Composition-Induced Variations in SIMS Instrumental Mass Fractionation during Boron Isotope Ratio Measurements of Silicate Glasses

An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated.     

Recommended Values of 239Pu, 240Pu and 239+240Pu Concentrations in Reference Material IAEA-315 (Marine Sediment) Estimated by Thermal Ionisation Mass Spectrometry, Inductively Coupled Plasma-Mass Spectrometry and Alpha Spectrometry

The recommended concentrations of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of ²³⁹Pu and ²⁴⁰Pu (^239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of ²⁴²Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg^?1, (28 ± 3) Bq kg^?1 and (66 ± 4) Bq kg^?1 are proposed as recommended values for ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu, respectively, and (9.5 ± 0.4) Bq kg^?1 for ²³⁸Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg^?1, (3.3 ± 0.4) ng kg^?1 and (0.015 ± 0.003) ng kg^?1 for ²³⁹Pu, ²⁴⁰Pu and ²³⁸Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study.     

基于ICCP算法的重力辅助惯性导航

迭代最近等值线算法(ICCP)是一种重要的匹配导航算法,文中首先介绍ICCP算法的基本原理,随后在0.2′×0.2′重力异常数据库的基础上,利用ICCP算法进行仿真计算得到最佳匹配位置。最后为了验证匹配位置是否可用于修正惯导误差,提出将匹配位置误差作为观测量,用卡尔曼滤波对惯导系统误差进行最优估计。由最后的仿真结果可以看出,ICCP算法可有效抑制惯导纬度误差的增长,且最大纬度误差不超过2,′以匹配位置误差作为观测量可以用来估计惯导方位误差角。     

倒Y形竖井联系测量

介绍在小直径竖井联系测量中取消联系三角形,改用单根钢丝定点,全站仪引测高程的施测方法。     

Some Results on the Spatial Breakdown Point of Robust Point Estimates of the Variogram

The effect of outliers on estimates of the variogram depends on how they are distributed in space. The ‘spatial breakdown point’ is the largest proportion of observations which can be drawn from some arbitrary contaminating process without destroying a robust variogram estimator, when they are arranged in the most damaging spatial pattern. A numerical method is presented to find the spatial breakdown point for any sample array in two dimensions or more. It is shown by means of some examples that such a numerical approach is needed to determine the spatial breakdown point for two or more dimensions, even on a regular square sample grid, since previous conjectures about the spatial breakdown point in two dimensions do not hold. The ‘average spatial breakdown point’ has been used as a basis for practical guidelines on the intensity of contaminating processes that can be tolerated by robust variogram estimators. It is the largest proportion of contaminating observations in a data set such that the breakdown point of the variance estimator used to obtain point estimates of the variogram is not exceeded by the expected proportion of contaminated pairs of observations over any lag. In this paper the behaviour of the average spatial breakdown point is investigated for cases where the contaminating process is spatially dependent. It is shown that in two dimensions the average spatial breakdown point is 0.25. Finally, the ‘empirical spatial breakdown point’, a tool for the exploratory analysis of spatial data thought to contain outliers, is introduced and demonstrated using data on metal content in the soils of Sheffield, England. The empirical spatial breakdown point of a particular data set can be used to indicate whether the distribution of possible contaminants is likely to undermine a robust variogram estimator.     

抓“热点”、解“难点”，依法行政搞矿管

原达县地区是全省矿业活动最频繁的地区之一,也一度成了全省有名的“采煤混战”大区。近几年来,以《矿产资源法》为指针,抓住“重点”,调处“热点”,解决“难点”,以点带面,加强矿管行政执法工作,促进了全区矿业秩序的全面好转,矿业生产也相应得到健康发展。矿业产值占全区工业总产值的１５％左右,是全区的一大支柱产业,有力地促进了地方经济的发展。     

自重湿陷性黄土地区桩基设计探讨

根据自重湿陷性黄土的特点、《湿陷性黄土地区建筑规范》（GB50025—2004）和《建筑桩基技术规范》（JGJ94—94）中关于桩基设计的对比分析，通过自重湿陷性黄土场地工程实例分析计算，依据负摩擦产生的机理——中性点理论，论述了自重湿陷性黄土场地中桩基设计应考虑中性点，而不应全部计入负摩阻的观点。     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

Reference Materials in Geoanalytical Research -Review for 2004 and 2005

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.     

Site Effects Study in the Serravalle Village (NE Italy) by Means of Spectral Ratios Analyses Relatively to Multiple Reference Sites

The area of Serravalle, sited in the northern part of the town of Vittorio Veneto (TV), NE Italy, has been the target of a seismic microzonation campaign. 10 seismic stations have been deployed for a 7 months period to record in continuous mode. Three stations were installed on bedrock outcrops and seven on sedimentary sites with variable cover thickness. Spectral analyses have been performed on the collected data-set using the Generalized Inversion Technique (GIT, e.g. Andrews, 1986). In particular, spectral ratios have been calculated for each station relatively to the average of the three reference, bedrock sites. The spectral ratios provide quantitative estimates of the seismic motion amplifications which occur in each of the monitored sites. Two sites show high values of amplification, 5 times larger than signal amplitude at the reference sites, in correspondence of well discernible peak frequencies of 5 Hz. Results for the other stations show smaller amounts of site amplification spreading over a broad range of frequencies. Sites where the highest amplifications were recorded all lie on the left bank of the Meschio River and in areas farther away from its outlet into the plain correlating with the presence of thick layers of Quaternary deposits.