Long-Term Measurements of Light Hydrocarbons (C2–C5) at Schauinsland (Black Forest)

Long-term measurements of light hydrocarbons(C₂–C₅ HCs) were performed in the courseof the EUROTRAC sub-project TOR (Tropospheric Ozone Research) in thesouthern part of the Black Forest in southwest Germany. The measurementscover a time period of five years (January 1989–January 1994) and theair samples were analyzed onsite by an automated GC-system. Pronouncedannual cycles with maxima in late winter and minima in late summer wereobserved in the case of the slowly reacting hydrocarbons ethane, propane andacetylene, reflecting the fact that the seasonal variation of these speciesis photochemically driven. For the shorter lived compounds the seasonalvariations are considerably weaker, connected with a stronger scatter of theindividual measurements, which is caused by different distances to theirmain sources for different wind vectors as well as by varying sourcestrengths. From a detailed characterization of the hydrocarbon patterns theinfluence of two different sources could be distinguished. An extrapolationto photochemical age of zero and completion of our data with those from aspeciated VOC inventory yields an estimated [VOC]/NO_x sourceratio for Schauinsland of 5 [ppbC/ppb]. Comparable[VOC]/NO_x ratios are observed in automobile exhaust gasesunder low speed conditions, which points to the important role of trafficunder conditions, when freshly polluted air masses from a near-by city areadvected to the site. From an investigation of the photochemical age of theadvected air masses it becomes clear that there must exist biogenic sourcesof light olefins in the vicinity of the observatory during the vegetationperiod. For propene and the butenes we are able to estimate a lower limit oftheir contributions in terms of reactivity to the total reactivity( [HC](i) k_OH(i),i=C₂-C₅) of the measured hydrocarbons. Forlowest pollution levels in summer (acetylene <300 ppt, about 40%of the summer values) this source is found to be responsible for15–20% of the total C₂–C₅reactivity observed at Schauinsland. On the average, this source accountsfor 5–10% of the total C₂–C₅reactivity.     

EPR and SQUID magnetometry study of Cu2FeSnS4 (stannite) and Cu2ZnSnS4 (kesterite)

An EPR and SQUID magnetometry study of Cu₂FeSnS₄ (stannite) and Cu₂ZnSnS₄ (kesterite) has been performed in order to gain a deeper insight into the crystal chemistry of these minerals, in which the mixed character of bonds lends uncertainty to the determination of the metal valence states. EPR investigations were performed down to almost liquid nitrogen temperature on both natural and synthetic samples of stannite and kesterite. The interpretation of their parameters (g- and T-tensors) was refined by computer simulation. The main feature of all the spectra is the unstructured signal centered at about 0.310 T due to the presence of Cu(II). The absence of structure in the signal is due to spin-spin exchange interaction between Cu(II) and Fe(II), pointing to a diluted distribution of Cu(II). The temperature dependence of the Cu(II) signal can be related to a topological variation of the first-neighbors coordination. The SQUID measurements, while allowing a more precise interpretation of the EPR data, led to a full characterization of magnetic behavior of stannite and kesterite down to liquid helium temperature, evidencing antiferromagnetic interactions between the Fe(II) ions in all samples but in synthetic kesterite. From the EPR and SQUID experimental data no evidence was provided for the existence of two different structures for stannite and kesterite. Received: 2 August 1999 / Accepted: 7 January 2000     

植被冠层日光诱导叶绿素荧光塔基自动观测方法及系统介绍

植物光合作用所提供的物质和能量是人类赖以生存的关键因素,而日光诱导叶绿素荧光SIF(Sun-Induced chlorophyll Fluorescence)是植物光合作用的副产品,与光合作用关系密切,深入研究SIF将对于更加深入理解光合作用机制有着重要的意义.目前,近地面植被冠层SIF遥感观测发展迅速,但不同SIF观...