In situ and laboratory investigations of fluid flow through an argillaceous formation at different scales of space and time, Tournemire tunnel, southern France

In the context of a research and development program on waste disposal, an experimental site (Tournemire tunnel, Aveyron, France) was selected by the French Institute for Nuclear Protection and Safety (IPSN) in order to undertake studies on potential fluid flow at different scales of space and time within a 250-m-thick argillaceous formation. The argillite has a low natural water content (~3–5%) and very low radii access porosity. Diffusion (tritiated water) coefficients (1×10^–12 to 2×10^–11 m²/s) and hydraulic conductivities derived from different types of laboratory tests (10^–14 to 10^–13 m/s) are characteristics of a very low-permeable rock. In situ hydraulic tests (including long-term hydraulic-head measurements) were used to obtain values for hydraulic head and hydraulic conductivity at a scale of 1–10 m (10^–13 to 10^–11 m/s). Despite uncertainties on these data (due to a scale factor, presence of fissures, and possible artefacts due to hydro-chemo-mechanical coupling), it is expected that fluid flow is essentially governed by diffusion processes. Identification of possible natural flows at larger scales of time and space was investigated using natural isotopic tracers from interstitial fluids. Modelling, based on the deuterium profile along the clay formation and assuming pure diffusion processes, provides estimations of possible flow times. However, lack of knowledge concerning the past geological evolution of the site and the possible role of a fracture network do not permit reduction of uncertainties on these estimations at this stage. Electronic Publication     

Fourier transform measurement of NO2 absorption cross-section in the visible range at room temperature

New laboratory measurements of NO₂ absorption cross-section were performed using a Fourier transform spectrometer at 2 and 16 cm^-1 (0.03 and 0.26 nm at 400 nm) in the visible range (380–830 nm) and at room temperature. The use of a Fourier transform spectrometer leads to a very accurate wavenumber scale (0.005 cm^-1, 8×10^-5 nm at 400 nm). The uncertainty on the new measurements is better than 4%. Absolute and differential cross-sections are compared with published data, giving an agreement ranging from 2 to 5% for the absolute values. The discrepancies in the differential cross-sections can however reach 18%. The influence of the cross-sections on the ground-based measurement of the stratospheric NO₂ total amount is also investigated.     

Measurement of PAN in the Polluted Boundary Layer and Free Troposphere Using a Luminol-NO2 Detector Combined with a Thermal Converter

Peroxyacetyl nitrate (PAN,CH³C(O)O₂NO₂) has been measured inthe polluted boundary layer and free troposphere by thermal conversion tonitrogen dioxide (NO₂) followed by detection of thedecomposition product with a Scintrex LMA-3 NO₂-luminolinstrument. Following laboratory tests of the efficiency of PAN conversionand investigations of possible interferences, the technique was evaluated atthe West Beckham TOR (Tropospheric Ozone Research) Station near the northNorfolk coast in Eastern England between September 1989 and August 1990. PANmeasured by the new technique was reasonably well correlated with PANrecorded using electron capture gas chromatography (EC/GC). PAN was alsowell correlated with ozone (O³) in the summer months. Springand autumn episodes of simultaneously high concentrations of PAN andO³ were examined in conjunction with air parcelback-trajectories and synoptic- and local-scale meteorology in a study ofthe sources of photooxidants on the east coast of England. Spring-timemeasurements of PAN made in the free troposphere in a light aircraft ataltitudes up to 3.1 km showed the presence of 0.54 and 0.26 ppbv PAN inpolar maritime and mid-latitude oceanic air masses, respectively. Thetechnique is particularly suited to airborne applications because potentialinterferences are minimised and the frequency of measurements is higher thangenerally achieved with EC/GC methods.     

Katabatic wind profiles over the Greenland ice sheet: observation and modelling

Profiles of wind and temperature have been observedabove the Greenland ice sheet, 90 km from its westernmargin, in July 1991. The terrain slopes downward tothe west. Measurements were performed with instrumentson a 30 m mast, combined with a Doppler SODAR and aRASS. Whereas the surface is usually at the meltingpoint, the temperatures in the free atmosphere areabove freezing. The depth of the boundary layer, in whichthe wind turns to the free atmosphere direction, is notmuch more than 100 m. The surface wind is always aboutfrom the southeast (hence with a downslope component),whereas winds from the southwest (with an upslopecomponent) often occur at the 100 m level.Mixing length profiles for momentum were estimatedby comparison of calculated and observed windprofiles. A good accordance between calculated andobserved wind speed was obtained. The neutralmixing length had a maximum of only a few metres, whichwas approached already at low height. The limiting valueis proportional to the 0.7-th power of the Froudenumber times a length scale obtained from thetemperature profile.     

Coordinated Simultaneous Freja Satellite and Niemegk Observatory ULF Measurements

The standard FFT analysis was applied to thirteen pulsation events selected from the March–April 1993 simultaneous measurements in space (Freja satellite) and on the ground (Niemegk Observatory). The spectral processing of the six-minute sections of record in two coordinate components perpendicular to the magnetic field lines had two principal subjects in view: a) Frequency-amplitude satellite-ground relations. The average values of smoothed spectral amplitude transmission coefficients in the total Pc4-3 and, separately, in Pc4 and Pc3 bands were 0.60, 0.48 and 0.70, respectively. The maximum values were observed within the Pc3 band, near f 30 mHz. b) Estimation of frequency bands of field line resonances (FLRs) recorded on Freja. Freja's motion in a broad latitude range (±5° around Niemegk) during the measurements enabled two frequency bands of FLRs with a width of 10's of mHz to be identified on Freja. The weighted frequencies of the FLRs bands on Freja were f _wA 36 mHz and f _wB 18 mHz with fine structure separations of about 5 mHz and 4 mHz, respectively. The second band with f _wB 18 mHz was mostly not observed at Niemegk, and this could be the consequence of the satellite moving partly through regions of L greater than that of Niemegk.     

Near bottom variations of turbidity in the St Lawrence estuary

Observations of the turbidity and velocity fields in the near-bottom waters of the St Lawrence estuary were obtained with a package which includes a self-recording attenuance meter and a currentmeter. The latter also measures salinity and temperature. Time series varying in length between 26 h and 26 days, and with repetition rates between one and 15 min are discussed for 3 typical open-channel and nearshore stations. A high-frequency sampling mode provides a means to observe the passage of a frontal disturbance over the bottom during the semi-diurnal cycle. With lower frequency records having lengths of one week to one month, contributions to the turbidity fluctuations due to the spring-neap oscillations, seasonal changes in run-off, and the sudden rise in solid discharge of local tributaries following storms, can be resolved. From turbidity polar diagrams, local onshore sources of particulate suspended matter can be identified. Among other advantages, it is possible from such records to time precisely the occurrence of turbidity peaks in relation to the ebb and flow velocities, to assess the importance of resuspension, and to specify exactly the time rate of change of the turbidity. On the whole, self-recording equipments provide a wealth of information unavailable from more traditional hydrocast sampling techniques.     

Seasonal and daily variation of mercury evasion at coastal and off shore sites from the Mediterranean Sea

Dissolved gaseous mercury (DGM) was measured continuously using two newly developed techniques and a manual technique. The continuous techniques were based on the equilibrium between the aqueous and gaseous phase (DGM = Hg_extr / H', Hg_extr is the measured mercury concentration in the gas phase, H' is the Henry's Law coefficient at the desired temperature). In order to calculate the annual mercury evasion from the Mediterranean Sea, diurnal and seasonal measurements of DGM, total gaseous mercury in air (TGM), water temperature and wind speed were performed. During August 2003, March–April 2004 and October–November 2004 measurements of these parameters were conducted on board the RV Urania. The continuous measurements of DGM showed a diurnal variation in concentration, at both coastal and off shore sites, with higher concentrations during daytime than nighttime. The concentration difference could be as large as 130 fM between day and night. The degree of saturation was calculated directly from the measurements, S = Hg_extr / TGM and was found to vary between the different seasons. The highest average degree of saturation (850%) and the largest variation in saturation (600–1150%) was observed during the summer. The spring showed the lowest variation (260–360%) and the lowest average degree of saturation (320%). The autumn also showed a large variation in saturation (500–1070%) but a lower average (740%) compared to the summer cruise. This might be explained by the temperature difference between the different seasons, since that parameter varied the most. The flux from the sea surface was calculated using the gas exchange model developed by Nightingale et al. [Nightingale, P.D., Malin, G., Law, C.S., Watson, A.J., Liss, P.S., Liddicoat, M.I., Boutin, J., Upstill-Goddard, R. C., 2000. In situ evaluation of air–sea gas exchange parameterization using novel conservative and volatile tracers. Global Biogeochemical Cycles, 14(1):373–387]. The evasion varied between the different seasons with the highest evasion during the autumn, 24.6 pmol m^− 2 h^− 1. The summer value was estimated to 22.3 pmol m^− 2 h^− 1 and the spring to 7.6 pmol m^− 2 h^− 1. Using this data the yearly evasion from the Mediterranean Sea surface was estimated to 77 tons.     

Source rock characteristics and biostratigraphy of the Lower Silurian (Telychian) organic-rich shales at Akyaka, central Taurus region, Turkey

The Akyaka section in the central Taurus region in the southern part of Turkey includes the organic matter and graptolite-rich black shales which were deposited under dysoxic to anoxic marine conditions in the Early Silurian. A biostratigraphical analysis, based on graptolite assemblages, indicates that the sediments studied may well be referable to the querichi Biozone and early Telychian, Llandovery. A total of 15 samples have been subjected to Leco and Rock-Eval pyrolysis and graptolite reflectance measurements for determination of their source rock characteristics and thermal maturity. The total organic carbon content of the graptolite-bearing shales varies from 1.75 to 3.52 wt% with an average value of 2.86 wt%. The present Rock-Eval pyrolytic yields and calculated values of hydrogen and oxygen indexes imply that the recent organic matter type is inert kerogen. The measured maximum graptolite reflectance (G_Rmax %) values are between 5.04% and 6.75% corresponding to thermally over maturity. This high maturity suggests a deep burial of the Lower Silurian sediments resulting from overburden rocks of Upper Paleozoic to Mesozoic Upper Cretaceous and Middle-Upper Eocene thrusts occurred in the region.     

Modeling of tropical cyclone winds and waves for emergency management

This paper compares three commonly used parametric models of tropical cyclone winds and evaluates their application in the wave model WAM. The parametric models provide surface wind fields based on best tracks of tropical cyclones and WAM simulates wave growth based on the wind energy input. The model package is applied to hindcast the wind and wave conditions of Hurricane Iniki, which directly hit the Hawaiian Island of Kauai in 1992. The parametric wind fields are evaluated against buoy and aircraft measurements made during the storm. A sensitivity analysis determines the spatial and spectral resolution needed to model the wave field of Hurricane Iniki. Comparisons of the modeled waves with buoy measurements indicate good agreement within the core of the storm and demonstrate the capability of the model package as a forecasting tool for emergency management.