Os水吸收液ICP-MS测量信号强度衰减原因研究

蒸馏法能从样品中有效分离出OsO_4,吸收液直接用于ICP-MS测定,是辉钼矿Re-Os定年的关键技术环节。但实验发现,长时间放置的吸收液中Os信号强度显著降低。根据OsO_4化学性质推测原因在于一是挥发使吸收液Os含量减少,二是还原使+8价Os变成低价态,气态比例降低,若雾化效率不变,进入质谱仪的Os减少,两者都会导致信号降低,但具体影响情况不明,需深入研究。本文利用辉钼矿标准物质制备不同放置时间、酸度和温度的吸收液,对比上述条件对ICP-MS信号强度的影响。实验时将残余吸收液与稀释剂、氧化剂封入Carius管加热蒸馏,测定Os含量。结果表明:吸收液放置时间越长,酸度越低,温度越高,信号降幅越大,幅度达到3.2%~68.6%。室温下放置相同时间,低酸度吸收液的Os保存率高于高酸度吸收液,但Os信号强度低于后者,证明了挥发和还原共同导致信号衰减,且还原是主导原因。本文提出,冷冻(-18℃)可抑制OsO_4挥发,提高酸度(约3.5 mol/L)可减弱OsO_4还原,两者结合抑制信号衰减,提高了蒸馏法的灵活性和适用性。     

Hydrothermal Dolomite: A Review and PerspectiveEI北大核心CSCD

Hydrothermal dolomite commonly closely associates with oil-gas reservoirs and sediment-hosted Pb-Zn deposits, the Mississippi Valley-type (MVT) Pb-Zn deposits in particular. Host rocks of MVT deposits usually experienced extensive dolomitization, and indeed, hydrothermal dolomite is considered as a useful prospective indicator for MVT mineralization. However, genetic link between the hydrothermal dolomitization and MVT Pb-Zn mineralization is a matter of debate. This paper briefly reviewed the nomenclature and research history of hydrothermal dolomite, introduced the major geological, geochemical characteristics, and distribution of hydrothermal dolomite, spatial and possibly genetic relationship between hdyrothermal dolomite and hdyrothermal ore deposits and oil-gas reservoirs based on case studies including the occurrence of hydrothermal dolomites in MVT deposits in Southwest China. The temporal and genetic relationships between dolomitizaiton and thermal sulfate reduction, sulfide precipitation and thus the location of ore mineralization well worthy more attention, and comprehensive geological and isotope geochemical and state of art in situ techniques will contribute to understanding of the genesis of hydrotherml dolomite and the spatially related ore deposits and oil-gas reservoirs. © 2018, Science Press. All right reserved.     

温室气体排放的环境库兹涅茨曲线检验与减排路径的冲击动态——基于黑龙江省统计核算数据

基于2001-2015年黑龙江省温室气体排放统计核算数据,对地区GDP与温室气体排放的环境库兹涅茨曲线关系检验呈现倒U型,预期2019年达到理论拐点;通过偏最小二乘回归模型得到4个减排路径的年平均减排效果顺序依次为单位GDP化石能源消费量减少、经济结构调整、人均GDP增长、贸易结构变化;减排路径对应脉冲响应函数的动态冲击效果分别为波动性增排、收敛性减排、发散性减排、转变的排放作用;推动黑龙江省温室气体减排的路径顺序为控制化石能源消费量、优化经济结构、发展低碳经济、调整贸易结构。     

Flood insurance arrangements in the European Union for future flood risk under climate and socioeconomic change

Flood risk will increase in many areas around the world due to climate change and increase in economic exposure. This implies that adequate flood insurance schemes are needed to adapt to increasing flood risk and to minimise welfare losses for households in flood-prone areas. Flood insurance markets may need reform to offer sufficient and affordable financial protection and incentives for risk reduction. Here, we present the results of a study that aims to evaluate the ability of flood insurance arrangements in Europe to cope with trends in flood risk, using criteria that encompass common elements of the policy debate on flood insurance reform. We show that the average risk-based flood insurance premium could double between 2015 and 2055 in the absence of more risk reduction by households exposed to flooding. We show that part of the expected future increase in flood risk could be limited by flood insurance mechanisms that better incentivise risk reduction by policyholders, which lowers vulnerability. The affordability of flood insurance can be improved by introducing the key features of public-private partnerships (PPPs), which include public reinsurance, limited premium cross-subsidisation between low- and high-risk households, and incentives for policyholder-level risk reduction. These findings were evaluated in a comprehensive sensitivity analysis and support ongoing reforms in Europe and abroad that move towards risk-based premiums and link insurance with risk reduction, strengthen purchase requirements, and engage in multi-stakeholder partnerships.     

Sulfide and iron control on mercury speciation in anoxic estuarine sediment slurries

In order to understand the role of sulfate and Fe(III) reduction processes in the net production of monomethylmercury (MMHg), we amended anoxic sediment slurries collected from the Venice Lagoon, Italy, with inorganic Hg and either potential electron acceptors or metabolic byproducts of sulfate and Fe(III) reduction processes, gradually changing their concentrations. Addition of sulfide (final concentration: 0.2–6.3 mM) resulted in an exponential decrease in the sulfate reduction rate and MMHg concentration with increasing concentrations of sulfide. Based on this result, we argue that the concentration of dissolved sulfide is a critical factor controlling the sulfate reduction rate, and in turn, the net MMHg production at steady state. Addition of either Fe(II) (added concentration: 0–6.1 mM) or Fe(III) (added concentration: 0–3.5 mM) resulted in similar trends in the MMHg concentration, an increase with low levels of Fe additions and a subsequent decrease with high levels of Fe additions. The limited availability of dissolved Hg, associated with sulfide removal by precipitation of FeS, appears to inhibit the net MMHg production in high levels of Fe additions. There was a noticeable reduction in the net MMHg production in Fe(III)-amended slurries as compared to Fe(II)-amended ones, which could be caused by a decrease in the sulfate reduction rate. This agrees with the results of Hg methylation assays using the enrichment cultures of anaerobic bacteria: whereas the enrichment cultures of sulfate reducers showed significant production of MMHg (4.6% of amended Hg), those of Fe(III), Mn(IV), and nitrate reducers showed no production of MMHg. It appears that enhanced Fe(III)-reduction activities suppress the formation of MMHg in high sulfate estuarine sediments.     

基于乡村人口转移和农村道路建设的空间贫困破解机理及其对策研究——以贵州省为例

贫困与地理环境之间交互耦合形成了空间贫困陷阱,本文在对贵州50个国家级贫困县乡村人口转移减贫效应和松桃、威宁、望谟3个典型县域贫困村贫困发生率与农村道路可达性指数空间耦合关系进行实证研究基础上,阐释了破解空间贫困的作用机理,并构建相应政策体系。结果表明：① 贵州国家级贫困县乡村户籍人口向县内城镇转移和县外转移具有显著的减贫效应,但县内城镇转移比县外转移减贫效应的作用力更大。② 松桃县、望谟县极度贫困、可达性较差型和深度贫困、可达性较差型贫困村所占比例在15%左右,威宁为10%左右,对该类型贫困村实施整村易地搬迁和村庄撤并;对具有自然历史文化特色资源的深度贫困、可达性中等型和一般贫困、可达性中等型贫困村应进一步扩展道路宽度,打通断头路,形成网络,增强通行能力。③ 应坚持以县城为中心的就地城镇化和发达地区中心城市、省会城市等异地城镇化并重,加强对转移劳动人口的技能培训,提升其城镇生存能力。继续加大对具有自然历史文化特色资源的保护类村庄的“通村、通组、通户”道路拓宽、硬化等措施,逐步完善自来水、宽带等较为薄弱的基础设施投入力度,推进贫困村基本公共服务均等化;通过发展山区“绿水青山”内生性和外生性产业,引导贫困人口提升自我发展能力。     

Direct numerical simulation of flow over a slotted cylinder at low Reynolds number

Direct numerical simulation was conducted to investigate the flow past a slotted cylinder at low Reynolds number (Re) of 100. The slotting of cylinder affects the boundary layer separation, vortex formation position, recirculation region length and wake width, which are determined by the type of slit. The streamwise slit (SS1), T-shaped slit (SS3) and Y-shaped slit (SS4) act as passive jets, while the transverse slit (SS2) achieves an alternate self-organized boundary layer suction and blowing. The flow rate in slits fluctuates over time due to the alternate vortex shedding and fluctuating pressure distribution around the cylinder surface. One fluctuation cycle of flow rate is caused by a pair of vortices shedding for SS2, SS3 and SS4, while it is created by each vortex shedding for SS1. The wall shear stress and flow impact on the slit wall partly contribute to the hydrodynamic forces acting on the slotted cylinder. Taking into account the internal wall of slit, the transverse slit plays the best role in suppressing the fluid forces with drag reduction of 1.7% and lift reduction of 17%.     

加权空-谱联合保持嵌入的高光谱遥感影像降维方法

高光谱遥感影像数据量大、波段数多,容易导致“维数灾难”。传统流形学习方法一般仅考虑其光谱特征,忽略了空间信息。为此提出一种非监督的基于加权空-谱联合保持嵌入(WSCPE)的维数约简算法。首先采用加权均值滤波(WMF)方法对高光谱影像进行滤波,以消除噪点和背景点的干扰。然后根据遥感影像地物分布的空间一致性,通过采用加权空-谱联合距离(WSCD)来融合像素点的光谱信息和空间信息,有效选取各像素点的空-谱近邻,并根据像素点与其空-谱近邻点之间的坐标距离来有区别的利用其近邻点进行流形重构,提取低维鉴别特征进行地物分类。在PaviaU和Indian Pines数据集上的分类结果表明,总体分类精度分别达到了98.89%和95.47%。该方法在反映影像内部流形结构的同时,有效融合了影像的空间-光谱信息,故能提高影像特征的鉴别性,并提升分类性能。     

一体化综合减灾智能服务系统研究

针对目前我国减灾服务重决策轻预警,减灾服务技术、系统、应用集成不够,尚缺乏完善的一体化综合减灾智能服务体系现状。该文从测绘地理信息视角,分析了室内外一体化应急定位、多源应急数据融合、灾害场景可视化、灾害模型分析服务等关键技术,构建了一体化综合减灾智能服务原型系统,并在国家基础地理信息中心和陕西省的相关应急部门进行了实际应用,实现了应急信息的一体化感知、定位、融合、分析、服务,为我国综合减灾决策分析提供了技术支撑。     

国内外防灾减灾科技应用的思考

我国是世界上自然灾害最严重的国家之一,依靠科技进步来提高全国防灾减灾的综合能力已成为防灾减灾工作的重要内容之一。介绍了国内外防灾减灾领域科技应用与建设的现状,讨论了我国在这方面存在的主要问题;总结了国内外防灾减灾领域科技支撑建设的经验与启示,提出了增强我国防灾减灾领域科技应用能力的措施及建议。