Sub-arcsec 10 μm imaging of β pictoris and other star disk candidates

We have used the ESO 10 m camera, TIMMI, to image with a very high angular resolution (PFoV: 0.3; FWHM:0.9) several main-sequence star disk candidates. Information on the -Pictoris dust disk has been obtained in a region largely inaccessible to previous observations: 0–80 AU, with a resolution of about 5 AU after deconvolution. Another promising target for 10 m imaging, 51 Ophiuchi, appears point-like.based on data collected at the European Southern Observatory (ESO), La Silla, Chile     

Laboratory study of the rates and products of the phototransformations of naphthalene adsorbed on samples of titanium dioxide,ferric oxide,muscovite, and fly ash

The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO₂, Fe₂O₃, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO₂ (mainly anatase, nonporous, 50 m² g^–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm^–2 h^–1 (>340 nm, radiant fluxca. 22 mW cm^–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O₂. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO₂, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe₂O₃. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO₂. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.     

On the pH-dependent formation constants of iron(III)-sulfur(IV) transient complexes

An experimental study is described of Fe(III)-S(IV) formation constants measured as a function of pH (1–3), ionic strength (0.2–0.5 M) and [Fe(III)] _T (2.5–5.0×10^–4 M) using a continuous-flow spectrophotometric technique to make observations 160 ms after mixing. Preliminary experiments using pulse-accelerated-flow (PAF) spectrophotometry to measure rate constants on a microsecond timescale are also described. The conditional formation constant at 25 °C can be modeled with the following equation: {ie307-1} where {ie307-2}K ₇ andK ₈ can be interpreted as intrinsic constants for the coordination of HSO ₃ ^– by FeOH²⁺ and Fe³⁺, respectively, but until further evidence is obtained they should be regarded as fitting constants. PAF spectrophotometry showed that the initial reaction of Fe(III) with S(IV) (pH 2.0) is characterized by a second-order rate constant of 4×10⁶ M^–1 s^–1 which is comparable to rate of reaction of FeOH²⁺ with SO ₄ ^2– . However, the PAF results should be regarded as preliminary since unexpected features in the initial data indicate that the reaction may be more complex than expected.     

矿产预测中成矿信息的提取和强化

成矿信息的提取是矿产预测的重要手段,其方法的有效性直接影响到预测成果的可靠性。在成矿规律研究的基础上,有意识地干预模型的构成,突出与成矿有关的信息;抑制某些成矿意义不明显和属干扰的信息,有目的地使模型向反映成矿信息的方向逼近,提高模型与矿床实际赋存地质环境的吻合程度,均是成矿信息提取和强化的内涵。本文从研究实践中总结了先验约束模型和非先验约束模型的强化方法,在新疆阿勒泰地区的地质－找矿工作中已取得     

极性转换期间地球磁场形态学研究

本文对采自中国黄土高原西峰（35.7°N,107.6°E）和段家坡（34.2°N,109.2°E）两个剖面中黄土层L8和古土壤层S8的1281块定向古地磁样品做了详细的岩石磁学和古地磁学研究.证实了Matuyama-Brunhes（M-B）极性转换带位于L8的中下部.提出了下列观点:1.M-B极性转换过程与地球磁场方向变化相联系的持续时间为3600-4500a,而与地球磁场强度变化相联系的持续时间则为8000-9000a,即强度变化存在“超前和滞后” 效应;2.M-B转换场的形态是由三次快速倒转和一次不成功的倒转构成,或者说,转换场具有快速变换极性的振荡特征;3.M-B转换过程中地球磁场并不是以轴对称的非偶极子场为主,而是偶极子场至少与非偶极子场相当;4.中国黄土-古土壤沉积物所含磁性矿物的主要成分是磁铁矿,它是研究极性转换期间地球磁场详细结构的良好物质.     

Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

首都减灾圈的思考与建议

首都减灾圈,系首都减轻自然灾害预测防治圈。1991年12月20—21日在北京召开了《首都圈自然灾害及其减灾对策研讨会》。本文根据这次会议所提供的材料,在从整体上实现减灾的思想指导下,就首都减灾圈的“成灾背景”、“首都减灾圈的组成”、“首都减灾圈的灾害预测与防治状况”、“首都减灾圈的灾害关联性分析”、“首都减灾圈的减灾实效预估”和“首都减灾圈的减灾对策与实施”等六个带有共同性的问题,进行了讨论。供制定首都圈减灾方案时参考。     

大别杂岩中混合岩的矿物空间分布研究

介绍了矿物空间分布研究的基本原理及两种统计方法(接触频数法和线切法)。作者对混合岩矿物空间分布的研究表明:(1)前人提出的统计方法存在方法上的缺陷和应用上的局限性,作者推导出矿物接触类型的概率公式;(2)部分浅色体中矿物显示聚集分布的特征,而绝大部分的浅色体中矿物具有分散分布的特点。结合质量平衡和地球化学研究认为:大别杂岩中主体混合岩成因机制是重熔和交代作用。     

安徽巢湖大型平卧褶皱研究

巢湖平卧褶皱由一个背斜和一个向斜组成,枢纽呈NNE向,轴面微向NWW平卧背斜根部倾斜。卷入褶皱的地层为上震旦统至上三叠统,厚达3.1km。褶皱分布面积约380km~2,波长9km,波幅18km。后期直立褶皱叠加于平卧褶皱之上,褶皱缩短量达19.17km,缩短率约53.7％,褶皱受控于大玵台阶状滑脱断层。褶皱地层由NWW往SEE运动,是一种变动滑脱褶皱。     

The arrangement in mean elements space of the periodic orbits close to that of the Moon

In a simplified model of the Earth-Moon-Sun system based on the restricted circular 3-dimensional 3-body problem, it is possible to find numerically a set of 8 periodic orbits whose time evolutions closely resemble that of the Moon's orbit. These orbits have a period of 223 synodic months (i.e. the period of the Saros cycle known for more than two millennia as a means of predicting eclipses), and are characterized by a secular rotation of the argument of perigee . Periodic orbits of longer durations exhibiting this last feature are very abundant in Earth-Moon-Sun dynamical models. Their arrangement in the space of the mean orbital elements- for various values of the lunar mean motion is presented.