The role of vibrationally excited nitrogen in the ionosphere

Theoretical and experimental aspects of the production, transformation, diffusion and loss of N₂ in the upper atmosphere are considered. The N₂-CO₂ near-resonant system in theD andE regions is taken into account. We describe our understanding of the methods necessary to find the vibrational populations of N₂ and CO₂ (asymmetric mode of CO₂). The calculations of the vibrational temperatures in theD, E, andF regions for the mid-latitude ionosphere and an aurora are presented. The connection between the excited species and the 4.26-m radiation intensities is considered. The models for the rate coefficient of the reaction of O⁺ with N₂ and the electron density decrease resulting from N₂ in the F region are discussed.     

Phosphorus and nitrogen limitation of algal biomass across trophic gradients

Regression results based on data from 46 northern temperate lakes show that total phosphorus (TP) is the best predictor for phytoplankton (as chl-a) at lower trophic levels, TP < 200 mg · m^–3. A regression including both TP and TN as regressors is the best predictor for lakes with TP > 200 mg · m^–3. However, the good correlation is probably due to a high correlation between lake average chl-a (all years observed) and lake average TP and TN. Within single hypereutrophic lakes, TN alone is the best predictor. It was not possible to identify a medium trophic domain where TN and TP in combination was the best predictor for chl-a. The ratio TN:TP in the water decreases from about 40 to about 5 with increasing trophic level. Optimum TN:TP ratio for algal species with high abundance during late summer and autumn reflects this decreasing ratio, but within a lesser range, i.e., 20 to 5. In contrast, TN:TP ratios for species abundant during the early vernal period showed no, or an inverse, relation to the TN:TP ratio of the water.     

Historical changes in sediments of Pyramid Lake,Nevada, USA: consequences of changes in the water balance of a terminal desert lake

Sediment cores from the shallow and deep basins of Pyramid Lake, Nevada, revealed variations in composition with depth reflecting changes in lake level, river inflow, and lake productivity. Recent sediments from the period of historical record indicate: (1) CaCO₃ and organic content of sediment in the shallow basin decrease at lower lake level, (2) CaCO₃ content of deep basin sediments increases when lake level decreases rapidly, and (3) the inorganic P content of sediments increases with decreasing lake volume. Variations in sediment composition also indicate several periods for which productivity in Pyramid Lake may have been elevated over the past 1000 years. Our data provide strong evidence for increased productivity during the first half of the 20th Century, although the typical pattern for cultural eutrophication was not observed. The organic content of sediments also suggests periods of increased productivity in the lake prior to the discovery and development of the region by white settlers. Indeed, a broad peak in organic fractions during the 1800's originates as an increase starting around 1600. However, periods of changing organic content of sediments also correspond to periods when inflow to the lake was probably at extremes (e.g. drought or flood) indicating that fluctuations in river inflow may be an important factor affecting sediment composition in Pyramid Lake.     

一个高分辨对流层物质交换模式

在区域酸沉积模式(RADM)基础上,设计了一个高分辨对流层(TL)物质交换模式(EM3)。EM3在以下五个方面明显不同于RADM:第一,增加行星边界层(PBL)的垂直网格层次;第二、TL内考虑分层的垂直涡旋扩散系数型;第三,使用TL内分层的水平涡旋扩散系数型;第四,采用包含有植物冠层垂直结构影响的新干沉积速度型;第五,使用数值扩散小的二阶矩守恒平流格式.用EM3和RADM对OSCAR Ⅳ实例作对比模拟,结果表明EM3能更好地预测出TL内的三维物质分布规律,在同样条件下,两模式预测的PBL低层中心浓度比值均大于1.8,最大值可大于3。     

Interpretation of210Pb profiles and verification of the CRS dating model in PIRLA project lake sediment cores

This paper reports results and analysis of²¹⁰Pb-activity measurements in 51 lake-sediment cores from 32 lakes in the four PIRLA (Paleoecological Investigations of Recent Lake Acidification) project regions (Adirondack Mountains [New York], Northern New England, Northern Florida, and the Northern Great Lakes States). General application of the Constant Rate of Supply (Constant Flux) model for²¹⁰Pb dating is valid for lakes in the PIRLA study, although application of the model is equivocal in a few lakes.²¹⁰Pb inventories and profiles are replicable among closely spaced cores within a lake. Specific²¹⁰Pb activity in surface sediments is negatively correlated with bulk sediment accumulation rate in seepage lakes, but not in drainage lakes. Drainage lakes with lower pH have lower unsupported²¹⁰Pb inventories in sediments, but the relationship does not occur in seepage lakes.²¹⁰Pb profiles in only seven of the cores, all from either the Adirondacks or the northern Great Lakes states, exhibit exponential decay curves. Deviations from an exponential profile include a flattening of the profile in the top few cm or excursions of one or a few measurements away from an exponential curve.²¹⁰Pb dates typically agree with other chronostratigraphic markers, most of which are subject to greater uncertainty. Several hypotheses, including sediment mixing, hydrologic regime, sediment focusing, and acidification, are proposed to explain variation of²¹⁰Pb distribution among lakes and regions. Hydrologic factors exert control on unsupported²¹⁰Pb inventories in PIRLA lakes, and there is a strong focusing effect in drainage lakes but a weak focusing effect in seepage lakes.This is the third of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

SEDIMENT TRANSPORT OF LOW CONCENTRATION IN PIPES

The study of Sediment transport of low concentration in pipes bas been applied in the design of a self-cleansing storm sewer. An alternative criterion is suggested as op- posed to the widely used single flow velocity approach. A conceptual model which simu- lates the condition in a storm sewer is developed and tested against experimental data. The results proved that the volumetric sediment concentration, pipe diameter and sedi- ment size have to be taken into consideration to produce a self-cleansing storm sewer. It also shows that the slope obtained by this alternative criterion is lower than the single flow velocity approach.     

Deposition of trace substances via cloud interception on a coniferous forest at Kleiner Feldberg

A resistance model to calculate the deposition of cloud droplets on a coniferous forest and some improved parameterizations of the indispensable input parameters are described. The deposition model is adapted to the coniferous forest at the Kleiner Feldberg site and verified by the data of a drip water monitoring station below the forest canopy. The measurements of liqud water content, wind speed and trace substance compounds in cloud water of the Ground-based Cloud Experiment (GCE) at Kleiner Feldberg in 1990 are used to calculate the cloud water deposition fluxes and the deposition of trace substances via cloud water interception. The calculated deposition of trace substances via cloud water interceptions is three to six times higher than via rain during the experiment. On a long term data basis the yearly amount of cloud water deposition is 180 mm year^–1 at Kleiner Feldberg site (840 m a.s.l.) while the precipitation amount is 1030 mm year^–1. Due to higher trace substance concentrations in cloud water compared to rain the ionic deposition via cloud water interception and via precipitation were assessed to be of comparable magnitude.     

论雾与污染的关系

简述了近年来雾的研究进展，并从雾的酸化、雾层内污染物的扩散、雾层对污染物的清除、污染物对雾形成与发展的影响等方面讨论了雾与大气污染的关系。     

Physical and chemical characteristics of a metal-contaminated overbank deposit,west-central South Dakota,U.S.A.

A metal-contaminated overbank deposit in west-central South Dakota resulted from the discharge of a large volume of mine tailings into a river system between the late 1800s and 1977. The deposit along the Belle Fourche River is typically up to 2 m thick and extends about 90 m away from the channel along the insides of meander bends. The sediments contain above-background levels of copper, iron, manganese, zinc, and particularly arsenic, which is commonly two orders of magnitude above background level in the contaminated sediments. Carbonate minerals in the deposit limit the desorption of arsenic by preventing acid formation. Arsenic concentrations provide a measure of the dilution of mine tailings by uncontaminated sediment. The arsenic appears to have been transported and deposited as arsenopyrite, but is now at least partially associated with iron oxides and hydroxides. Within individual samples, arsenic concentration has an inverse relation with grain size that results from the more efficient accumulation of arsenic on the greater surface area of the smaller particles. Arsenic concentration is inversely related to the sample weight percent finer than 16 μm, however, as a consequence of the dilution of the contaminated sediments by uncontaminated sediment with a finer grain-size distribution. Dilution by uncontaminated sediment from tributaries cause arsenic concentrations to decrease by a factor of 3 along 100 km of floodplain. An influx at high streamflow of uncontaminated sediment from terraces and the premining floodplain as well as from tributaries causes arsenic concentrations in parts of the contaminated deposit that are farthest away from the channel to be two to three times less than arsenic concentrations in overbank sediment that is immediately adjacent to the channel.