Geochemical constraints on the origin of the late Jurassic proto-Caribbean oceanic crust in Hispaniola

The nature of the oceanic crust produced through rifting and oceanic spreading between North and South America during the Late Jurassic is a key element for the Caribbean plate tectonic model reconstruction. Located in the Cordillera Central of Hispaniola, the Loma La Monja volcano-plutonic assemblage (LMA) is composed of gabbros, dolerites, basalts, and oceanic sediments, as well as metamorphic equivalents, which represent a dismembered fragment of this proto-Caribbean oceanic crust. Petrologic and geochemical data show that the LMA have a relatively broad diversity in composition, which represent the crystallization products of a typical low-pressure tholeiitic fractionation of mid-ocean ridge basalts (MORB)-type parental magmas, ranging from N- to E-MORB. Three geochemical groups have been distinguished in the volcanic sequence: LREE-flat to slightly LREE-enriched basalts of groups II and III occur interlayered in the lower stratigraphic levels; and LREE-depleted basalts of group I in the upper levels. Mantle melt modeling suggests that group III magmas are consistent by mixing within a mantle melt column of low-degree (<1%) melts of a deep garnet lherzolite source and high-degree (>15%) melts of a shallow spinel source, and groups II and I magmas are explained with moderate to high (14–18%) and very high (>20%) fractional melting degrees of a shallower spinel mantle source, respectively. Thus, upward in the volcanic sequence of the LMA, the magmas represent progressively more extensive melting of shallower sources, in a plume-influenced spreading ridge of the proto-Caribbean oceanic crust. Nb/Y versus Zr/Y systematics combined with recent plate tectonic model reconstructions reveal that Caribbean Colombian oceanic plateau fragments in Hispaniola formed through melting of heterogeneous mantle source regions related with distinct plumes during at least from Aptian–Albian (>96 Ma) to Late Campanian.     

Plume and bloom: effect of the Mississippi River diversion on the water quality of Lake Pontchartrain

The opening of the Bonnet Carré spillway to prevent flood threat to New Orleans in April 2008 created a sediment plume in the Lake Pontchartrain. The nutrient rich plume triggered a massive algal bloom in the lake. In this article, we have quantified the spatio-temporal distribution of the plume (suspended solids) and the bloom (chlorophyll-a (chl-a)) in the lake using remotely-sensed data. We processed the Moderate-resolution Imaging Spectroradiometer satellite data for mapping the total suspended solids (TSS) and chl-a concentrations. An existing algorithm was used for estimating TSS whereas a novel slope model was developed to predict the per-pixel chl-a concentration. Both algorithms were successful in capturing the spatio-temporal trend of TSS and chl-a concentrations, respectively. Algal growth was found to be inversely related to TSS concentrations and a time lag of ～45 days existed between the spillway opening and the appearance of the first algal bloom at an observation location.     

一个理想河口中拦门沙的存在对河口羽流扩展的影响

河口羽流是河口冲淡水在陆架中扩展的主要形式, 其扩展受到诸多动力与地形因素的影响, 口门拦门沙就是其中之一。以一个理想化的河口为例, 采用区域海洋模型(regional ocean modelling system, ROMS), 研究口门拦门沙对河口羽流扩展的影响, 具体包括拦门沙对羽流的出流状态、扩展范围以及远场区沿岸流淡水输运的影响。研究结果表明, 拦门沙增加了口门处的水体分层, 减小了羽流出流速度, 增大了羽流凸出体的半径, 减小了远场区沿岸流宽度, 并进而减少了沿岸流中的淡水输送。本项研究对地形因素对河口羽流的扩展研究以及陆源物质的向海输运等均具有重要意义。     

Petrogenesis of the Piqiang mafic-ultramafic layered intrusion and associated Fe-Ti-V oxide deposit in Tarim Large Igneous Province,NW China

ABSTRACT

The Piqiang intrusion is one of the two important ma?c-ultrama?c layered intrusions that host giant Fe-Ti-V oxide deposits in the Permian Tarim Large Igneous Province, NW China. The intrusion mainly consists of gabbro, anorthosite and minor plagioclase-bearing clinopyroxenite in the marginal zone. Disseminated to massive Fe-Ti oxide ores occur as layers and lenses within the gabbro. SHRIMP zircon U-Pb results from both a gabbro from the Piqiang intrusion and a granite from the surrounding granitic dyke yield ages of ~270 Ma. Geochemically, the Piqiang silicate rocks are enriched in light rare earth elements (LREE) and large ion lithophile elements (LILE), moderately depleted in high ?eld strength elements (HFSE), and have a limited range of Sr-Nd-Hf isotopic compositions. The similar mineralogy, mineral compositions, and trace element characteristics of the layered units suggest that all the rocks are co-magmatic. The parental magma is Fe-Ti-rich and is akin to the most primitive diabasic dyke which is associated with the Piqiang intrusion. Partial melting of the Tarim mantle plume with involvement of a subduction-metasomatized lithospheric mantle source best explains the geochemistry and petrogenesis of the parental magmas of the Piqiang intrusion. We propose that the lithospheric mantle source may have been metasomatized by subduction-related materials and the metasomatic enrichment of this source region which may be correlated with oceanic sediment recycling during southward subduction of the South Tianshan oceanic slab during the Early-Middle Paleozoic. Crystal settling and mechanical sorting is the predominant process responsible for the formation of the massive Fe-Ti oxide ores in the Piqiang intrusion. Central to ore formation is a combination of the protracted differentiation history of a Fe-Ti-enriched parental magma and the later addition of external H₂O from the country rocks to the slowly cooling magma chamber.     

Complex geometry of the Cenozoic magma plumbing system in the central Sahara,NW Africa

Topographic uplifts in the central Sahara occur in the Hoggar-Aïr and Tibesti-Gharyan swells that consist of Precambrian rocks overlain by Cenozoic volcanic rocks. The swells and associated Cenozoic volcanism have been related either to mantle plumes or to asthenospheric upwelling and to partial melting due to rift-related delamination along pre-existing Pan-African mega-shears during the collision between Africa and Europe. The Cenozoic volcanic rocks in the Hoggar generally range from Oligocene tholeiitic/transitional plateau basalts, which occur in the centre of the dome, to Neogene alkali basalts characterized by a decrease in their degree of silica undersaturation and an increase in their La/Yb ratios. The alkali basaltic rocks occur mainly along the margins of the dome and typically have less radiogenic Nd and Sr isotopic ratios than the tholeiitic/transitional basalts. The geochemistry of the most primitive basaltic rocks resembles oceanic island basalt (OIB) tholeiitic – in particular high-U/Pb mantle (HIMU)-type – and is also similar to those of the Circum-Mediterranean Anorogenic Cenozoic Igneous (CiMACI) province. These characteristics are consistent with, but do not require, a mantle plume origin. Geophysical data suggest a combination of the two mechanisms resulting in a complex plumbing system consisting of (a) at depths of 250–200 km, an upper mantle plume (presently under the Aïr massif); (b) between 200 and 150 km, approximately 700 km northeastward deflection of plume-derived magma by drag at the base of the African Plate and by mantle convection; (c) at approximately 150 km, the magma continues upwards to the surface in the Tibesti swell; (d) at approximately 100 km depth, part of the magma is diverted into a low S-wave velocity corridor under the Sahara Basin; and (e) at approximately 80 km depth, the corridor is tapped by Cenozoic volcanism in the Hoggar and Aïr massifs that flowed southwards along reactivated Precambrian faults.     

Geochronologic-petrochemical studies of the Hongshishan mafic–ultramafic intrusion,Beishan area,Xinjiang (NW China): petrogenesis and tectonic implications

The Hongshishan mafic–ultramafic intrusion (SIMS zircon U–Pb age 286.4 ± 2.8 Ma) consists of dunite, clinopyroxene peridotite, troctolite, and gabbro. Major elements display systematic correlations. Trace elements have identical distribution patterns, including flat rare-earth element (REE) patterns with positive Eu anomalies and enrichments in large ion lithophile elements (LILE) but depletions in Nb and Ta, indicating fractional crystallization as a key factor in magmatic evolution. Petrologic and geochemical variations in drill core samples demonstrate that minor assimilation and progressive magma injections were closely associated with Ni–Cu mineralization. Mass balance estimates and Sr–Nd isotopes reveal that the Hongshishan parental magmas were high-Mg and low-Ti tholeiitic basalts and were derived from a lithospheric mantle source that had been modified by subducted slab metasomatism before partial melting.

Southward subduction of the Palaeo-Tianshan–Junggar Ocean is further constrained by a compilation of inferred, subduction-induced modifications of mantle sources in mafic–ultramafic intrusions distributed in the eastern Tianshan–Beishan area. Integrating the regional positive ?_Nd(t) granites, high-Mg and low-Ti basaltic magmas (mafic–ultramafic intrusions), and slightly later high-Ti basalts in NW China suggests that their petrogenesis could be attributed to Permian mantle plume activities.     

Geochronology,geochemistry, Hf isotopic compositions and formation mechanism of radial mafic dikes in northern Tibet

A large mafic dike swarm is radially distributed in southern Qiangtang. Three typical samples were selected for geochronology, geochemistry, and Hf isotopic analysis. Zircon U–Pb dating indicates that the three dikes formed at 291 ± 2, 292 ± 3, and 300 ± 2 Ma. Whole-rock compositions show that the southern Qiangtang mafic dikes are alkaline, Fe + Ti rich, and exhibit relative enrichment in light rare-earth elements. The ratios of incompatible elements are similar to those of oceanic island and Emeishan basalts. Geochemical diagrams show that the dikes erupted in an intraplate environment. Zircon Hf isotopic data suggest that magma that produced the mafic dikes was derived from a depleted mantle source. The geochemical characteristics of the dikes approximate that of eruption products of a brief period of mantle plume activity (300–280 Ma). According to eight geologic maps of Qiangtang, the mafic dikes crop out over an area of 150 km from north to south and 500 km from east to west, radiating outward from Mayigangri. We conclude that the mafic dikes in southern Qiangtang are related to the combined effect of Permian plate motions and mantle plume activity, and the Mayigangri area overlies the hot spot. Furthermore, the mantle plume in southern Qiangtang may have propelled the closing of the Palaeo-Tethys Ocean.     

深部咸含水层CO2注入下压力抬升与流体迁移的大尺度模拟研究:以松辽盆地为例

地下深部封存CO2已经被公认是人类削减温室气体排放的一条有效而又科学的途径。深部咸含水层CO2地质封存因封存潜力巨大,技术可行,且已有实际的工程运行,因而备受关注。松辽盆地是中国潜在的CO2储存场地之一,选择松辽盆地为大尺度模拟研究对象,选取姚家组砂岩层为储层,选取嫩江组泥岩为盖层,运用TOUGH-MP并行计算代码建立了覆盖整个松辽盆地的三维地质模型,在中央凹陷区开展大尺度CO2注入模拟研究,包括CO2运移、储存、地层压力提升以及储存安全性等问题。模拟结果表明:持续注入100a后形成的CO2羽远小于产生的压力积聚区影响范围。注入产生的压力抬升将在注入停止后迅速消散,不会对区域地层压力和浅层地下水系统产生显著影响。在千年之内注入的CO2将随着时间持续,逐渐溶解于水中,而不会因盖层微弱的渗透性而逃逸。     

中条裂谷的幔柱构造与成矿

中条山地区的地球物理场具有“三低一高”(低波速、低密度、低黏度及高地热异常)特点,变质核杂岩中赋存有科马堤岩并具“双层”结构,火成岩呈“双峰”状态,变质期的古地温为522～608℃,压力0.3～0.73GPa,地热梯度23℃/km,表明中条山地区为新太古代-元古宙的大陆裂谷—地幔热柱构造.其成矿作用存在着“四代同堂”的成矿模式,成矿期与岩浆侵入期的时差甚小;成矿空间上,大多数矿床沿着裂谷内两组断裂呈X型“对称式”展布,有益元素矿物组合及成矿温度自中心向周围呈有规律降低趋势.由于在新太古代以前,富铜的扬子板块俯冲至华北板块之下,促使中条裂谷的地壳加厚,形成丰富的成矿物质场,因为地幔热柱脉动式隆升,热液在运移过程中不断萃取地壳的铜质,故成为区域内独特的铜矿集中区.     

A buoyant plume adjacent to a headland—Observations of the Elwha River plume

Small rivers commonly discharge into coastal settings with topographic complexities - such as headlands and islands - but these settings are underrepresented in river plume studies compared to more simplified, straight coasts. The Elwha River provides a unique opportunity to study the effects of coastal topography on a buoyant plume, because it discharges into the Strait of Juan de Fuca on the western side of its deltaic headland. Here we show that this headland induces flow separation and transient eddies in the tidally dominated currents (O(100 cm/s)), consistent with other headlands in oscillatory flow. These flow conditions are observed to strongly influence the buoyant river plume, as predicted by the “small-scale” or “narrow” dynamical classification using Garvine's (1995) system. Because of the transient eddies and the location of the river mouth on the headland, flow immediately offshore of the river mouth is directed eastward twice as frequently as it is westward. This results in a buoyant plume that is much more frequently “bent over” toward the east than the west. During bent over plume conditions, the plume was attached to the eastern shoreline while having a distinct, cuspate front along its westernmost boundary. The location of the front was found to be related to the magnitude and direction of local flow during the preceding O(1 h), and increases in alongshore flow resulted in deeper freshwater mixing, stronger baroclinic anomalies, and stronger hugging of the coast. During bent over plume conditions, we observed significant convergence of river plume water toward the frontal boundary within 1 km of the river mouth. These results show how coastal topography can strongly influence buoyant plume behavior, and they should assist with understanding of initial coastal sediment dispersal pathways from the Elwha River during a pending dam removal project.