Measurement of PAN in the Polluted Boundary Layer and Free Troposphere Using a Luminol-NO2 Detector Combined with a Thermal Converter

Peroxyacetyl nitrate (PAN,CH³C(O)O₂NO₂) has been measured inthe polluted boundary layer and free troposphere by thermal conversion tonitrogen dioxide (NO₂) followed by detection of thedecomposition product with a Scintrex LMA-3 NO₂-luminolinstrument. Following laboratory tests of the efficiency of PAN conversionand investigations of possible interferences, the technique was evaluated atthe West Beckham TOR (Tropospheric Ozone Research) Station near the northNorfolk coast in Eastern England between September 1989 and August 1990. PANmeasured by the new technique was reasonably well correlated with PANrecorded using electron capture gas chromatography (EC/GC). PAN was alsowell correlated with ozone (O³) in the summer months. Springand autumn episodes of simultaneously high concentrations of PAN andO³ were examined in conjunction with air parcelback-trajectories and synoptic- and local-scale meteorology in a study ofthe sources of photooxidants on the east coast of England. Spring-timemeasurements of PAN made in the free troposphere in a light aircraft ataltitudes up to 3.1 km showed the presence of 0.54 and 0.26 ppbv PAN inpolar maritime and mid-latitude oceanic air masses, respectively. Thetechnique is particularly suited to airborne applications because potentialinterferences are minimised and the frequency of measurements is higher thangenerally achieved with EC/GC methods.     

Katabatic wind profiles over the Greenland ice sheet: observation and modelling

Profiles of wind and temperature have been observedabove the Greenland ice sheet, 90 km from its westernmargin, in July 1991. The terrain slopes downward tothe west. Measurements were performed with instrumentson a 30 m mast, combined with a Doppler SODAR and aRASS. Whereas the surface is usually at the meltingpoint, the temperatures in the free atmosphere areabove freezing. The depth of the boundary layer, in whichthe wind turns to the free atmosphere direction, is notmuch more than 100 m. The surface wind is always aboutfrom the southeast (hence with a downslope component),whereas winds from the southwest (with an upslopecomponent) often occur at the 100 m level.Mixing length profiles for momentum were estimatedby comparison of calculated and observed windprofiles. A good accordance between calculated andobserved wind speed was obtained. The neutralmixing length had a maximum of only a few metres, whichwas approached already at low height. The limiting valueis proportional to the 0.7-th power of the Froudenumber times a length scale obtained from thetemperature profile.     

Currents in the Luzon Strait during the spring of 2002: observation and computation by modified inverse model

On the basis of the current measurements at 200,500 and 800 m from moored current meters with the time series data from March 17 to April 15 at the mooring station (20°49′57″N, 120°48′ 12″E) and the hydrographic data obtained in the Luzon Strait during the spring of 2002 cruise, the circulation in the investigated     

长江口北支进入南支净盐通量的观测与计

根据 2 0 0 1年 4月 1 0— 1 3日长江口大潮期 5个潮周期 3条测量船的同步连续观测资料 ,计算了长江口北支进入南支的净盐通量为 5 4 5× 1 0 6 t,这一结果为预测长江口南支及青草沙水源地的咸潮入侵强度和开发利用长江口淡水资源提供了重要数据。     

Source rock characteristics and biostratigraphy of the Lower Silurian (Telychian) organic-rich shales at Akyaka, central Taurus region, Turkey

The Akyaka section in the central Taurus region in the southern part of Turkey includes the organic matter and graptolite-rich black shales which were deposited under dysoxic to anoxic marine conditions in the Early Silurian. A biostratigraphical analysis, based on graptolite assemblages, indicates that the sediments studied may well be referable to the querichi Biozone and early Telychian, Llandovery. A total of 15 samples have been subjected to Leco and Rock-Eval pyrolysis and graptolite reflectance measurements for determination of their source rock characteristics and thermal maturity. The total organic carbon content of the graptolite-bearing shales varies from 1.75 to 3.52 wt% with an average value of 2.86 wt%. The present Rock-Eval pyrolytic yields and calculated values of hydrogen and oxygen indexes imply that the recent organic matter type is inert kerogen. The measured maximum graptolite reflectance (G_Rmax %) values are between 5.04% and 6.75% corresponding to thermally over maturity. This high maturity suggests a deep burial of the Lower Silurian sediments resulting from overburden rocks of Upper Paleozoic to Mesozoic Upper Cretaceous and Middle-Upper Eocene thrusts occurred in the region.     

Modeling of tropical cyclone winds and waves for emergency management

This paper compares three commonly used parametric models of tropical cyclone winds and evaluates their application in the wave model WAM. The parametric models provide surface wind fields based on best tracks of tropical cyclones and WAM simulates wave growth based on the wind energy input. The model package is applied to hindcast the wind and wave conditions of Hurricane Iniki, which directly hit the Hawaiian Island of Kauai in 1992. The parametric wind fields are evaluated against buoy and aircraft measurements made during the storm. A sensitivity analysis determines the spatial and spectral resolution needed to model the wave field of Hurricane Iniki. Comparisons of the modeled waves with buoy measurements indicate good agreement within the core of the storm and demonstrate the capability of the model package as a forecasting tool for emergency management.     

Temperature of an active lava channel from spectral measurements,Kilauea Volcano,Hawaii

A narrow band spectroradiometer was used to determine the characteristic temperatures of a very active channeled lava flow for the phase 50 eruption of Pu'u 'O'o on the East Rift Zone of Kilauea Volcano, Hawaii. During the twilight of 19 February 1992, 14 spectra of this activity were acquired over a 51 minute interval [18.29 to 19.20 Hawaiian Standard Time (HST)], from which the thermal distribution of energy of two 18 m² areas, one near the center and one near the margin of the flow, may be investigated. A twocomponent thermal mixing model applied to the data taken of the center of the channel gave, in the most powerful instance (1.8x10⁵ W/m²), a crust temperature of 940° C, a hot component temperature of 1120°C and a hot radiating area of 60% of the total area. A simultaneous spectrum acquired near the channeled flow margin yielded a crust temperature of 586° C and a hot area of only 1.2% of the total area radiating at 1130° C. Average radiant flux densities recorded for the center of the lava channel (1.3x10⁵ W/m² average) are much greater than previous measurements of lava lakes (4.9x10³ W/m²) or recently emplaced lava flows (maximum of 7.2x10⁴ W/m²). The energetic nature of this eruption is shown by satellite measurements made at 02.33 HST on 22 February 1992 by the Advanced Very High Resolution Radiometer in Band 2 (0.72–1.10 m). These show the utility of using existing satellites with moderate resolution (1 km x 1 km pixels) and high temporal coverage (eight overpasses each day for Hawaii) as potential thermal alarms for rapidly assessing the hazard potential of large volcanic eruptions.     

Coordinated Simultaneous Freja Satellite and Niemegk Observatory ULF Measurements

The standard FFT analysis was applied to thirteen pulsation events selected from the March–April 1993 simultaneous measurements in space (Freja satellite) and on the ground (Niemegk Observatory). The spectral processing of the six-minute sections of record in two coordinate components perpendicular to the magnetic field lines had two principal subjects in view: a) Frequency-amplitude satellite-ground relations. The average values of smoothed spectral amplitude transmission coefficients in the total Pc4-3 and, separately, in Pc4 and Pc3 bands were 0.60, 0.48 and 0.70, respectively. The maximum values were observed within the Pc3 band, near f 30 mHz. b) Estimation of frequency bands of field line resonances (FLRs) recorded on Freja. Freja's motion in a broad latitude range (±5° around Niemegk) during the measurements enabled two frequency bands of FLRs with a width of 10's of mHz to be identified on Freja. The weighted frequencies of the FLRs bands on Freja were f _wA 36 mHz and f _wB 18 mHz with fine structure separations of about 5 mHz and 4 mHz, respectively. The second band with f _wB 18 mHz was mostly not observed at Niemegk, and this could be the consequence of the satellite moving partly through regions of L greater than that of Niemegk.     

精密三角高程代替一等水准测量的研究

通过对三角高程测量的原理、误差来源及精度分析，指出了用三角高程测量代替一等水准的关键问题，第一次提出了在特定条件下用三角高程测量代替一等水准是完全可行的，并在生产实践中得到了验证。