应力腐蚀开裂的一种概率竞争机制

１９９８年１月,采用极化曲线,慢应变速率及扫描电镜等试验技术,研究了奥氏体不锈钢的应力腐蚀开裂。结果表明,奥氏体不锈钢在酸性氯离子溶液中处于活性阳极溶解状态,但去发生应力腐蚀开裂,其断口形貌具有解理特征。这种ＳＣＣ无法用钝化膜破裂一再钝化理论和氢脆理论解释。本文以阳极溶解和表变的相互作用,激光散斑干涉术对裂纹尖端应变行为的测量,断口形貌观察等实验结果为基础,结合韧性和脆性断裂概率竞争的观点,提出了     

Effect of Sacrificial Anode Protection for Steel Pipe Piles at Dandong Port

The sacrificial anode protection system for the steel pipe piles of the 3rd berth of Dandongwharf at Dandong port has operated for eight years.In this paper,the program design and the protectioneffect of the sacrificial anode protection system are presented.The results of various,inspections show thatthe piles are protected very satisfactorily.     

非对称局部壁厚减薄海底管道的屈曲分析

在深海环境中,海底管线不仅承受较高外压,还会因为海水及运输介质的常年侵蚀而形成腐蚀缺陷,而腐蚀缺陷往往会导致管道的外压承载力下降。基于壳体稳定性理论,建立了含有非对称局部壁厚减薄管道在外压作用下的屈曲压力理论公式。公式具有广泛的适用性,当内、外局部壁厚减薄深度相等时,可用于计算含有对称局部壁厚减薄管道屈曲压力,而当内部或外部缺陷深度为零时,便可用于计算只含外部或者内部腐蚀缺陷的管道屈曲压力。通过有限元分析验证了该公式的正确性,结果表明公式可以准确预测不同缺陷位置及尺寸时管道的屈曲压力。详细研究了局部壁厚减薄缺陷位置、长度和深度等参数对屈曲压力的影响。研究表明,局部腐蚀对管道的屈曲压力产生重要影响,尤其当腐蚀角度和深度较大时,在腐蚀形成初期就会造成管道的承载力急剧下降,并且管道的屈曲压力与缺陷的径向位置有关,腐蚀缺陷位于管道外侧时的屈曲压力明显大于其位于管道内侧时的屈曲压力。     

反应位移法在埋地腐蚀管线抗震分析中的应用

埋地管线作为油、气、水等的传输载体,是地下工程的重要设施之一。埋地管线特别是金属管线容易发生腐蚀现象,在地震灾害的影响下,含有腐蚀缺陷的管线容易发生泄漏和断裂事故,造成巨大的资源浪费和环境污染等损失。因此埋地腐蚀管线抗震性能研究的重要性也越发凸显。本文以埋地腐蚀管线为研究对象,探索管线腐蚀深度、宽度、腐蚀位置和腐蚀管线埋深等腐蚀参数对管线抗震性能的影响,旨在为管线的安全性和实用性提供理论参考,对管线是否继续使用、维护或更换和安全生产提供指导,以及为管线的抗震设计提供基础研究。本文运用反应位移法在有限元软件ANSYS上实现各参数下的埋地腐蚀管线的地震响应分析。     

Seismic Collapse Performance of Jacket Offshore Platforms with Time-Variant Zonal Corrosion Model

Corrosion of offshore platforms is inevitable. In an ocean corrosion environment, the strength of a platform is weakened greatly. When simultaneously subjected to earthquakes or other extreme loads, the ultimate bearing capacity of the corroded platform is dramatically reduced, resulting in compounded damage from both corrosion and earthquake. Thus, the influence of corrosion cannot be neglected in the seismic performance investigation of platforms. The commonly used corrosion model in platform design is uniform corrosion, and the corrosion rate rule for any parts or zones in a platform is the same. In real cases, however, there are significant differences between the corrosion characteristics in different parts of a platform. Based on theoretical aspects and measured data, a zonal time-variant corrosion model of a platform is developed for a seismic collapse performance investigation. The pushover and incremental dynamic analysis (IDA) methods are adopted here to calculate the collapse margin ratio (CMR), there serve strength ratio (RSR) and ductility coefficient (μ) that are frequently used for the safety reserve evaluation of a platform. The failure reason and collapse probability of platforms considering different service periods are compared. The most prominent feature of the proposed time-variant zonal corrosion model is to capture potential switch of weak location and resulting failure path of corroded jacket offshore platforms although the proposed model needs further calibration by more reliable in-field measured data. As expected, corrosion can definitely cause a reduction in earthquake resistance of a jacket offshore platform, as well as ultimate deformability. The coupled effect between the time-variant vibration properties of the platform and the spectral characteristics of selected motions, the collapse-level spectral acceleration (SA) does not always decrease with increasing corrosion degree. The curves corresponding to normalized CMR and RSR agree very well with each other in the early corrosion development stage and service period beyond 30 years. Some distinct differences can be found during the two stages, with the greatest difference up to 10% for the example platform.     

海洋环境微生物腐蚀机理研究进展

微生物腐蚀(microbiologically influenced corrosion, MIC)是海洋环境中一种非常重要的腐蚀形式,其是微生物、环境、材料共同作用的结果,本文自MIC对海洋环境、菌株、材料性质的依赖性三个方面概述其机理的研究进展。在MIC对海洋环境的依赖性方面,突出溶解氧浓度和营养水平的影响规律与机制。在MIC对菌株的依赖性方面,首先介绍典型单菌株的腐蚀影响机制,然后分析混合菌株间不同菌株的腐蚀协同与拮抗作用,最后阐述复杂微生物群落的影响。在MIC对材料性质的依赖性方面,在总结基体化学成分与结构影响的基础上,介绍对MIC有抑制作用的典型表面的特性及其作用机制。     

川东北飞仙关组鲕滩储层硫酸溶蚀的证据和模式探讨

川东北飞仙关组鲕滩储层的主要储集空间为溶蚀孔洞,主要由大气淡水溶蚀作用、有机酸溶蚀作用和硫酸溶蚀作用所形成。通过硫酸对灰岩和白云岩溶蚀实验、天然气中硫化氢含量与飞仙关组石膏厚度关系分析、天然气中硫同位素与地层中的硫同位素比较、方解石胶结物的阴离子分析等证据,首次提出了硫酸溶蚀在该储层形成中起很重要的作用。探讨了硫酸溶蚀形成储层的模式。     

含辣素衍生结构疏水缔合聚合物的缓蚀性能研究

采用失重法、电化学方法以及表面观察方法对比研究了含辣素衍生结构疏水缔合聚合物P(AM-MAA-AMPSHDDE-SA)(PAMAHS)和聚丙烯酰胺对Q235钢在CO_2饱和的模拟油田采出水中的缓蚀性能。实验结果表明:相较于聚丙烯酰胺,PAMAHS对碳钢在油田水中的腐蚀具有较好的抑制作用,其缓蚀率随着聚合物浓度的增加而增大,缓蚀剂浓度为500mg·L^-1时,缓蚀效率能达到80.64%。因此,PAMAHS是一种混合抑制型缓蚀剂,其分子可以吸附在金属表面,形成一层具有保护作用的吸附膜,从而起到减缓腐蚀的作用。PAMAHS在碳钢表面的吸附行为符合Langmuir吸附等温式。     

氯离子侵蚀对钢筋混凝土构件抗力影响的研究

氯化物是钢筋混凝土结构在使用寿命期内可能遇到的一种最危险的侵蚀介质,混凝土中钢筋表面的氯离子浓度超过一定的限值,钢筋就可能会发生锈蚀,锈蚀的钢筋会导致混凝土构件的承载力下降.通过分析国内外研究者所做的大量工作,讨论了氯离子侵入引起的锈蚀钢筋混凝土构件的抗力计算方法,为氯化物环境条件下混凝土结构的耐久性评估提供参考.     

海泥中硫酸盐还原菌数量变化对主要腐蚀环境因子的影响

海泥中硫酸盐还原菌(SulfateReducingBacteria,SRB)数量的变化会对其主要腐蚀环境因子产生影响。实验室条件下,在灭菌青岛海泥中加SRB菌种得到含SRB的海泥。在SRB的一个生长周期内,测量了由SRB数量变化引起的硫电位、银电位、pH值、氧化还原电位及电导率等主要腐蚀环境因子的变化,并找出了该变化的规律,探讨了通过腐蚀环境因子的变化测量SRB数量的可能性。