矿渣磷酸镁水泥的力学性能和水化机理

以高炉矿渣作为磷酸镁水泥(MPC)的活性混合材料,研究了MPC的凝固时间、力学性能、物相组成和显微结构,并探讨了矿渣MPC的作用机理。实验固定磷镁比为25%,硼镁比为7.5%,矿渣掺量分别为磷镁总质量的0%、10%、20%、30%和40%。结果表明,矿渣参与了水化反应并提高了MPC的胶凝性能,随着矿渣掺量增大,矿渣MPC的抗压强度提高,但矿渣水化产生的膨胀应力会破坏MPC的内部结构,因此其抗折强度随矿渣掺量增大而降低。矿渣MPC的主要水化产物为六水合磷酸镁铵(MgNH4PO4.6H2O),矿渣的掺入使凝胶相增加,并有部分Ca2+进入MgNH4PO4.6H2O晶格,使水化产物的形貌、大小发生变化。样品中剩余较多死烧镁和矿渣颗粒,可起骨料作用。     

从废水中萃取回收铟的工艺研究

采用还原净化,磷酸三丁酯(TBP)共同萃取,稀HCl选择性反萃取分离,二(2-乙基己基)磷酸酯(P204)萃取纯化,HCl反萃取,反萃铟液除杂质,置换和熔炼的湿法冶金新工艺,从废水中回收稀散元素In,可获得合格的粗铟产品,In的质量分数w98.5%,总回收率大于90%。     

The mined-out phosphate lands of Nauru,equatorial western Pacific

Nauru once possessed the world's purest deposits of rock phosphate, the precursor of the agricultural fertiliser, superphosphate. This resource was almost entirely depleted during the 20th century, mainly destined for Australia and New Zealand, where it played a critical role in the economic, social and demographic development of these nations and their biological transformation to outposts of temperate Northern Hemisphere flora.

By the early 1990s, the primary phosphate that had once blanketed the island had been almost completely removed, exposing a dramatic buried landscape of karst pinnacles and transforming Nauru into the world's most environmentally altered nation. Investigations into the rehabilitation of the mined-out area began in 1953, but all rejected the idea of restoration on the grounds of expense. In 1993, Nauru won an out-of-court settlement of A$135 million from Australia for restitution of the phosphate lands. No rehabilitation has yet taken place, however, and the project is unlikely to succeed. The soil stockpiled for the project is inadequate in quantity, in fertility, in elemental composition, in water retention capacity, and contains toxic levels of cadmium. Rainfall is too unreliable to support regular cultivation and the Nauruans possess no tradition of agriculture.

One alternative to rehabilitation is to exploit the terrain that has been exhumed from beneath the phosphate overburden. This closely resembles the Nauruan landscape of a quarter of a million years ago, before humans arrived and before phosphate buried the land. Such spitzkarren landscapes elsewhere in the tropics are venerated as landscape wonders and revered as scientific marvels. They are protected by World Heritage status and receive millions of visitors a year. The end of mining in Nauru is meanwhile leading to the re-establishment of an ecologically valuable and visually striking indigenous vegetation. This spectacular new landscape should be preserved, not destroyed, and exploited as a global travel destination.     

Relationship between tissue phosphorus and seawater phosphate in the brown alga Hormosira banksii

We measured tissue phosphorus content of high and low intertidal Hormosira banksii to test the hypothesis that tissue phosphorus content would be greater in individuals from the low intertidal because of greater total uptake associated with longer immersion in seawater. Moreover, we predicted that tissue phosphorus would be greater at sites where the seawater contained higher phosphate concentrations. There was a positive, linear relationship between local seawater phosphate concentrations and tissue phosphorus content of H. banksii from high and low intertidal zones at six different sites in winter. However, there were no comparable relationships in summer, even though the range of seawater phosphate concentration was similar in both seasons. The phosphorus contents of low intertidal H. banksii were significantly greater than high intertidal H. banksii in winter, but not in summer. Reasons for these differences may be related to greater access to seawater phosphate in low intertidal algae (than those in the high intertidal) in winter, followed by greater utilisation of the internal phosphorus between winter and summer, due to faster growth rates in the low intertidal.     

聚合羟基铁铝蒙脱石复合体对磷的吸附行为及其动力学

在一定条件下利用钠基化蒙脱石合成了聚合羟基铝-蒙脱石复合体(HyA1-Mt)、2个不同铁含量的聚合羟基铁-蒙脱石复合体(HyFe-Mt)和3个不同Fe:Al摩尔比的聚合羟基铁铝-蒙脱石复合体(HyFeAl-Mt),研究了酸性和弱酸性条件下(pH=3.0～6.5)以上蒙脱石复合体对磷的吸附行为和动力学特征。结果表明,HyFeAl-Mt对磷的吸附容量大于HyA1-Mt和HyFe-Mt复合体,且随着Fe:Al摩尔比的增大,对磷的吸附容量依次增加。随pH升高,蒙脱石复合体对磷的吸附量容量变小。但随Fe:Al摩尔比增大,HyFeAl-Mt复合体零电荷点(pHZPC)升高,pH对磷的吸附的影响越来越小,HyFe-Mt对磷的吸附几乎不受pH的影响。随Fe:A1摩尔比的增大,HyFeAl-Mt对磷的吸附能力增强,铁含量是磷吸附量的重要控制因素。磷在各蒙脱石复合体上的吸附实验数据可很好地用Langmuir吸附等温方程拟合。磷在各蒙脱石复合体上的吸附动力学过程可分为快速和慢速两个过程,快速过程中的动力学受铁含量影响明显。动力学数据可同时用准二级动力学方程和Elovich方程拟合。     

三峡库区蓄水后夏季长江口及其邻近水域粒级叶绿素a

了解长江口水域富营养化现状对浮游植物的影响及浮游植物对长江口水域富营养化现状的指示作用,根据2004年8月30日~9月4日在长江口水域进行的多学科综合调查结果,报道了调查区叶绿素a的空间分布及其粒级组成特征,并初步研究了其与环境因子的关系。叶绿素a浓度在长江河道内和口门外水域浓度变化范围分别为0.40~2.13mg.m-3,0.48~4.89mg.m-3,平均值分别为1.09mg.m-3,1.70mg.m-3;与三峡库区蓄水前相比叶绿素a浓度偏低,高值区向口门方向西移,其水平分布与浮游植物丰度分布基本一致。垂直方向上叶绿素a浓度峰值出现在20m以上水层,与浮游植物丰度垂向分布有一定的差异。在调查水域<20μm粒径叶绿素a的平均浓度比>20μm粒径叶绿素a要高。统计分析表明磷酸盐与叶绿素a浓度呈显著的正相关,是控制浮游植物生长的重要因子。     

围隔生态系富磷及油污染对叶绿素a变化的影响

根据 1 997年 1 0月和 1 998年 5月 2次围隔生态系实验中获得的叶绿素 a资料 ,分析了在富磷围隔实验中不同粒径叶绿素 a的变化及各自所占的百分比以及油污染对叶绿素 a变化的影响。实验结果表明 :在 P- meso中 ,1 0月份 Chl- a的含量每天以 1 0～ 1 6 μg/L的速度呈指数生长 ,最高达到 74.89μg/L;大于 2 0μm的大型浮游植物是浮游植物总生物量的主要贡献者。5月份 Chl- a含量在加磷后增长的速度每天为 3～ 8μg/L,较 1 0月份慢 ;2～ 2 0 μm和 GF/F～ 2μm的小型和微型浮游植物是浮游植物总生物量的主要贡献者     

非晶态磷酸锡去除高盐介质中Pb（Ⅱ）研究

利用合成的非晶态磷酸锡作为吸附剂, 研究了多种因素（pH、吸附时间、初始浓度、温度、离子强度）对吸附剂吸附水溶液中Pb2＋的影响。结果表明, 非晶态磷酸锡对Pb2＋的吸附量随着pH（3～6）以及吸附时间的增大而增加。用Freundlich、Langmuir 模型对等温吸附数据进行处理, Langmuir 方程拟合效果最...     

Sorption of P by ferric hydroxide film, cover particles of sediments of Lake Baikal

We investigated in more detail the adsorption phenomenon which was described earlier. It was clearly established that the hydroxyl apatite was not participated in P adsorption. This phenomenon takes place because of ferric hydroxide film. Modem sediments from the Southem Basin of Lake Baikal were taken and stirred with Baikal water. Carrier-free [^32p]-orthophosphate was added in this system. Similar experiments were made with carrier-free [^35S]-sulphate. Sulphate stayed in supematant completely. The influence of pH on the system with inorganic phosphate was also studied. In low alkali conditions phosphate migrated in supematant, in low acid, in sediments. Baikal sediment was stripped of iron-hydroxous film by treatment with 1% oxalic acid. Investigation of striped sediment shown that phosphate stays in supematant only. Hence, hydroxyl apatite cannot be the phase of the sediments of Lake Baikal which binds phosphate. This all showed by our group before. Now we have found the limit of phosphate sorption in Lake Baikal sediments and the stehiometry of the sorption. The sorption limit of Lake Baikal sediments was studied. An experiment with inorganic ^31P phosphate was made. 0.025% K2HPO4 solution with adding ^32P radioactive mark into it was prepared. 100 μL of mixture of ^31PO4^3- and ^32PO4^3- seven times were added in a ＂Baikal water-Baikal sediment＂ system and blank （100 ml BW only）. Concentrations of inorganic ^31PO4^3- were very low so the bend dot on the diagram was found and sorption limit of sediment was estimated. Baikal sediment stopped assimilating phosphate in the bend dot. The stehiometry of sorption was estimated by supematant-sediment radioactive ratio, which equals 3, that is, three Fe （Ⅲ） atoms associate one PO4^3- anion. The only Fe （Ⅲ） substance which could associate P is -Fe-O-Fe- polymer film. It also dissolves in acid conditions.