西藏雄村斑岩型铜(金)矿床Ⅰ、Ⅱ号矿体热液黑云母特征及地质意义

雄村铜(金)矿区位于西藏冈底斯成矿带中段南缘,由Ⅰ、Ⅱ、Ⅲ号矿体和多个矿化体组成。本文以Ⅰ、Ⅱ号矿体钾硅酸盐化蚀变带内的热液黑云母为研究对象,采用光薄片镜下鉴定、电子探针等分析方法,系统研究了热液黑云母的产状和成分特征。结果显示,雄村矿区Ⅰ号矿体黑云母类型主要为金云母和镁质黑云母;Ⅱ号矿体黑云母类型为镁质黑云母。两个矿体黑云母都具有低Ti(TiO_2 3%)、高Al(Al_2O_315%)的特点,且具有较高的MgO含量,Mg/Fe0.5,K/Na10,显示了与矿化良好的相关性。Ⅰ号矿体热液黑云母平均结晶温度470℃,氧逸度位于镍-氧化镍缓冲剂与磁铁矿-钛铁矿缓冲剂之间(NNO—HM);Ⅱ号矿体热液黑云母平均结晶温度234℃,氧逸度位于镍-氧化镍缓冲剂与铁橄榄石-石英-磁铁矿缓冲剂之间(NNO—FQM),说明Ⅰ号矿体形成于较高温、高氧逸度的热液系统,Ⅱ号矿体形成于相对较低温、低氧逸度的热液系统。此外,Ⅰ号矿体热液黑云母Ⅳ(F)值介于0.61～2.72之间,平均值1.26,Ⅳ(Cl)值介于-5.49～-4.53之间,平均值-5.03,Ⅳ(F/Cl)值介于5.63～7.89之间,平均值6.29;Ⅱ号矿体热液黑云母Ⅳ(F)值介于1.83～3.32之间,平均值2.66,Ⅳ(Cl)值介于-5.64～-4.89之间,平均值-5.31,Ⅳ(F/Cl)值介于7.14～8.68之间,平均值7.97,说明Ⅰ、Ⅱ号矿体都形成于富Cl的热液系统,且Ⅱ号矿体热液较Ⅰ号矿体更富Cl,贫F。富Cl流体易萃取流体中的Cu和Au等金属元素并以Cl的络合物形式运移,在沿构造裂隙向上运移的过程中,物理化学条件发生改变,使得流体中金属元素络合物溶解度降低,促使硫化物沉淀成矿。     

福建李坊重晶石矿床中硅质岩硅、氧同位素组成及成因意义

福建李坊大型重晶石矿床围岩中发育层状硅质岩,为了研究硅质岩的成因,本文对14件硅质岩样品进行了硅、氧同位素分析。结果表明:δ(~(30)Si)分布范围为-0.3×10~(-3)～+0.1×10~(-3),平均值为-0.1×10~(-3);δ(~(18)O)分布范围为10.6×10-3～18.9×10-3,平均值为14.7×10~(-3)。基于该层状硅质岩的δ(~(30)Si)和δ(~(18)O)分布范围特征,结合野外地质调查研究工作的认识,该硅质岩应为原生沉积成因,二氧化硅来源于热水沉积;根据燧石-海水氧同位素地质温度计估算石英的形成温度为100.2℃—198.7℃,平均值为146.0℃,即该硅质岩形成于热水沉积,暗示李坊重晶石矿床形成于热水沉积作用。     

OIPC和RCWIP降水氢氧稳定同位素数据在新疆天山地区的适用性

降水中氢氧稳定同位素的空间分布是同位素水文学和同位素生态学研究的基础资料, 近年来高空间分辨率的氢氧稳定同位素分布数据产品获得了越来越多的重视。利用新疆天山地区实测降水同位素数据, 评估两套常用的全球降水同位素分布模拟数据（OIPC和RCWIP）的适用性。结果表明： 从时间尺度来看, 两套产品在夏半年（4 - 10月）的模拟效果明显优于冬半年（11月 - 次年3月）; 在各自然区中, 准噶尔盆地荒漠自然区的模拟效果相对较好, 而吐鲁番盆地-哈密（戈壁）荒漠自然区模拟效果相对较差。通过均方根误差、 线性判定系数、 平均偏置误差、 平均绝对误差等指标的比较, 在本研究区内RCWIP数据产品对降水同位素值的模拟效果比OIPC的效果好。结合乌鲁木齐多年降水氢氧稳定同位素数据, 发现降水同位素年际变化差异并未明显影响到代表性, 在缺乏长期监测的情况下这两套数据仍有重要的使用价值。     

邯邢地区中生代侵入岩中磷灰石的成因矿物学研究

氧逸度为有效的氧分压,是实验岩石学中重要的研究课题,岩浆的氧逸度是继温度、压力、浓度等影响成岩成矿过程的关键性物理化学参数。本文利用磷灰石的氧逸度计,对邯邢地区六大主要岩体的岩浆氧逸度进行了计算。研究结果显示,样品中的磷灰石主要为羟-氟磷灰石,磷灰石的形态、成分和结构特征指示其为岩浆成因。磷灰石中的Mn元素在晶格中有两种方式,多以Mn3＋和Mn5＋的方式进入晶格。磷灰石氧逸度计计算的logfo2为-12.31~-9.75,均值-11.02。参考与磷灰石共生角闪石的形成温度,认为邯邢地区岩浆岩普遍具有较高的氧逸度。根据磷灰石氧逸度值与矿床规模的填图结果,认为并非氧逸度越高越有利于邯邢式铁矿的形成。结合矿物学填图等值线闭合的趋势,进而推断邯邢地区中部的符山和武安岩体深部可能仍存在较好的找矿远景。     

A Late Pleistocene marine clay succession at Kriegers Flak,westernmost Baltic,southern Scandinavia

In the Baltic Sea south of Skåne county in southern Sweden, an over- consolidated marine clay succession on the northeastern slope of Kriegers Flak was observed in shallow seismic data as a unit overlain by younger Weichselian sediments. Two cores were taken from the clay succession. The Foraminifera present were predominantly of two species, Elphidium excavatum and Elphidium albiumbilicatum, reflecting deposition under arctic– boreal conditions. Stable oxygen isotope analyses were performed on foraminiferal tests, and the results show extremely light δ¹⁸O values ranging between −11‰ and −12‰. The cause of these extreme values is uncertain but may result from the high influence of meltwater. Brackish conditions are also indicated by the tolerance for low salinity shown by the Foraminifera. Radiocarbon dating shows an infinite age >40000 yr BP. The pollen flora seems mainly to have been redeposited, which makes interpretation difficult. The sea may have entered the Baltic basin during periods with high eustatic levels, an isostatic downloading of the crust, or a combination of both. It is suggested that the deposition of the overconsolidated marine clay succession occurred in the Late Saalian, Early Eemian or Early Weichselian. © 1998 John Wiley & Sons, Ltd.     

High‐Precision,High‐Accuracy Oxygen Isotope Measurements of Zircon Reference Materials with the SHRIMP‐SI

Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ¹⁸O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ¹⁸O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ¹⁸O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ¹⁸O values associated with low‐U zircon grains.     

Cu–Mo Differential Mineralization Mechanism of the Dabate Polymetallic Deposit in Western Tianshan,NW China: Evidence from Geology,Fluid Inclusions,and Oxygen Isotope Systematics

Classic porphyry Cu–Mo deposits are mostly characterized by close temporal and spatial relationships between Cu and Mo mineralization. The northern Dabate Cu–Mo deposit is a newly discovered porphyry Cu–Mo polymetallic deposit in western Tianshan, northwest China. The Cu mineralization postdates the Mo mineralization and is located in shallower levels in the deposit, which is different from most classic porphyry Cu–Mo deposits. Detailed field investigations, together with microthermometry, laser Raman spectroscopy, and O‐isotope studies of fluid inclusions, were conducted to investigate the origin and evolution of ore‐forming fluids from the main Mo to main Cu stage of mineralization in the deposit. The results show that the ore‐forming fluids of the main Mo stage belonged to an NaCl + H₂O system of medium to high temperatures (280–310°C) and low salinities (2–4 wt% NaCl equivalent (eq.)), whereas that of the main Cu stage belonged to an F‐rich NaCl + CO₂ + H₂O system of medium to high temperatures (230–260°C) and medium to low salinities (4–10 wt% NaCl eq.). The δ¹⁸O values of the ore‐forming fluids decrease from 3.7–7.8‰ in the main Mo stage to ?7.5 to ?2.9‰ in the main Cu stage. These data indicate that the separation of Cu and Mo was closely related to a large‐scale vapor–brine separation of the early ore‐forming fluids, which produced the Mo‐bearing and Cu‐bearing fluids. Subsequently, the relatively reducing (CH₄‐rich) Mo‐bearing, ore‐forming fluids, dominantly of magmatic origin, caused mineralization in the rhyolite porphyry due to fluid boiling, whereas the relatively oxidizing (CO₂‐rich) Cu‐bearing, ore‐forming fluids mixed with meteoric water and precipitated chalcopyrite within the crushed zone at the contact between rhyolite porphyry and wall rock. We suggest that the separation of Cu and Mo in the deposit may be attributed to differences in the chemical properties of Cu and Mo, large‐scale vapor–brine separation of early ore‐forming fluids, and changes in oxygen fugacity.     

封闭系统中的白云石化作用过程及其油气地质意义——以南羌塘拗陷中侏罗统布曲组白云岩为例

南羌塘拗陷中侏罗统布曲组结晶白云岩作为盆地最优质的储层是通过埋藏成岩过程中封闭条件下的白云石化作用形成的,岩石所具有的高孔隙度与封闭系统中白云石化反应有关。根据对羌资11井和羌资12井布曲组的岩石结构分类、碳氧同位素组成及温度计算、流体包裹体均一温度等分析结果,可以认为：结晶白云岩碳同位素值分布区间较窄（2. 86‰~4. 27‰）,氧同位素值随着白云石晶体变粗（自形程度变差）逐渐偏负（-3. 27‰~-8. 17‰）,显著低于保留原始组构的白云岩,表明结晶白云岩碳源来自于先驱灰岩中的碳,其白云石化作用应是在远离大气水的封闭成岩环境中进行;结晶白云岩流体包裹体均一温度主峰值区间为90~140 ℃,且随着白云石晶粒变粗（自形程度变差）,均一温度呈升高的趋势,与氧同位素计算温度变化趋势一致,表明白云石化作用过程是在封闭的条件下进行,白云石随地热增温而生长,并非受外来流体的影响。开放系统中的白云石化作用对油气储集空间的形成没有实际意义,而埋藏成岩过程中封闭系统的白云石化是形成南羌塘拗陷优质储层最为重要的成岩机制。     

水动力条件对沉积物-水界面氧通量的影响

氧环境决定了水体沉积物中各种生命所需元素的最终归趋,沉积物-水界面是水相与沉积物相氧传递的重要场所,而水动力条件是影响沉积物-水界面氧传递的重要因素.选择三峡库区一级支流御临河为研究对象,根据长年监测数据建立实验室模型,采用声学多普勒流速测试仪及微电极测试系统构建了非侵入式涡度相关测试系统,探究了不同水动力条件对沉积物-水界面氧通量的影响.结果表明：水体静止状态下沉积物-水界面溶解氧浓度随时间的增加而减少,非静止状态下随时间的增加而增加;沉积物-水界面氧通量随水体流速的增加而增加.根据氧通量求解对应流速下垂直涡动扩散系数并进行线性拟合,当水体流速为0.01~0.14 m/s时,垂直涡动扩散系数与水体流速的相关性最好,此时沉积物-水界面氧通量的传递以涡动扩散为主导.     

Dynamics and driving mechanisms of asymmetric human water consumption during alternating wet and dry periods

Increases in human water consumption (HWC) and consequent degradation of the ecological environment are common in arid regions. Understanding the mechanisms behind these processes is important for sustainable development. Analyses of changes in HWC between alternating wet and dry periods are carried out in four arid inland basins in Central Asia and China (Syr Darya, Tarim, Heihe and Shulehe river basins). Based on runoff records, the presence of an asymmetric HWC response is proved (p < 0.01), with an increase in HWC during wet periods and a muted decrease during subsequent dry periods. This behaviour is interpreted by invoking theories from behavioural economics at the individual and community levels. A simple model based on these theories is shown to be able to reproduce the observed dynamics and is used to discuss the importance of strengthening institutional factors for water sustainability.