傅立叶变换红外光谱联用技术在化石燃料分析中的应用

对傅立叶变换红外光谱联用技术在化石燃料分析中的应用进行了较全面的总结评述,重点介绍了气相色谱／红外光谱联机、高压液相色谱／红外光谱联机、薄层色谱／红外光谱联机、超临界流体色谱／红外光谱联机、裂解色谱／红外光谱联机、热重分析／红外光谱联机、气相色谱／红外光谱／质谱三机联用技术等在化石燃料的结构组分分析、成因机理研究及其勘探等诸方面的重要应用,尤其是在芳香族化合物和几何异构体的分离鉴定方面发挥出的突出功效。引用文献５９篇。     

Inversion, error analysis, and validation of GPS/MET occultation data

The global positioning system meteorology (GPS/MET) experiment was the first practical demonstration of global navigation satellite system (GNSS)-based active limb sounding employing the radio occultation technique. This method measures, as principal observable and with millimetric accuracy, the excess phase path (relative to propagation in vacuum) of GNSS-transmitted radio waves caused by refraction during passage through the Earth’s neutral atmosphere and ionosphere in limb geometry. It shows great potential utility for weather and climate system studies in providing an unique combination of global coverage, high vertical resolution and accuracy, long-term stability, and all-weather capability. We first describe our GPS/MET data processing scheme from excess phases via bending angles to the neutral atmospheric parameters refractivity, density, pressure and temperature. Special emphasis is given to ionospheric correction methodology and the inversion of bending angles to refractivities, where we introduce a matrix inversion technique (instead of the usual integral inversion). The matrix technique is shown to lead to identical results as integral inversion but is more directly extendable to inversion by optimal estimation. The quality of GPS/MET-derived profiles is analyzed with an error estimation analysis employing a Monte Carlo technique. We consider statistical errors together with systematic errors due to upper-boundary initialization of the retrieval by a priori bending angles. Perfect initialization and properly smoothed statistical errors allow for better than 1 K temperature retrieval accuracy up to the stratopause. No initialization and statistical errors yield better than 1 K accuracy up to 30 km but less than 3 K accuracy above 40 km. Given imperfect initialization, biases ≫ 2 K propagate down to below 30 km height in unfavorable realistic cases. Furthermore, results of a statistical validation of GPS/MET profiles through comparison with atmospheric analyses of the European Centre for Medium-range Weather Forecasts (ECMWF) are presented. The comparisons indicate the high utility of the occultation data in that very good agreement of upper troposphere/lower stratosphere temperature (better than 1.5 K rms, ≪ 0.5 K bias) is found for a region (Europe+USA) where the ECMWF analyses are known to be good, but poorer agreement for a region (Southern Pacific) where the analyses are known to be degraded.     

Sodium beacon tip–tilt determination with Rayleigh-aided auxiliary telescope technique

The usefulness of tracking the Rayleigh portion of a mesospheric sodium laser guide star as reference for absolute tip–tilt recovery in the frame of the auxiliary telescopes technique is shown. This approach leads to the reduction of the ground occupation needed to attain a given sky coverage by more than one order of magnitude. Speed, tracking precision, and the number of auxiliary telescopes are also reduced, making this new approach a more attractive one. The use of a low-altitude Rayleigh spot reinforces the fundamental limitations affecting this and other techniques, thus degrading significantly the quality of the recovered tip–tilt. However, it is shown that, provided adequate care is taken in the collection and treatment of data, an interesting tilt signal can still be retrieved.     

Interferometer phase calibration sources — II. The region 0° ≤ δB1950≤ +20°

We present a catalogue of 781 compact radio sources in the declination range 0° ≤ δ_B1950≤ +20° whose positions have been measured to an rms accuracy of about 14 mas with the Very Large Array (VLA). These sources are primarily intended for use as phase calibration sources for the Jodrell Bank MERLIN. However, they will also be suitable as phase calibrators for the VLA and can be considered as candidate phase calibrators for very long-baseline interferometry (VLBI) networks.     

技术方法的进步与地球科学的发展

地球科学作为自然科学的一大门类,其发展速度十分惊人。地球科学的迅速发展一方面反映了人类生产的发展对资源和环境方面愈来愈高的要求,一方面得益于科学技术的普遍发展为地球科学研究提供的越来越有利的条件。关于技术方法对地球科学研究的推动作用,人们早有认识,而现在更为深刻。当今对地球科学研究影响最大的关键技术,包括空间技术,深部探测技术,高新分析测试技术和数据综合分析技术,均来源于现代科学技术的最新发展。为了推动地球科学研究,不但要注意引进各种高新技术,还要注意将这些技术与地学研究相结合,发展和创造适合于地学研究的高新技术,并善于综合应用它们,使它们在地学研究中发挥最有效的作用。     

On the frequency and amplitude variations of the δ Scuti star CD−24 7599 (=XX Pyx)

We present 132 h of new time-series photometric observations of the δ Scuti star CD−24 7599 acquired during 86 nights from 1993 to 1996 to study its frequency and amplitude variations. By using all published observations we demonstrate that the three dominating pulsation modes of the star can change their photometric amplitudes within one month at certain times, while the amplitudes can remain constant within the measurement errors at other times. CD−24 7599 also exhibits frequency variations, which do not show any correspondence between the different modes.   The typical time-scale for the amplitude variations is found to be several hundred days, which is of the same order of magnitude as the inverse linear growth rates of a selected model. We find no evidence for periodic amplitude modulation of two of the investigated modes ( f ₂ and f ₃), but f ₁ may exhibit periodic modulation. The latter result could be spurious and requires confirmation. The observed frequency variations may either be continuous or reflect sudden frequency jumps. No evidence for cyclical period changes is obtained.   We exclude precession of the pulsation axis and oblique pulsation for the amplitude variations. Beating of closely spaced frequencies cannot explain the amplitude modulations of two of the modes, while it is possible for the third. Evolutionary effects, binarity, magnetic field changes or avoided crossings cannot be made responsible for the observed period changes. Only resonance between different modes may be able to explain the observations. However, at this stage a quantitative comparison is not possible. More observations, especially data leading to a definite mode identification and further measurements of the temporal behaviour of the amplitudes and frequencies of CD−24 7599, are required.     

'Stokes imaging' of the accretion region in magnetic cataclysmic variables — I. Conception and realization

Modelling the polarized cyclotron emission from magnetic cataclysmic variables has been a pivotal technique for determining the structure of the accretion zones on the white dwarf. To date, model solutions have been obtained from trial fits to the intensity and polarization data, which have been constructed from emission regions (for example arcs and spots) put in by hand. These models were all inferred indirectly from arguments based on the polarization and X-ray light curves.   We present a more analytical and objective technique using optimization by a genetic algorithm, Tikhonov regularization and Powell's method that robustly models the details of polarized emission.   To demonstrate the success of this technique, we show the results of several simulations in which we calculated the intensity and polarization curves from arbitrarily shaped emission regions on the surface of a sphere and then applied our code to these curves to recover the original test data. We also show how adding artificial noise affects the outcome of the optimization technique.     

Semi-automated extraction of digital objective prism spectra

We describe a method for the extraction of spectra from high-dispersion objective prism plates. Our method is a catalogue-driven plate solution approach, making use of the right ascension and declination coordinates for the target objects. In contrast to existing methods of photographic plate reduction, we digitize the entire plate and extract spectra off-line. This approach has the advantages that it can be applied to CCD objective prism images and spectra can be re-extracted (or additional spectra extracted) without having to re-scan the plate. After a brief initial interactive period, the subsequent reduction procedure is completely automatic, resulting in fully reduced, wavelength-justified spectra. We also discuss a method of removing stellar continua using a combination of non-linear filtering algorithms.   The method described is used to extract over 12 000 spectra from a set of 92 objective prism plates. These spectra are used in an associated project to develop automated spectral classifiers based on neural networks.     

Foreground separation methods for satellite observations of the cosmic microwave background

A maximum entropy method (MEM) is presented for separating the emission resulting from different foreground components from simulated satellite observations of the cosmic microwave background radiation (CMBR). In particular, the method is applied to simulated observations by the proposed Planck Surveyor satellite. The simulations, performed by Bouchet &38; Gispert, include emission from the CMBR and the kinetic and thermal Sunyaev–Zel'dovich (SZ) effects from galaxy clusters, as well as Galactic dust, free–free and synchrotron emission. We find that the MEM technique performs well and produces faithful reconstructions of the main input components. The method is also compared with traditional Wiener filtering and is shown to produce consistently better results, particularly in the recovery of the thermal SZ effect.     

Precise laboratory wavelengths of the Mg I and Mg II resonance transitions at 2853, 2803 and 2796 Å

Strong ultraviolet resonance transitions are observed routinely both in the Galactic interstellar medium and in quasar absorption systems. The quality of the astronomical spectroscopic data now available demands more precise laboratory rest wavelengths. Of particular interest is the accuracy with which one can constrain space–time variations in fundamental constants using quasar spectra. A recent analysis by Webb et al. of 25 quasar spectra using Mg and Fe transitions tentatively suggests that the fine-structure constant was smaller at earlier epochs. To permit a check on this result, and to allow further more extensive investigations, we have carried out a new determination of the laboratory wavelengths of Mg  i  2853 Å, Mg  II  2796 Å and Mg  II  2803 Å by high-resolution Fourier transform spectroscopy. Our results for Mg  II  2796 Å are consistent with the value measured independently by two other groups. To our knowledge, no previous measurements of comparable precision exist for Mg  I  2853 Å and Mg  II  2803 Å.