close to the Valsugana overthrust, which document an important exhumation event at about 10 Ma. The related erosion has been analysed through the combined use of arenite petrography and fission-track analysis on detrital samples of the Veneto foredeep succession, which represents the storage of detritus during Tertiary. These data confirm that after Serravalian the Southalpine domain and related covers were affected by subaerial erosion.