船舶金属腐蚀失效与防护研究

论文对船舶金属腐蚀机理及表现、船舶结构防腐要求等问题做了探讨,对船舶防腐蚀系统进行了分类,分析了腐蚀涂层状况与检验的关系,并对涂层失效的对策和恢复涂层的要求进行了研究。     

Probabilistic seismic loss assessment of aging bridges using a component‐level cost estimation approach

Deteriorating highway bridges in the United States and worldwide have demonstrated susceptibility to damage in earthquake events, with considerable economic consequences due to repair or replacement. Current seismic loss assessment approaches for these critical elements of the transportation network neglect the effects of aging and degradation on the loss estimate. However, the continued aging and deterioration of bridge infrastructure could not only increase susceptibility to seismic damage, but also have a significant impact on these economic losses. Furthermore, the contribution of individual aging components to system‐level losses, correlations between these components, and uncertainty modeling in the risk assessment and repair modeling are all crucial considerations to enhance the accuracy and confidence in bridge loss estimates. In this paper, a new methodology for seismic loss assessment of aging bridges is introduced based on the non‐homogeneous Poisson process. Statistical moments of seismic losses can be efficiently estimated, such as the expected value and variance. The approach is unique in its account for time‐varying seismic vulnerability, uncertainty in component repair, and the contribution of multiple correlated aging components. A representative case study is presented with two fundamentally distinct highway bridges to demonstrate the effects of corrosion deterioration of different bridge components on the seismic losses. Using the proposed model, a sensitivity study is also conducted to assess the effect of parameter variations on the expected seismic losses. The results reveal that the seismic losses estimated by explicitly considering the effects of deterioration of bridge components is significantly higher than that found by assuming time‐invariant structural reliability. Copyright © 2011 John Wiley & Sons, Ltd.     

Life‐cycle reliability of RC bridge piers under seismic and airborne chloride hazards

Over the last two decades, the probabilistic assessment of reinforced concrete (RC) structures under seismic hazard has been developed rapidly. However, little attention has been devoted to the assessment of the seismic reliability of corroded structures. For the life‐cycle assessment of RC structures in a marine environment and earthquake‐prone regions, the effect of corrosion due to airborne chlorides on the seismic capacity needs to be taken into consideration. Also, the effect of the type of corrosive environment on the seismic capacity of RC structures has to be quantified. In this paper, the evaluation of the displacement ductility capacity based on the buckling model of longitudinal rebars in corroded RC bridge piers is established, and a novel computational procedure to integrate the probabilistic hazard associated with airborne chlorides into life‐cycle seismic reliability assessment of these piers is proposed. The seismic demand depends on the results of seismic hazard assessment, whereas the deterioration of seismic capacity depends on the hazard associated with airborne chlorides. In an illustrative example, an RC bridge pier was modeled as single degree of freedom (SDOF). The longitudinal rebars buckling of this pier was considered as the sole limit state when estimating its failure probability. The findings show that the life‐cycle reliability of RC bridge piers depends on both the seismic and airborne chloride hazards, and that the cumulative‐time failure probabilities of RC bridge piers located in seismic zones can be dramatically affected by the effect of airborne chlorides. Copyright © 2011 John Wiley & Sons, Ltd.     

硫酸盐热化学还原作用对原油裂解成气和碳酸盐岩储层改造的影响及作用机制

硫酸盐热化学还原作用(Thermochemical sulfate reduction, TSR)是发生在油气藏中复杂的有机-无机相互作用,它不仅会引起含H₂S天然气的富集,其产生的酸性气体对碳酸盐岩储层还具有明显的溶蚀改造作用。本文基于黄金管热模拟实验,研究了TSR反应对原油裂解气的生成的影响,发现这种氧化还原反应的存在能明显降低原油的稳定性,促进具高干燥系数的含H₂S天然气的生成。结合原位激光拉曼实验结果,证实了实际油藏中启动TSR反应的最可行的氧化剂应该是硫酸盐接触离子对(CIP)。全面探讨了影响TSR反应的地质和地球化学因素,提出除了初始原油的组分特征、不稳定含硫化合物(LSC)的含量外,地层水的含盐类型及盐度同样是控制TSR反应的关键因素。同时,基于大量地质分析,发现TSR对碳酸盐岩储层具有明显的溶蚀改造作用。结合溶蚀模拟实验,提出了酸性流体对碳酸盐储层溶蚀改造的机制,且深层碳酸盐岩层存在一个由TSR作用形成的次生孔隙发育带。研究认为,烃类与硫酸盐矿物的氧化还原反应与其产物对碳酸盐岩储层的改造是TSR作用的两个不可分割的部分,它们相互依存和制约。     

Probabilistic lifetime assessment of marine reinforced concrete with steel corrosion and cover cracking

In order to study the durability behavior of marine reinforced concrete structure suffering from chloride attack,the structural service life is assumed to be divided into three critical stages,which can be characterized by steel corrosion and cover cracking.For each stage,a calculated model used to predict the lifetime is developed.Based on the definition of durability limit state,a probabilistic lifetime model and its time-dependent reliability analytical method are proposed considering the random natures of influencing factors.Then,the probabilistic lifetime prediction models are applied to a bridge pier located in the Hangzhou Bay with Monte Carlo simulation.It is found that the time to corrosion initiation t0 follows a lognormal distribution,while that the time from corrosion initiation to cover cracking t1 and the time for crack to develop from hairline crack to a limit crack width t2 can be described by Weibull distributions.With the permitted failure probability of 5.0%,it is also observed that the structural durability lifetime mainly depends on the durability life t0 and that the percentage of participation of the life t0 to the total service life grows from 61.5% to 83.6% when the cover thickness increases from 40 mm to 80 mm.Therefore,for any part of the marine RC bridge,the lifetime predictions and maintenance efforts should also be directed toward controlling the stage of corrosion initiation induced by chloride ion.     

蒸馏海水淡化产品水对铸铁材质腐蚀研究

分析了多级闪蒸海水淡化产品水水质特点,研究了淡化水对铸铁管网的腐蚀影响.利用稳定指数法、失重法、电化学分析和腐蚀产物的XRD检测等方法开展了实验研究.实验结果显示了淡化水对铸铁试片的腐蚀程度及淡化水对铸铁腐蚀产物的类型,可为淡化水进入市政管网提供参考.     

人工冻结梁构件中不同加筋作用的对比试验研究

考虑土层冻结构件中冻结管的加筋作用,对于增加冻结构件强度,减小变形量,提高人工冻结支护工程经济效益有重要作用。为研究冻结管对人工冻结构件的加筋作用,通过淤泥质粘土人工冻结梁构件三点弯试验,获得了各级载荷下构件的位移值。根据对冻土梁加筋与否,构件特定力学响应的比较,完成了冻结管加筋作用的量化分析。     

Research on Corrosion Effect of Sulfate Ions on Concrete Under Wetting-Drying Cycle

Saline soil is widely distributed in the marine sediments along the coast of the world and the arid-semi-arid areas of the Middle East and Iraq,and calcium sulfate erosion has become one of the important factors affecting the durability of concrete in this area.In order to clarify the mechanism of sulfate ion damage to concrete,this paper mainly takes saline soil with high sulfate content in coastal area as well as arid-semi-arid area as the research object,and uses indoor geotechnical test,field test and numerical simulation to study the influence of different dry-wet cycle times on the unconfined compressive strength of concrete test blocks,and puts forward the relationship between the erosion arrival depth and time of sulfate ion in concrete,so as to predict the long-term erosion depth by using the erosion depth of sulfate ion in concrete in short time.The results show that the shorter the erosion time when the erosion reaches a certain depth,and the larger the erosion reaches when the erosion time is the same,the faster the erosion reaches the depth with the increase of erosion time.Compared with rectangular section concrete,circular section concrete penetrates faster.The results of this study can provide a reference for the durability design of concrete in saline soil sites containing sulfate.     

克拉玛依油田二厂八区套管破损机制研究

克拉玛依油田二厂八区井区经过长期开采出现了大量的套管破损问题。对套管破损位置进行总结归纳发现,套管破损主要存在于白垩系吐谷鲁群、侏罗系齐古组、二叠系乌尔禾组等地层中。对研究区连井进行地层对比、地震数据体进行波阻抗反演和砂体分析,发现研究区内白垩系吐谷鲁群和侏罗系齐古组的砂体十分发育,广泛存在于整套地层中。砂体中流体的渗流作用对套管的腐蚀为套管破损的主要因素。泥岩吸水蠕变膨胀、油层出砂和固井质量不合格为套管破损的其他因素。     

Condensation water in heritage touristic caves: Isotopic and hydrochemical data and a new approach for its quantification through image analysis

Condensation water is a major factor in the conservation of heritage caves. It can cause dissolution of the rock substrate (and the pigments of rock art drawn on it) or covering thereof with mineral components, depending on the chemical saturation degree of the condensation water. In show caves, visitors act as a source of CO₂ and thus modify the microclimate, favouring negative processes that affect the conservation of the caves. In spite of their interest, studies of the chemical composition of this type of water are scarce and not very detailed. In this work we present research on the condensation water in the Nerja Cave, one of the main heritage and tourist caves in Europe. The joint analysis of isotopic, hydrochemical, mineralogical and microbiological data and the use of image analysis have allowed us to advance in the knowledge of this risk factor for the conservation of heritage caves, and to demonstrate the usefulness of image analysis to quantify the scope of the possible corrosion condensation process that the condensation water could be producing on the bedrock, speleothem and rock art. To our knowledge, this application of image analysis (relative to the condensation water in caves) is the first one of this type that has been documented.