中国东南沿海地区PWV直接转换模型研究

针对东南沿海地区GNSS大气可降水量(PWV)计算过程参数多、数据量大、效率不高且易产生累积误差等问题,本文基于中国东南沿海地区2017~2018年18个CORS站的GNSS数据,分析GNSS-PWV与对流层延迟(ZTD)、地面气温(T_s)和地面大气压(P_s)之间的线性关系,并利用多元线性拟合方法建立多因子GNSS-PWV直接转换模型,为研究区提供简捷高效的PWV计算方法。结果表明,GNSS-PWV与ZTD、P_s和T_s之间具有良好的相关性,相关系数分别为0.98、－0.65和0.78;基于ZTD、P_s和T_s的多因子PWV模型RMS为0.33 mm,精度最高,明显优于基于ZTD的单因子PWV模型（4.66 mm）,而基于ZTD和P_s的双因子PWV模型RMS为0.50 mm。     

Tidal effect on dynamics of pore water nitrate in intertidal sediment of a eutrophic Estuary

To evaluate the effect of the tidal cycle on the pore water nitrate dynamics in intertidal sediment, concentrations of inorganic nitrogen in water and sediment were monitored during tidal cycles in the mud flat of Tama Estuary, Japan. During submergence, nitrate concentration was highest in the overlying water and decreased monotonically with increasing depth in the sediment, suggesting that the primary source of nitrate in the sediment was nitrate transported from the overlying water. Pore water nitrate decreased remarkably during the initial 3–4 hours after the onset of exposure. Thereafter, it was constant or slightly increased until tidal flooding.In situ accumulation of nitrate at the end of exposure, however, did not exceed the nitrate concentrations in the overlying water. The inhibition of nitrate reduction and the stimulation of nitrification would explain the change of nitrate concentration, both consistent with the input of oxygen into the sediment following a 10 mm drop of the water table. In Tama Estuary sediments, the effect of the tidal cycle on the removal of combined nitrogen is rather negative, because high nitrate concentrations in the overlying water canceled the positive effect of nitrate accumulation by nitrification during exposure, while tidal oxygen intrusion have an inhibitory effection sedimentary denitrification.     

Bioassessment Techniques for Monitoring of Eutrophication and Nutrient Limitation in Coastal Ecosystems

Bioassesment by the use of the macroalga, Ulva lactuca L., was carried out in the Limfjord, Denmark, to assess the significance of nitrogen and phosphorus as limiting factors for primary production during 1985, 1993, 1994 and 1995 and for the detection of changes in eutrophication levels.

Minimum and critical tissue concentrations for nitrogen and phosphorus in macroalgae were identified. The concentrations of nitrogen were generally below the critical concentration level in June–October in 1985, 1993, and 1995 but in 1994 nitrogen was only limiting for primary production in short periods. Only in early spring in 1985 and 1993 were the tissue concentrations of phosphorus below the critical concentration level, whereas in 1994 up to 3–4 months showed phosphorus limited growth, indicating that significant changes in limitation patterns can occur between different years.

It was concluded that the use of biomonitoring techniques is well suited as a bioassessment method for direct detection and for providing a time-integrated measure of nutrient availability in coastal waters, and thus for assessing ecosystem health with regard to eutrophication. It is recommended that biomonitors and the concept of critical tissue concentrations should be used in environmental management and incorporated in future monitoring programmes.     

INTERACTION BETWEEN TROPICAL CYCLONE AND MEIYU FRONT*

Generally speaking,the convection activities are inactive over western Pacific warm pool and tropical cyclone (TC) activity seldom occurs over the offshore of East Asia during the period of Meiyu rainfall.However,if a TC is active in this area,the Meiyu rainfall will often weaken or end up.Based on a statistical study with the data from 1980 to 1995,it is found that about 91% of 23 TC activities affected the intensity of Meiyu rainfall,and 50% of the end-up of Meiyu events were related to the active TCs and the change of subtropical high.The present paper simulates the effect of TC on Meiyu circulation by using MM4 model,and the results agree with the observations.From the point of view of vapor and energy transport,the landing of TC cuts not only the transport of the water vapor to Changjiang-Huaihe River basin from the Bay of Bengal but also the conversion of the mean flow energy to the Meiyu circulation because of the TC forcing to the zonal circulation.These two effects make the convection and perturbation existing in Meiyu region lack the supply of the vapor and energy for their maintenance and lead to the end of Meiyu rainfall.     

局部地形校正的精密算法

对局部地形校正中的中央区奇异积分部分进行非奇变换,使用Simpson公式和Cotes公式推导出两种中央区的数值计算方法。试算结果表明,新方法可有效地提高地形校正的精度。     

云南暴雨涡散场动能转换函数的动态分析

对1996年云南主汛期（6－8月）逐日散度风动能和旋转风动能之间的转换函数C（KD,KR）特征进行深入研究,同时分析了C（KD,KR）各项Af、Az、B、C在动能转换函数中所起的作用。研究结果表明,对流层内C（KD,KR）＞0,同时对流层低层的C（K,KR）＞中高层的C（KD,KR）之和．极易出现暴雨过程;Af项在整个动能转换中起主要作用,71％的Af与C（KD,KR）具有相同的符号,Az项和B项在动能转换中起振荡作用,Az＋B控制着29％的动能转换方向。     

含氮化合物的实验方法初步评价

对吡咯类含氮化合物的两种分离方法以及两步分离法中使用国产与进口试验的实验结果进行了对比与评价。结果表明,分离方法不同,所得吡咯类含氮化合物总体馏分的丰度也不同,一步分离法普遍低于两步法;不同分离方法对吡咯类化合物相对分布的影响较小。国产与进口试验性能不影响吡咯类含氮化合物的绝对丰度与相对分布的分析结果,两步分离法具备分析试剂国产化的条件。     

菜田施肥(化肥)对地下水氮污染影响的实验研究

为研究菜田施肥（化肥）对地下水氮污染的影响,进行了２个土柱模拟菜田施肥（化肥）残存量的实验．结果表明,土柱中化肥残存量的７２．０８％和４７．４４％从渗出水中流出．依据实验数据将实验过程分为３个可能阶段：第１阶段,化肥中的ＮＨ＋４被土壤吸附,并交换出土壤中的Ｋ＋＋Ｎａ＋,Ｃａ２＋和Ｍｇ２＋,使之进入渗出水中;第２阶段,为硝化作用增强的阶段,表现为土柱渗出水中ＮＯ－３的质量浓度比注入水有大幅度增加;第３阶段,为硝化作用强度减弱的阶段,表现为渗出水中ＮＯ－３的质量浓度比注入水增加的幅度减小．     

朝长地区原油中的有机含氮化合物及其应用

松辽盆地朝长地区 (朝阳沟—长春岭 )原油中含有丰富的吡咯类含氮化合物 ,其地球化学特征明显。与烃类化合物类似 ,非烃中吡咯类化合物可用于反映原油的成因类型。朝长地区原油中吡咯类化合物的分布特征及其运移效应为油气注入模型理论提供了很好的例证 ,表明吡咯类等非烃化合物在油藏地球化学理论与应用研究中具有广泛的前景。     

巢湖四条入湖河流硝态氮污染来源的氮稳定同位素解析

采用氮稳定同位素技术对巢湖四条主要污染输入河流(南淝河、十五里河、派河和双桥河)的氮污染状况和硝态氮来源进行研究.结果表明,巢湖四条入湖河流氮污染最严重的是十五里河,其次是南淝河和派河,双桥河的污染相对较轻.硝态氮的稳定同位素分析结果表明,巢湖四条入湖河流的硝态氮污染物在季节上受到不同因子的影响.十五里河和南淝河的硝态氮污染主要来源于城市生活污水和工业废水;派河的硝态氮污染在冬季主要来源于工业废水,春季来源于农业面源,而在夏季主要受到雨水的影响;双桥河的硝态氮污染冬、春季主要来源于农业面源,夏季主要受雨水的影响.此外本研究结果还表明巢湖四条主要入湖河流的氮污染源主要为铵态氮,因此今后要对铵态氮的来源进行同位素示踪.