绿柱石通道中配合物的振动光谱和辐照裂解

以四川平武富碱型绿柱石为研究对象 ,采用 IR和 L RM测试方法 ,重点对通道中氢化物和多聚合离子的配位构型、辐照裂解及热致转型进行了较深入系统的研究。研究表明 ,在该区成矿作用条件下 ,绿柱石通道中的钠离子趋向与氢离子化合反应生成 Na H氢化物 ,并占据通道中的 C2 位。在垂直 c轴方向上 ,以 3165 cm-1,3114 cm-1及 30 31cm-1伸缩振动弱吸收谱带为特征。[Fe2 ( OH) 4 ] 2 多聚合离子占据通道中的 C1位 ,以 32 34 cm-1伸缩振动锐吸收谱带为特征 (∥ c轴 )。辐照作用导致上述多聚合离子的裂解 ,并形成不稳定的 [H0 ] i心和相对稳定的 [Fe3 ] OH心。与之对应的吸收谱带分别出现在 3110 cm-1(⊥ c轴 )和 335 5cm-1(∥c轴 )处。通道中 Na H和 [Fe2 ( OH) 4 ] 2 多聚合离子的存在 ,可视为该类型绿柱石的一个重要的成因标志。     

辐照绿柱石的色心与赋色机制

在不同辐照剂量的带电粒子作用下，四川无色绿柱石因赋色而呈现浅蓝色，蓝绿色，黄绿色，浅黄色及橙黄色，紫外可见吸收光谱（UV－VIS）和阴极发光光谱（CLS）研究表明，辐照绿柱石中存在两组与赋色密切相关的色心组合，其一为相对稳定的[Fe^3 ]OH和[Fe^3 4]心，其二则为不稳定的[H^0]i心和F^ 心，二者对可见光的能量分别具有不同程度的选择性吸收和发射，由此产生特征的吸收与发射光谱。低温退火处理（210℃），有助于消除辐照绿柱石中不稳定的色心，使相对稳定的[Fe^3 ]OH心黉度再度聚集，并形成新的缺陷（二次缺陷），进而提高稳定色心的主波长和饱和度。研究证实，二次缺陷形成的初始温度，可近似代表辐照绿柱石的最佳热固色温度点，经辐照与热固色作用而形成的黄色，橙黄色绿柱石的颜色相对稳定，并不因长期日照或低温受热（＜280℃）而褪色。     

绿柱石的辐照赋色与效应

利用电子加速器为辐照源，对四川，新疆等产的无色绿柱石进行了辐照改色处理。在改色实验中，对辐照源的输出功率，电子能量，扫描面积，扫描速度，辐照剂量等参数，及辐照后样品的辐照效应，环境适应性，时效考验等特性进行了较系统的实验研究，并拟定出一套适合不同成因的无色绿柱石辐照改色的优选方案，对绿柱石的辐照机制和应效进行了探讨。     

Investigating the ancient Martian magnetic field using microwaves

The new microwave palaeointensity technique has been used to investigate samples from the Martian meteorite Nakhla. This technique is a promising new way to obtain absolute palaeointensity information regarding the ancient Martian magnetic field as recorded by the Martian meteorites. Assuming that a part of the magnetic remanence is of thermal origin and originating on Mars the two samples studied yield estimates of 4 μT for the Martian magnetic field at 1.35 Ga.     

扁椭球形雨滴和冰粒后向散射实验与理论研究

本文介绍了对扁椭球形雨滴和冰（雹）粒散射能力的实验模拟和测量技术，报告了一个系列扁水(冰)椭球后向散射截面的实验测量结果；并用扩张边界条件法(EBCM)计算出相应的理论值，用Mie公式计算出等容积球形后向散射截面。将实验结果与理论计算作了综合对比分析，得到了若干有用的结论。     

微波炉在重量法测定硫中的应用

采用玻璃砂芯坩埚过滤BaSO_4沉淀,微波炉代替马弗炉恒重坩埚、沉淀,重量法测定了矿石中的硫。方法准确,精密度好。微波炉不需预先升温,加热6min可达恒重,省时、省电。     

基于地基微波辐射计资料对成都双流机场两次雷雨过程的分析

利用地基微波辐射计资料,比较了2017年7月成都双流机场的两次雷雨过程,根据天气形势分为"两高切变"和"东高西低"2类,在此基础上分析微波辐射计要素变化特征,结果表明:在垂直方向0～10 km,以相对湿度达到80%来区分干区和湿区,则两次过程前3 h,相对湿度在垂直方向均呈现"上下干、中间湿"三层结构,并早于近地层前2 h达到饱和状态;过程期间相对湿度呈现"上干、下湿"两层结构;过程结束后湿层抬高,低层变干。两次过程水汽含量充沛,保持在70 kg/m~2以上,峰值超过85 kg/m~2。每一次中阵雨发生后水汽含量都会短暂回落,但仍高于过程前的数值,不足2 h后再次发生中阵雨。由0℃线高度变化可知,降水过程中,暖区(温度≥0℃)内相对湿度≥90%;云中液态水含量主要分布于6 km以下,温度在0℃以上的液态水占比很高,故两次过程以暖云降水为主。雷雨前1 h左右有"低层气温上升,0℃层抬升,K指数、CAPE指数也明显增大"的典型特征。降水发生在相对湿度、水汽总含量、云中液态水含量和稳定度指数快速增长的波峰中。     

Spectral index determination between 408 MHz and 5 GHz in the northern sky

We present the joint analysis of two 5-GHz interferometric surveys of the northern sky, taken with different baselines. The two surveys were carried out on the Jodrell Bank 5-GHz interferometer based at Manchester. The Maximum Entropy Method is used to check the consistency of the two surveys and the final two-dimensional maps are used, together with low-frequency full sky surveys, to put constraints on the Galactic spectral index. It is found that synchrotron emission is the dominant process at high Galactic latitudes below 5 GHz.     

Space-time soil wetness variations monitoring by a multi-temporal microwave satellite records analysis

In the last few years, remote sensing observations have become a useful tool for providing hydrological information, including the quantification of the main physical characteristics of the catchment, such as topography and land use, and of its variables, like soil moisture or snow cover. Moreover, satellite data have also been largely used in the framework of hydro-meteorological risk mitigation.Recently, an innovative Soil Wetness Variation Index (SWVI) has been proposed, using data acquired by the microwave radiometer AMSU (Advanced Microwave Sounding Unit) which flies aboard NOAA (National Oceanic and Atmospheric Administration) satellites.SWVI is based on a general approach for multi-temporal satellite data analysis (RAT - Robust AVHRR Techniques). This approach exploits the analysis of long-term multi-temporal satellite records in order to obtain a former characterization of the measured signal, in term of expected value and natural variability, providing a further identification of signal anomalies by an automatic, unsupervised change-detection step. Such an approach has already demonstrated, in several studies carried out on extreme flooding events which occurred in Europe in the past few years, its capability in reducing spurious effects generated by natural/observational noise. In this paper, the proposed approach is applied to the analysis of the flooding event which occurred in Europe (primarily in NW Spain) in June 2000. Results obtained, in terms of reliability as well as efficiency in space-time monitoring of soil wetness variation, are presented. Future prospects, in terms of exportability of the methodology on the new dedicated satellite missions, like ESA-SMOS and NASA-HYDROS, are also discussed.     

微波消解-等离子体发射光谱法同时测定水中硅铁钠

讨论使用电感耦合等离子体发射光谱法测定水样中si、Fe、Na时，四种水样前处理方法对测试结果的影响。提出采用HNO3^-HF体系微波消解、H3BO3掩蔽HF的方法前处理水样，用等离子体发射光谱法可同时准确快速地测定水中Si、Fe、Na三种元素的含量。5次测定的相对标准偏差小于4％，加标回收率为89．2％-106％。