Interplay of S and As in Mekong Delta sediments during redox oscillations

The cumulative effects of periodic redox cycling on the mobility of As,Fe,and S from alluvial sediment to groundwater were investigated in bioreactor experiments.Two particular sediments from the alluvial floodplain of the Mekong Delta River were investigated:Matrix A(14 m deep)had a higher pyrite concentration than matrix B(7 m deep)sediments.Gypsum was present in matrix B but absent in matrix A.In the reactors,the sediment suspensions were supplemented with As(Ⅲ)and SO_4~(2-),and were subjected to three full-redox cycles entailing phases of nitrogen/CO_2,compressed air sparging,and cellobiose addition.Major differences in As concentration and speciation were observed upon redox cycling.Evidences support the fact that initial sediment composition is the main factor controlling arsenic release and its speciation during the redox cycles.Indeed,a high pyrite content associated with a low SO_4~(2-)content resulted in an increase in dissolved As concentrations,mainly in the form of As(Ⅲ),after anoxic half-cycles;whereas a decrease in As concentrations mainly in the form of As(Ⅴ),was instead observed after oxic half-cycles.In addition,oxic conditions were found to be responsible for pyrite and arsenian pyrite oxidation,increasing the As pool available for mobilization.The same processes seem to occur in sediment with the presence of gypsum,but,in this case,dissolved As were sequestered by biotic or abiotic redox reactions occurring in the Fe—S system,and by specific physico-chemical condition(e.g.pH).The contrasting results obtained for two sediments sampled from the same core show that many complexes and entangled factors are at work,and further refinement is needed to explain the spatial and temporal variability of As release to groundwater of the Mekong River Delta(Vietnam).     

硫氧同位素示踪污染物来源在济南岩溶水中的应用

近年来,济南岩溶水硫酸盐浓度逐年升高,为了对硫酸盐污染区域实施有效的防治措施,保障饮用水安全,识别硫酸盐的污染来源极其重要。在系统分析研究区水文地质条件的基础上,根据实际的采样测试数据,采用硫、氧(S、O)双同位素示踪技术,分析识别了济南趵突泉泉域硫酸盐的主要污染来源,并通过IsoSource质量守恒模型,估算了硫酸盐各污染来源的贡献率。结果表明: 泉域内硫酸盐主要污染来源有大气沉降、污水和土壤; 大气沉降来源贡献率最大,均值达到53.9%; 其次是污水来源,均值为31%; 土壤来源贡献率最小,均值为15.1%。该研究为北方岩溶区地下水硫酸盐来源的定量研究提供了一种新方法,为济南趵突泉泉域硫酸盐污染防治提供了科学依据。     

细菌反硝化法测试硝酸盐氮、氧同位素的研究与应用

为了验证细菌反硝化法对水体中硝酸盐氮、氧同位素组成测定的适用性、重现性及准确性, 在不同时间(2019年7月28日、8月19日、8月26日)利用反硝化细菌分别将海水、湖水和自来水样品中的硝酸盐转化为氧化亚氮（N₂O）, 并进行氮、氧同位素测定。结果表明, 不同时间段3个批次实验的硝酸盐氮同位素校准曲线斜率都接近理论值1, 相关性系数均高于0.999, 说明反硝化细菌在将样品中的硝酸盐全部还原为N₂O的过程中氮同位素分馏效应很小; 同一样品3个批次测定的硝酸盐的氮同位素值基本相同, 表明细菌反硝化法对硝酸盐氮同位素的测定在长时间周期内具有很好的重现性和准确性。3个批次氧同位素校准曲线斜率稳定在0.61～0.63之间, 相关性系数均高于0.99, 单批次内海水、湖水和自来水3类样品中硝酸盐氧同位素比值的标准偏差范围在0.18‰～0.69‰之间, 表明经过氧同位素校准曲线的校正, 可以准确反映样品中硝酸盐氧同位素组成; 同一样品3个批次测定的氧同位素值差异较大, 其变化范围为1.33‰～16.38‰, 可能是由于样品储存过程中硝酸盐与水之间发生的氧同位素交换作用所致。     

Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.     

The role of fog,orography, and seasonality on precipitation in a semiarid,tropical island

Isotopes of water (²H/¹H and ¹⁸O/¹⁶O) are commonly used to trace hydrological processes such as moisture recycling, evaporation loss, and moisture source region and often vary temporally in a given region. This study provides a first‐ever characterization of temporally variable precipitation mechanisms of San Cristóbal Island, Galápagos. We collected fog, rain, and throughfall samples over three field seasons to understand the mechanisms driving seasonal‐ and event‐based variability in the isotopic composition of precipitation in Galápagos. We establish that fog is a common phenomenon in San Cristóbal, especially during the dry season, and we found that fog, compared with cocollected rainfall, is consistently enriched. We further suggest that the relative contribution of fog formed via different mechanisms (orographic, advective, radiation) varied seasonally. We found that the source region is the most dominant control of the isotopic composition of rainfall in the Galápagos at both the seasonal and event scales, but subcloud evaporative processes (the nontraditional manifestation of the amount effect) became a dominant control on the isotopic composition of rainfall during the dry season. Overall, our findings suggest that understanding seasonally variable water‐generating mechanisms is required for effective water resource management in San Cristóbal Island and other semiarid island ecosystems under current and future regimes of climate change.     

Calibration of oxygen isotope fractionation and calcite-corundum thermometry in emery at Naxos,Greece

Corundum (Crn), including sapphire, occurs in emery pods surrounded by marble on the island of Naxos, Greece. The emery formed from bauxite deposited in karst that was metamorphosed to 400–700°C at 20–15 Ma. Many of these rocks initially appeared well suited for refractory accessory mineral (RAM) thermometry, which uses oxygen isotope fractionation between a RAM – corundum – and a modally dominant phase with faster diffusion of oxygen – calcite (Cc) – to determine peak metamorphic temperatures. However, previous attempts at oxygen isotope thermometry were confounded by highly variable fractionations (Δ¹⁸O) measured at mm-scale and the uncertain calibration of Δ¹⁸O(Cc-Crn) versus temperature. Secondary ion mass spectrometry (SIMS) permits in situ analysis of δ¹⁸O in corundum and calcite at the 10-μm scale in adjacent grains where textures suggest peak metamorphic equilibrium was attained. SIMS analyses of adjacent mineral pairs in eight rocks yield values of Δ(Cc-Crn) that systematically decrease from 7.2 to 2.9‰ at higher metamorphic grade. Pairing these data with independent temperature estimates from mineral isograds yields an empirical calibration of 1,000 lnα(Cc-Crn) = 2.72 ± 0.3 × 10⁶/T² (T in K). The new fractionations (2.7‰ at 1,000 K) are significantly smaller than those calculated from the modified increment method (6.5‰ at 1,000 K; Zheng, Geochimica et Cosmochimica Acta, 1991, 55:2299–2307; Zheng, Mineral Mag, 1994, 58A:1000–1001), which yield unreasonably high temperatures of 630 to 1,140°C when applied to the new Naxos data. The new calibration of Δ(Cc-Crn) can be combined with published fractionations to calculate A-factors for corundum versus a range of 14 other minerals. These new fractionation factors can be used for thermometry or to constrain the genesis of corundum. A compilation of gem corundum δ¹⁸O values shows that many igneous sapphires, including important deposits of basalt-associated sapphire, are mildly elevated in δ¹⁸O relative to the calculated range in equilibrium with mantle values (4.4–5.7‰) and formed from evolved magmas.     

青藏高原"一江两河"农区居民食物消费结构与特征

居民食物消费受自然地理环境、城镇化等因素影响,同时通过市场机制影响区域粮食安全和农牧业发展。以西藏“一江两河”地区为例,基于分层抽样,通过2019年实地入户调研,获取了262户农村居民上年度食物消费数据,对青藏高原农区居民的食物消费结构及其影响因素进行分析。结果表明：① 样本内居民的植物性食物的消费量是动物性食物的3.19倍,植物性食物以蔬菜和粮食为主,动物性食物以肉类和牛奶为主;青稞及青稞酒在藏民饮食中占有重要地位。② 居民食物消费规模和结构与食物自给率指标密切相关,自给自足特征显著。③ 不同地区、家庭规模、务工规模、收入水平以及家庭年龄之间,居民的家庭食物消费结构均有所差异,且不同家庭之间面粉和水果的消费差异最显著。④ 区域差异、家庭规模类型和家庭务工规模是影响样本农区居民食物消费综合差异的主要因素。结果可为青藏高原地区居民食物消费结构改善、膳食营养提升以及农牧业转型发展提供科学基础和决策借鉴。     

2022冬奥会背景下北京区域居民参与冰雪运动消费调查

运用文献资料、问卷调查和数理统计、应用因子分析方法,结合北京区域滑雪场空间分布情况,对比居民冰雪运动参与倾向和频率,发现北京区域居民参与冰雪运动及消费的主要影响因素为性别、年龄、距离、收入水平和政策红利;分析得出雪场密度和区域经济水平、性别等对参与冰雪运动消费特征的影响。归纳4个主要影响北京区域居民参与冰雪运动的公共因子,分别是冰雪运动基础因子、冰雪运动信息因子、冰雪运动距离因子以及冰雪运动友谊因子。提出不断提升冰雪运动产品服务质量,出台鼓励性冰雪运动消费政策,完善冰雪运动消费环境,创新冰雪运动消费内容,逐步扩大冰雪消费规模等建议。     

黄河流域多尺度水系统结构变化特征

大河流域的水系统是支撑社会-生态系统的基础,理解水系统的结构变化是深入揭示区域系统演化的关键。基于自然-社会水系统视角,从黄河全流域和二级水资源分区尺度,利用1998—2018年降水、蒸发、径流、社会经济耗水等水系统变量,通过Mann-Kendall趋势检验和线性回归分析方法,分析了水系统要素的变化趋势及结构演变特征。结果表明：在全流域尺度,降水、蒸发分别以4.25 mm·a^-1、4.09 mm·a^-1的速率上升,但蒸发在空间上的变化更显著;径流量呈现先减少再上升后急剧下降的趋势,且与降水量显著正相关。社会系统耗水量呈现增速减缓的特征,农业灌溉占耗水结构的比例以0.50%的速率逐年下降;城镇公共、居民生活和生态环境耗水比例分别以0.07%、0.29%、0.11%的速率上升。在二级水资源分区尺度,各水系统分异特征明显,兰州至头道拐段及花园口以下区域水系统所支撑社会经济发展的功能已经出现了超载。各水系统要素间具有不同程度的协同演变趋势,在湿润区域,蒸发相较于降水具有明显的滞后现象,但在干旱区域两者变化趋势基本一致。黄河流域水系统要素在时空上均存在明显的异质性,未来人口和经济的进一步发展可能会使区域的水资源压力加剧。