机载LiDAR技术支持下的荒漠地区1:10 000地形图测绘与研究——以内蒙古阿拉善地区为例

尝试应用机载LiDAR技术测绘1：10 000比例尺地形图3D（DLG、DEM、DOM）产品,给出了机载LiDAR测绘3D产品的技术流程,并选择荒漠地区作为试验区,验证了此种技术方法在荒漠地区测绘3D产品的可行性,分析了成果精度。试验证明,该方法可以满足荒漠区域的1：10 000比例尺3D基础数据生产要求,且具有外业工作量小、自动化程度高、成图快、高程精度高、受外界环境影响小等优点,同时也总结了该方法中有待完善之处。该方法为荒漠地区3D基础测绘数据获取提供了有益借鉴。     

铜镍硫化物铼-锇标准物质定值的溯源性讨论及总不确定度评估

对按国家一级标准物质技术规范研制的铜镍硫化物Re-Os标准物质定值的溯源性及其总不确定度进行讨论与评估。铜镍硫化物标准物质样品采用Carius管溶解,高精度的TRITON同位素质谱仪、MAT-262热电离质谱仪、四极杆等离子体质谱仪、多接收器等离子体质谱仪和高分辨四极杆等离子体质谱仪测量Re、Os含量和Os同位素比值,其中Re-Os含量可以溯源至基准物质,而187Os/188Os同位素比值可以溯源至国际纯粹与应用化学联合会(IUPAC)。在定值数据误差计算时,采用国际通用的ISOPLOT软件利用加权的方法对数据进行处理;在合成总不确定度时,考虑了物质的均匀性和稳定性,同时考虑了稀释剂标定和同位素丰度以及称量误差等影响测定因素的不确定度。标准值的不确定度由三部分组成:第一部分是通过所有参与定值数据,采用ISOPLOT软件,利用加权的方法对数据进行计算处理得到的不确定度;第二部分是物质的均匀性和稳定性的不确定度;第三部分是影响测定其他因素的不确定度。     

太平洋多金属结核及沉积物标准物质研制

太平洋多金属结核及深海沉积物标准物质,ＧＳＰＮ－２,３和ＧＳＭＳ－２,３,４个样品已研制完成。ＧＳＰＮ－２,３和ＧＳＭＳ－２采自太平洋ＣＣ区,ＧＳＭＳ－３采自中太平洋海盆（ＣＰ区）。原样被加工成－２００目（７４μｍ）的均匀粉未,其均匀性采用高精度的Ｘ射线荧光光谱法检测。样品的特性值采用国内外多实验室协同分析的方式定值,有包括台湾大学在内的１４个国内实验室和１８个国外实验室参加了合作分析。测试组分分别达７９和８１个,定值组分６３个。全组分的百分总和分别为：９９．７％,９９．５％,９９．８％和９９．７％。这４个标准物质已于１９９７年被国家技术监督局批准为国家一级标准物质,序号分别为ＧＢＷ０７２９５,ＧＢＷ０７２９６,ＧＢＷ０７３１５和ＧＢＷ０７３１。     

铜、铝需求“S”形规律的三个转变点剖析

本文分析了铜、铝人均消费"S"形轨迹的三个重要转变点:找出了理论上铝的三个转变点出现时间,指出铜和铝人均消费的三个重要转变点出现的时间比较接近,铝略早于铜.以此为基础,分析了我国未来铜、铝需求趋势,发现,2020年前后,我国铜和铝将达到需求峰值,届时需求量均将比目前水平增长1倍.     

传统村落理水生态智慧数字化解析——以江西流坑村为例（英文）

在传统村落长期除水害、兴水利的营建与发展过程中,通过适应天然水体和利用地域水系形成了一整套成熟的策略,有着朴素的理水生态智慧。本研究从村落水系格局梳理、空间特征计算、水环境量化三个方面,对江西流坑村的理水策略和效果做出定性和定量的分析,探索村落理水研究的技术方法和潜力。研究结果表明,流坑村具有源头引水—中程排水—末端调蓄的层次清晰的水系格局：通过三维点云计算可知,其选址精确利用了微地形,采用多水源理水策略,形成了一个有机的水系格局,为村落各类需求提供了充足水源;采用双水源理水策略;村中塘湖可容纳83.0%的雨水,且植被面积约占村落总面积的34.7%,具有较高的地表渗透率,中程排水效果甚佳;通过水环境质量检测可知,其塘湖水体环境质量良好,末端调蓄功能较强。该研究旨在填补以往对传统村落理水非量化研究的空缺,挖掘传统村落隐没的信息和价值,加深人们理解传统村落水利统筹、布局和营建的生态智慧,实现传统村落水利文化遗产保护与现代利用的双赢,为我国村镇聚落发展建设过程中妥善处理雨洪问题、实现水资源可持续、保护生态环境提供有益启示和借鉴。     

Determination of Rare Earth Elements, Sc, Y, Zr, Ba, Hf and Th in Geological Samples by ICP-MS after Tm Addition and Alkaline Fusion

We present a revised method for the determination of concentrations of rare earth (REE) and other trace elements (Y, Sc, Zr, Ba, Hf, Th) in geological samples. Our analytical procedure involves sample digestion using alkaline fusion (NaOH-Na₂O₂) after addition of a Tm spike, co-precipitation on iron hydroxides, and measurement by sector field-inductively coupled plasma-mass spectrometry (SF-ICP-MS). The procedure was tested successfully for various rock types (i.e., basalt, ultramafic rock, sediment, soil, granite), including rocks with low trace element abundances (sub ng g⁻¹). Results obtained for a series of nine geological reference materials (BIR-1, BCR-2, UB-N, JP-1, AC-E, MA-N, MAG-1, GSMS-2, GSS-4) are in reasonable agreement with published working values.     

GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.     

Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.     

城市地表饮用水源保护研究进展

城市水资源短缺和地表饮有水污染已成为全球范围的重大问题和人类社会共同关注的焦点。城市地表饮用水源的保护已越来越受到人们的重视,它的研究应该在城市地表饮用水源的科学管理和保护中发挥重要的作用。对国内外地表饮用水源保护研究现状和地表饮用水源保护现状进行综述,同时重点分析和讨论了国内外研究存在的不足,提出城市地表饮用水源保护的未来研究重点。     

近50a来塔里木河干流年径流量变化趋势及预测

根据塔里木河干流1957-2008年的年径流量监测数据,利用Mann-Kendall非参数技术检验和R/S法,对干流年径流量时间序列变化趋势进行分析,并在此基础上采用滑动t检验法和Mann-Kendall法对其突变点进行检验,最后运用方差分析外推法和叠加趋势预测模型对干流水文周期和未来径流量变化进行分析和预测.结果显示...