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对氯甲烷的海洋生物地球化学循环的研究进展进行述评。介绍了氯甲烷在海洋环境中的来源、分布、去除、海-气通量、大气氯甲烷的源、汇估算及海水中氯甲烷的分析方法等方面,并提出在国内海域进行氯甲烷研究的几点设想。 相似文献
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Mercury and methylmercury biogeochemistry in a thawing permafrost wetland complex,Northwest Territories,Canada
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In arctic and sub‐arctic environments, mercury (Hg), more specifically toxic methylmercury (MeHg), is of growing concern to local communities because of its accumulation in fish. In these regions, there is particular interest in the potential mobilization of atmospherically deposited Hg sequestered in permafrost that is thawing at unprecedented rates. Permafrost thaw and the resulting ground surface subsidence transforms forested peat plateaus into treeless and permafrost‐free thermokarst wetlands where inorganic Hg released from the thawed permafrost and draining from the surrounding peat plateaus may be transformed to MeHg. This study begins to characterize the spatial distribution of MeHg in a peat plateau–thermokarst wetland complex, a feature that prevails throughout the wetland‐dominated southern margin of thawing discontinuous permafrost in Canada's Northwest Territories. We measured pore water total Hg, MeHg, dissolved organic matter characteristics and general water chemistry parameters to evaluate the role of permafrost thaw on the pattern of water chemistry. A gradient in vegetation composition, water chemistry and dissolved organic matter characteristics followed a toposequence from the ombrotrophic bogs near the crest of the complex to poor fens at its downslope margins. We found that pore waters in poor fens contained elevated levels of MeHg, and the water draining from these features had dissolved MeHg concentrations 4.5 to 14.5 times higher than the water draining from the bogs. It was determined through analysis of historical aerial images that the poor fens in the toposequence had formed relatively recently (early 1970s) as a result of permafrost thaw. Differences between the fens and bogs are likely to be a result of their differences in groundwater function, and this suggests that permafrost thaw in this landscape can result in hotspots for Hg methylation that are hydrologically connected to downstream ecosystems. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
15.
Long‐term monitoring of a mercury contaminated estuary (Ria de Aveiro,Portugal): the effect of weather events and management in mercury transport
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J. P. Coelho P. Pato B. Henriques A. Picado A. I. Lillebø J. M. Dias A. C. Duarte M. E. Pereira M. A. Pardal 《水文研究》2014,28(2):352-360
The main aim of this research was to assess the mercury transport from an estuarine basin with a background of anthropogenic contamination during a spring tidal cycle (year 2009) and compare it with two previous tidal cycles (years 1994 and 1999), as part of a long‐term monitoring program. Results showed that effective mercury transport occurs both in the dissolved and particulate fractions (0.18 and 0.20 kg per tidal cycle, respectively), and despite an overall decrease in environmental contamination, results more than double previous findings on particulate transport in the system. These findings result essentially from changes in the tidal prism (net export of 2 million m3 of water), given that both dissolved and particulate concentrations did not increase over time. Hydrodynamic simulations were performed to evaluate the effect of physical disturbance (dredging) and weather events (increased freshwater flow) in these processes, and results suggest the increased freshwater flow into the system as the main forcing function for the mercury transport increment. These results highlight the importance of long‐term monitoring programs, since despite an overall improvement in local contamination levels, the enhancement of transport processes through hydrological changes increases environmental pressure away from the contamination source. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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用巯基棉富集水中痕量汞,用饱和氯化钠的盐酸溶液解吸,冷原子吸收法测定。当水样取1 L时,最低检测浓度可达0-003 μg/L,方法相对标准偏差为3-8 % ~6-9 % ,巯基棉汞平均回收率为91-1% 。该法操作简单、快速、富集倍数大,适用于天然水中痕量汞的分析。 相似文献
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湖南洞庭湖地区土壤中Hg的来源 总被引:1,自引:0,他引:1
Hg污染已成为全球性的环境问题,尤其是Hg对土壤的污染,因其具有隐蔽性、不可逆性和长期性的特点,对陆生生态系统构成潜在的巨大威胁,因此查明土壤中Hg的来源非常重要。运用生态地球化学填图的指导思想,对湖南洞庭湖地区土壤剖面分析和成土过程研究后发现,表层土壤中Hg含量的高低与成土母质中Hg的含量有很好的对应性,成土过程对土壤中Hg的含量也有显著的影响。 相似文献
19.
L. Marini G. Ottonello M. Canepa F. Cipolli M. Vetuschi Zuccolini 《Environmental Geology》2000,40(1-2):234-242
Systematic stream sediment investigation in a periurban area surrounding Genoa (Italy) revealed the existence of a significant
mercury anomaly localized on the main (3rd rank) bed of the Bisagno river. Statistical multivariate analysis of elemental
abundances points out the anthropic nature of this contamination. Because of the well-known bioaccumulation of Hg in contaminated
media, attention must be focused on the risks associated with the discovered pollution.
Received: 30 November 1999 · Accepted: 22 March 2000 相似文献
20.
J.P. Coelho M. Nunes M. Dolbeth M.E. Pereira A.C. Duarte M.A. Pardal 《Estuarine, Coastal and Shelf Science》2008
The annual total and organic mercury bioaccumulation pattern of Scrobicularia plana and Hediste diversicolor was assessed to evaluate the potential mercury transfer from contaminated sediments to estuarine food webs. S. plana was found to accumulate more total and organic mercury than H. diversicolor, up to 0.79 mg kg−1 and 0.15 mg kg−1 (wet weight) respectively, with a maximum annual uptake of 0.21 mg kg−1 y−1, while for methylmercury the annual accumulation was similar between species and never exceeded 0.045 mg kg−1 y−1. The higher organic mercury fraction in H. diversicolor is related to the omnivorous diet of this species. Both species increase methylmercury exposure by burrowing activities and uptake in anoxic, methylmercury rich sediment layers. Integration with the annual biological production of each species revealed mercury incorporation rates that reached 28 μg m−2 y−1, and to extract as much as 11.5 g Hg y−1 (of which 95% associated with S. plana) in the 0.4 km2 of the most contaminated area, that can be transferred to higher trophic levels. S. plana is therefore an essential vector in the mercury biomagnification processes, through uptake from contaminated sediments and, by predation, to transfer it to economically important and exploited estuarine species. 相似文献