北祁连山早古生代硅质岩稀土元素特征及构造环境意义

通过对北祁连山不同地质环境中的与火山岩相伴生的硅质岩稀土元素特征的分析,证明产于不同地质环境硅质岩的稀土元素特征,特别是稀土元素总量w( REE)、w(Ce)/w(Ce*)、w(LaN)/w(YbN)具有特定的规律性变化:从洋中脊→弧后盆地→岛弧→裂隙式火山作用大陆裂谷→中心式火山作用大陆裂谷,硅质岩的w( REE)、w(Ce)/w(Ce*)、w(LaN)/w(YbN)基本呈由小到大的规律性变化,w( REE)由7.64×10-6→8.20×10-6→23.74×10-6→28.40×10-6→69.41×10-6;w(Ce)/w(Ce*)由0.63→0.68→0.72→0.75→0.95;w(LaN)/w(YbN)由0.37→0.41→0.59→0.76→1.08。该研究成果为利用硅质岩稀土元素特征判定古老造山带的构造环境提供了参考标准。     

Organic Material and Trace Elements of Bituminous Rocks in the Ozankiiy Field, Ankara, Turkey

Bituminous rocks in the Ozankoey （Ankara） field are different from those of the Paleocene- Eocene Mengen and Giineytepe （Bolu） regions in metal enrichment levels. Organic carbon （Corg） content of organic material-rich rocks in the Ozankoey （Ankara） field is 3.66-40.72% wt averaging 14.34%. The dominant organic materials are algae/amorphous accompanied by minor amount of herbaceous material （The dominant kerogen type is Type-I with a limited amount of Type-Ⅱ kerogen.）. The bituminous rocks in the Ozankoey field are enriched in heavy metals such as Ni, Mn, As and Cr. In comparison with the average enrichment values of dements, Ni, Mn, As and Cr in bituminous shales of the Ozankoey field are as about 4.38, 14.93, 10.90 and 5.58 times as average values. The average concentrations of these heavy metals are also as high as 215× 10^-6, 828 × 10^-6, 58.54 × 10^-6, and 148 × 10^-6 respectively. In addition, sorption properties of day and organic materials are also important for metal enrichments in the bituminous shales.     

Organic Material and Trace Elements of Bituminous Rocks in the Ozank(?)y Field,Ankara,Turkey

Bituminous rocks in the Ozank(?)y(Ankara) field are different from those of the Paleocene- Eocene Mengen and Güineytepe(Bolu) regions in metal enrichment levels.Organic carbon(C_(org)) content of organic material-rich rocks in the Ozank(?)y(Ankara) field is 3.66-40.72% wt averaging 14.34%.The dominant organic materials are algae/amorphous accompanied by minor amount of herbaceous material(The dominant kerogen type is Type-Ⅰwith a limited amount of Type-Ⅱkerogen.). The bituminous rocks in the Ozank(?)y field are enriched in heavy metals such as Ni,Mn,As and Cr.In comparison with the average enrichment values of elements,Ni,Mn,As and Cr in bituminous shales of the Ozank(?)y field are as about 4.38,14.93,10.90 and 5.58 times as average values.The average concentrations of these heavy metals are also as high as 215×10~(-6),828×10~(-6),58.54×10~(-6),and 148×10~(-6) respectively.In addition,sorption properties of clay and organic materials are also important for metal enrichments in the bituminous shales.     

Late Miocene–Pliocene eclogite facies metamorphism, D'Entrecasteaux Islands, SE Papua New Guinea

The D'Entrecasteaux Islands of south‐eastern Papua New Guinea are active metamorphic core complexes that formed within a region where the plate tectonic regime has transitioned from subduction to rifting. While rapid, post 4 Myr exhumation and cooling of amphibolite and greenschist facies rocks that constitute the footwall of the crustal scale detachment fault system have been previously documented on Fergusson and Goodenough Islands of the D'Entrecasteaux chain, the timing of eclogite facies metamorphism in rocks of the footwall was unknown. Recent work revealed that at least one of the eclogite bodies formed during the Pliocene. We present combined in situ ion microprobe U–Pb age analyses of zircon from five variably retrogressed eclogite samples from Fergusson and Goodenough Islands that document Late Miocene–Pliocene (8–2 Ma) eclogite formation on these islands. Textural relationships and zircon–garnet rare earth element partition coefficients indicate that U–Pb ages constrain zircon crystallization under eclogite facies conditions in all samples. Results suggest westward younging of eclogite facies metamorphism from Fergusson to Goodenough Island. Present‐day exposure of Late Miocene–Pliocene eclogites requires exhumation rates > 2.5 cm yr^?1.     

秦岭珍稀濒危植物资源的利用价值与保护

秦岭分布着国家保护的珍稀濒危植物４２种,其中属国家一级保护１种,二级保护１５种,三级保护２６种．这些珍稀濒危植物在医药、木材、花卉、化工等方面具有较高的开发利用价值     

低温对玉米种子发芽的影响

通过发芽试验研究了东北地区早、中、晚熟３个玉米品种在４℃、８℃、１３℃、１７℃、２１℃和２５℃黑暗条件下的发芽率、发芽势和发芽指数;并求出不同品种的发芽临界温度。结果表明,低温抑制了种子发芽,降低了发芽能力;３个品种发芽的临界温度为３．２￣５．２℃。发芽临界温度愈低,种子的耐低温发芽能力愈强。稀土浸种有提高玉米种子发芽率和促进发芽的作用。     

贵州织金地区稀土磷块岩矿床中稀土元素赋存状态

以稀土磷块岩矿床为研究对象,采用电感耦合等离子体光谱法和质谱法研究了3个代表性样品的基本化学组成,分析了40多个元素的含量,确定了矿物质量分数和赋存状态,研究了稀土元素在其中的分布特征。结果表明,97%以上的稀土元素呈类质同象状态部分置换磷灰石晶格中的Ca2 存在,只有小于3%的稀土元素呈被粘土质等吸附状态或离子交换(吸附)状态存在。     

Molecular and distribution data on the poorly known,elusive, cave mysid Harmelinella mariannae (Crustacea: Mysida)

Mediterranean underwater marine caves harbour abundant populations of several species of mysids that are increasingly used as biological models in ecological and evolutionary studies. One exception is the species Harmelinella mariannae, described in 1989 and then hardly ever again reported in the literature. We here provide the first data on the distribution of this poorly known taxon that, contrary to expectations for a rare brooding cave dweller, we now report from Madeira Island in the nearby Atlantic, to the easternmost parts of the Mediterranean. Brief behavioural observations are added, particularly its atypical solitary habits and its feeding behaviour as a high trophic level carnivore. Molecular characterization of the different specimens captured provided three sorts of information. Mitochondrial COI and 16S haplotypes suggest different colonization waves in the Mediterranean, with one group in the Eastern Basin, two in the Marseille region in the NW part of this sea, and another group with a very wide extension from Madeira to Liguria and Malta. Mitochondrial data also support that one of the groups in Marseille might have diverged as a cryptic species of Harmelinella. 18S rRNA gene displays a single common sequence to all specimens from the four groups, and seems to confirm the original proposed placement of this taxon within the subfamily Heteromysinae, not Leptomysinae.     

富钴结壳中矿物组成对稀土元素分布的制约

为探讨富钴结壳中矿物组成对稀土元素分布的制约,对约翰斯顿岛富钴结壳中矿物组成及稀土元素特征进行了研究。依据主要矿物组成,富钴结壳可以分为3种类型,分别命名为A、B、C。由A到C,水羟锰矿含量逐渐降低,B类中磷灰石含量最高,C类中水钠锰矿和钙锰矿含量最高。A类结壳中富集REE3+、Ce,B类结壳中富集Ce和Y。A类富钴结壳中,REE3+、Y以专属吸附的方式富集在铁氧化物上,Ce3+氧化成Ce4+与其他REE分离,吸附在锰矿物上。B类结壳中,稀土元素主要以独立矿物的形式存在,另有部分Ce、LREE3+吸附于铁相中,部分Y存在于磷灰石中。C类结壳中,稀土元素主要赋存在锰矿物中,部分Y存在于磷灰石中。     

江西宜丰同安花岗细晶岩年代学及其成因研究

燕山期甘坊复式岩体是宜丰锂铌钽稀有金属矿田重要的赋矿岩体,细晶岩作为甘坊岩体晚阶段岩浆演化的产物,与区内细晶岩型稀有金属成矿作用关系密切,但前人对该类岩石及其成矿作用特征研究较薄弱。本文以甘坊岩体南侧同安矿区内的花岗细晶岩为研究对象,对其展开系统的岩相学、锡石U-Pb年代学和全岩地球化学分析。锡石U-Pb定年结果表明,同安花岗细晶岩形成时代为138.3 Ma。全岩地球化学分析结果显示,该类岩石具高磷铝、富碱钙、贫镁铁钛的特征,且A/CNK值(1.71～1.88)较高,σ值(1.40～1.72)较低,属于典型的强过铝质、高钾钙碱性岩石。全岩微量及稀土元素成分显示,同安花岗细晶岩具有稀土元素强烈亏损,相对富集Rb、U、Nb、Ta、Pb、P、Hf和明显亏损Ba、Th、Sr、Ti等元素的特征。综上所述,同安花岗细晶岩属高分异的S型花岗岩,来源于地壳浅部变沉积岩物质的部分熔融。在演化过程中,经历过早期高度结晶分异过程和晚期的岩浆-热液相互作用,其中早期的高度结晶分异过程对Li成矿起到了初始富集的作用,而演化晚期的岩浆-热液相互作用才是Li元素高度富集并成矿的关键。