不同采样点数量下土壤有机质含量空间预测方法对比

运用普通克里格、泛克里格、协同克里格和回归克里格4种方法,结合由DEM获取的高程因子以及土壤全氮和阳离子交换量（CEC）,预测了黑龙江省海伦市耕地有机质含量的空间分布。不同样点数量下海伦市土壤有机质含量的空间变异结构分析表明,样点数量多并不一定能够识别土壤有机质含量的结构性连续组分,最优化的布置采样点位置可能比单纯增加...     

A multi-method approach for the study of lanthanum speciation in coastal and estuarine sediments

Two independent analytical methods (sequential extraction and kinetic extraction methods) were applied in order to understand the distribution and speciation of La in the coastal and estuarine sediments from the central east coast of India. Sequential extraction study revealed that La was primarily present as inert complexes (~ 50–60% of the total La) in all the sediments. Amounts of ~ 20–30% of the total La in all the sediments were found to associate with the total organic carbon (TOC) in the sediments. The dissociation rate constants of La–sediment complexes obtained from kinetic extraction studies revealed that the concentration of thermodynamically weak complexes of La gradually increased with the increasing La/TOC ratio in the sediments.     

鸡西盆地城子河组泥岩有机质保存条件研究

鸡西盆地作为我国东北地区重要的煤炭基地,已在多口钻井中发现油气显示。早白垩世城子河组为一套夹数个海相泥岩层的含煤岩系,形成于滨浅湖—沼泽的沉积环境,为该盆地主力烃源岩层。本次对该层位泥岩样品的常、微量元素全分析结果表明,水体盐度指标Sr/Ba在0.11～0.38之间,碱度指标（Ca＋Mg）＊20/（Si＋Al）为0.2...     

塔里木盆地西北缘海相白垩系-古近系界线沉积物环境指标研究

发生于中生代-新生代之间的事件是地质历史上一次重大灾变和异常事件,因此白垩系-古近系之间的界线(K/T界线)就成为全球最重要的地质界线之一.通过对塔里木盆地西北缘乌恰地区库孜贡苏河剖面海相上白垩统-古新统地层的岩性和沉积环境变化以及地球化学特征研究,重点利用沉积物色度、有机碳含量、碳酸钙和碳、氧稳定同位素的明显异常变化...     

Human Health Risk Assessment Model of Organic Pollution in Groundwater: Shijiazhuang Industrial Zone

In this study, a risk-based management model is developed and applied to an industrial zone. The models proposed by the United States Environmental Protection Agency and Han Bing have been improved by adding a residual ratio of volatile organic compounds (VOC) after boiling and deleting the related parameters in half-life. Using this improved model, an integrated process was used to assess human health risk level in the study area. Compared with water quality analysis, the results highlight the importance of applying an integrated approach for decision making on risk levels and water protection. The results of this study demonstrated that: (1) Compared with these permissible level standards in China (GB 3838-2002) and National Primary Drinking Water Regulations of the United States, the residents’ daily life had not been affected by the groundwater in this area (except for relative bad water quality of HB3-4 and HB3-6); (2) The typical detected organic contaminants of all groundwater samples were chloroform, carbon tetrachloride, trichloroethylene and tetrachloroethene, and the pollution sources were mainly industrial sources by preliminary investigations; (3) As for groundwater, the non-carcinogenic risk values of all samples do not exceed the permissible level of 1.0 and the carcinogenic risk values are relatively lower than the permissible level of 1.00E-06 to 1.00E-04; (4) Drinking water pathway of trichloroethylene and tetrachloroethylene mainly contribute to increasing the health risk of residents’ in study areas; (5) In terms of non-carcinogenic risk and carcinogenic risk, the health risk order for drinking water pathway and dermal contact pathway was: drinking water pathway > dermal contact pathway.     

我国主要农耕区水稻土有机碳含量分布及影响因素研究

水稻土是我国主要的耕作土壤之一,水稻土有机碳变化与全球气候变化息息相关,因此研究我国主要农耕区水稻土有机碳含量分布特征及影响因素具有重要的现实意义。本文基于全国多目标地球化学调查1：250000土壤数据库,以行政区划分析了水稻土有机碳分布规律,从土壤pH值、年均气温、年均降雨量、耕作方式等角度探讨了其对水稻土有机碳含量...     

有机溴化物的溴同位素测试技术及其生物地球化学指示意义

有机溴化物已成为继有机氯化物之后又一值得关注的全球性新兴持久性有机污染物。稳定Br同位素测试技术的快速发展,为有机溴化物生物地球化学循环研究提供了更为有效的技术支撑。在综述稳定Br同位素研究进展的基础上认为：①基于GC-MC-ICPMS技术基础上的有机单体Br同位素（CSIA-OBr）是Br同位素研究的主要趋势,难点是...     

Microscopic Analyses of Insoluble Particles in an Ice Core of ürümqi Glacier No. 1: Quantification of Mineral and Organic Particles

Insoluble particle concentration in ice cores is commonly analyzed as a proxy for varia-tions in atmospheric mineral dust (aerosol concentration). However, recent studies have revealed that the mineral dust is not only a constituent of the particles but that biogenic organic particles are also contained. We microscopically analyzed insoluble particles in a shallow ice core drilled on a mountain glacier, the ürümqi Glacier No. 1, in eastern Tienshan, China. We distinguished different morphologi-cal particles...     

Temporal and spatial variability of dissolved organic carbon concentration in the Xijiang River, South China

A whole year analysis of riverine dissolved organic carbon (DOC) concentrations in the Xijiang River (XJR), South China, showed that the mean riverine DOC concentration (1.24 mg L-1) in the XJR was notably lower than the averaged value (5.75 mg L-1) of the global riverine DOC concentration in several major rivers. There is an inconspicuous monthly fluctuation of the DOC signal in the XJR, but on a semi-yearly time scale, however, the riverine DOC concentration had significant difference between hydrological...     

基于HJ1A-HSI超光谱影像的耕地有机质遥感定量反演

以环境小卫星超光谱影像为主要数据源,在耕地有机质实测样本的支持下,开展光谱反射率及其变化形式与有机质的相关性分析,筛选耕地有机质响应的敏感波段与特征组合算法,利用多元回归分析方法,建立基于HSI影像的耕地有机质定量反演模型。研究结果表明,耕地有机质的HSI影像响应波段均位于可见光与近红外波段间,其中以540～860nm范围最佳,相关系数均在0.5左右;HSI反射率对数一阶微分预测模型精度最高,模型及其检验的决定系数都在0.7以上,均方根误差在0.2%左右,可用于顺义区耕地有机质全覆盖空间填图。因此,环境小卫星的超光谱影像对耕地有机质含量具有较好的光谱响应能力,其空间覆盖能力有助于开展县域尺度的耕地有机质遥感反演和空间填图。