古海洋生产力与氧化还原指标——元素地球化学综述

海洋表层初级生产力大小以及水体氧化还原条件是古海洋和古气候研究的重要内容,而元素地球化学是研究初级生产力以及氧化还原条件最常用的手段。主量元素Fe和Si是限制生物的营养元素,痕量金属元素Cu、Ni和Zn是微营养元素,而营养条件是沉积生产力的限制因素,因此这些元素的含量能反映初级生产力大小。Ba和Mo是随有机质一起沉淀下来的,与水体的有机碳通量有关,也是古生产力大小的指标。对氧化还原敏感的痕量金属元素含量（如Cr、V和U）以及元素比值（如V/（V＋Ni）、V/Cr、Ni/Co、U/Th和V/Sc）常用来重构水体的氧化还原条件。     

西藏冈底斯北缘尼玛地区帮勒村一带寒武纪火山岩LA-ICP-MS锆石U-Pb年龄及其地球化学特征

青藏高原南部中国境内是否存在寒武纪地层一直是地质界关注的焦点。研究表明,冈底斯北缘西藏尼玛县控错南帮勒村一带,原划的前震旦纪念青唐古拉岩群为一套浅变质的拉斑系列双峰式火山岩。通过高精度LA-ICP-MS(激光剥蚀等离子体质谱)锆石微区原位U-Pb同位素测年,获得其中变流纹岩206Pb/238U年龄加权平均值为(536.4±3.6)Ma,确定该套火山岩形成于早寒武世。地球化学分析表明,变玄武岩富集LREE、LILE、部分HFSE,Nb、Ta、Zr、Hf等亏损,Zr/Nb比值(2.53~3.61)低;变流纹岩明显富集LREE、LILE、Th、HFSE,具有Eu负异常和Sr、Nb、Ta、Ti负异常。同时,变玄武岩的εNd(t)为负值(-2.80~-4.56),源区为富集地幔端元EMⅡ,反映其源区为岩石圈和软流圈相互作用的产物,并遭受了地壳物质的混染。综合分析认为该套火山岩形成于陆缘裂谷环境,为冈底斯北缘存在寒武纪裂解作用提供了佐证。     

滇西梁河—潞西地区新生代英安岩的源区及成因——来自地球化学的证据

报道了滇西梁河—潞西地区新生代英安岩的主量、微量、稀土元素和Nd同位素地球化学研究成果。英安岩富集轻稀土元素、大离子亲石元素(Rb、Th、U、K),相对亏损重稀土元素和Nb、Ta、Sr、P、Ti,具有Eu负异常和Pb正异常。火山岩的εNd(0)为-10.3~-8.72,Nd同位素模式年龄(tDM)为1.2~1.4Ga。这些地球化学特征表明,研究区英安岩源于区域基底岩系的部分熔融,并与该地区同期幔源玄武质岩浆发生了不同程度的混合。     

大兴安岭中段莫克河地区新生代火山活动

通过野外地质观测、岩石地球化学分析及高精度加速器质谱(AMS)14 C测年等工作,对大兴安岭中段莫克河地区新生代火山活动进行了详细研究。结果表明:莫克河地区新生代火山活动活跃,覆盖面积超过80km2,喷发方式为斯特朗博利型喷发。火山活动最早始于晚更新世,火山活动经历了4个火山喷发旋回,并在第一、二个火山旋回之间有短暂的间歇。火山岩为以低硅、高镁、高钾、高钛为主要特征的高钾钙碱性橄榄玄武岩。综合周边地区资料,研究区新生代火山岩是在拉张的构造环境下、以复活的深大断裂为通道产生的板内OIB型玄武岩,岩浆在上升过程中没有或很少发生壳源物质混染,也没有发生斜长石结晶分异,但有橄榄石、单斜辉石的分离结晶作用。     

成烃贡献值及其在烃源岩评价中的应用

烃源岩评价是油气勘探的关键工作之一。为了更加合理、直观和有效地评价烃源岩,以辽东湾地区为例,通过对烃源岩常规评价参数的分析,提出了考虑有机质丰度、类型和热演化程度的综合指标——成烃贡献值,并利用该指标对辽东湾地区烃源岩进行了评价。从个体评价和整体评价两方面,与常规评价方法的结论进行对比研究。结果表明,辽东湾地区辽中凹陷沙河街组烃源岩对成烃的贡献比东营组大,中洼烃源岩比北洼好。由此可见,用成烃贡献值评价烃源岩,不仅可以达到常规评价的要求,而且比常规方法更加合理和直观。     

The Stream Sediment Geochemistry of the Walawe Ganga Basin of Sri Lanka - Implications for Gondwana Mineralization

A regional geochemical and mineralogical study aimed at investigating the mineralization in the western-part of the Walawe Ganga (river) Basin in Sri Lanka is represented in this paper. The river basin is the 3^rd largest in the country and has within it a boundary zone between two geologically different crustal blocks, which are marked by granulitic grade rocks and amphibolite grade rocks. Size fractions of stream sediments (< 63 μm; 63–125 μm; 125–177 μm and 177–250 μm) developed on the granulite-grade metamorphic terrain have been analysed at their source for their mineralogical and selected element compositions. Thirty-eight (38) sediment samples and 15 representative probable parent rock samples were chemically analysed giving special emphasis to the High Field Strength trace Elements (HFSE) including the Rare Earth Elements (REE). The granulite grade rocks in the study area is geochemically similar to that of post Archean upper crust. However the stream sediments developed from the high-grade rocks during the intense weathering, are markedly enriched with HFSE and REE. The enrichment of HFSE and LREE is accounted for by the presence of HFSE- and REE- rich accessory mineral phases such as zircon, monazite, apatite, garnet and rutile in the sediments. In some samples, the content of heavy minerals contributes as much as 50 wt. %. These minerals act as a source of elements in the sediments. However, extreme hydraulic sorting of HFSE- and REE-bearing minerals during the sediment deposition cannot be expected within a short distance from near the sources except from a mineralized occurrence. Therefore, the higher enrichment of these elements presumably indicates occurrences of scattered mineral sources such as highly differentiated granites and associated pegmatites within the Walawe Ganga drainage basin. These granitic pegmatites are probably intruded during or soon after the main granulite-facies metamorphic event and similar events are seen in other terrains of East-Gondwana.     

川东北地区三叠系聚盐成钾机制及富集模式

川东北地区三叠系发育巨厚的蒸发岩层,并赋存优质的深层富钾卤水.因构造沉积条件的整体差异,川东北富钾卤水的成因机制与富集规律未有详尽研究.以"气钾兼探"为指导思想,综合利用野外露头?岩心?测井等资料,对川东北地区三叠系蒸发岩分布规律以及岩相古地理演化进行分析,明确了膏盐盆在T1j4?5?T2l1期间规模逐渐缩小、向SW逐...     

皖南天井山金矿床地质-地球化学特征及找矿前景

皖南地区山高林密,地质工作条件差,基础地质工作相对还很薄弱,金矿的找寻工作一直没有取得大的突破.本文选取皖南休宁县天井山金矿为切入点,对该矿床地质、地球化学特征进行了分析,基本理清了本区与金成矿相关的各种因素,对矿床成因进行了剖析,并对其找矿前景作了探讨.系统统计分析区内地层、岩浆岩、矿石的主微量元素、稀土元素特征,讨...     

Geochemical Features of the Hubin Spring Gases from the Northern Caldera Lake of the Tianchi Volcano,Changbai Mountains

This paper deals with geochemical features of gas emitted from the Hubin Springs.The Hubin Springs zone,a strong thermal emission zone,is are locatedd at the north edge of the Tianchi caldera lake.Very young deposits with uncertain eruption date are found on the top area of the Tianwenfeng,which might have been formed in one of the recent eruptions or the Millennium Eruption.It is of significance to study the geochemistry features of the emitting gas from the Hubin Springs to understand the activities of the Tianchi Volcano.This paper systematically sampled and analyzed the gases emitted from the Hubin Springs and discussed their geochemistry features.The results show that there is a high content of deep derived gases,such as CO2,He,CH4 and Ar in Hubin Springs zone.The isotopic ratio of He lies between 4.18 and 5.95 Ra.The averaged mantle derived gas content calculated from the 4He/20Ne ratio and He content reaches 67.1%.All these show that the Hubin Springs are located on a special belt of deep gases released in high intensity and large scale.The spatial distribution of Helium isotope is characterized by concavity,showing that this special area may be related to the volcanic edifice.It is highly possible that the released gases represent the residual gas samples of the latest eruptions from the Tianchi Volcano.However more detailed studies are demanded.     

西昆仑库科西鲁克地区基性岩脉地球化学及构造意义

新疆库科西鲁克地区广泛发育基性岩脉,多呈岩墙、岩枝和小岩滴。基性岩脉岩石类型为辉长岩和辉绿岩。辉长岩属于碱性玄武岩,而辉绿岩属于过铝质碱性系列碱玄武岩与粗面玄武岩过渡型,其形成深度（浅成相）比辉长岩浅（中深成相）。区内基性岩脉形成于闭合边缘岛弧、活动陆缘造山带环境,是由幔源原生岩浆经过分异并同化混染地壳物质而形成,结晶分异是控制岩浆演化的主要因素。辉长岩中δEu具有弱的亏损。辉绿岩δEu为正异常,而C e均具弱亏损,成岩氧逸度较高,其成因与典型的I型花岗岩类相似,为壳幔混合型。辉长岩偏幔源,而辉绿岩偏壳源,可能为幔源岩浆上侵受围岩混染所致。辉长岩年龄（119 M a）要比辉绿岩年龄（46.1M a）老,辉长岩为冈底斯陆块向欧亚大陆板块碰撞拼贴过程中,逆冲挤压结束的标志,辉绿岩为大规模逆冲挤压剪切结束,青藏高原隆升初期拉张作用的产物。