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131.
132.
有关煤成烃的基本认识 总被引:7,自引:0,他引:7
在煤化作用过程中,煤岩组分产出气相和液相物质的同时,固相煤岩组分本身也遭受改造。现今的固相煤岩组分与已产出的气相和液捐物质都是它们共有“前身”演化的“产物”,所以只根据固相煤岩组分的生烃潜能作为评价油气资源的依据还不够理想。煤在短时间高温条件下的热演化,与煤在漫长地质时期、低温条件下自然煤化作用过程中的热化有本质差异,用热解实验方法研究煤成烃尚存在一定问题。煤层内的气处在吸附一解吸和运移的动态平衡状态,决定煤层含气的主导因素是煤层的储气和运移条件,生烃潜能不起主导作用。 相似文献
133.
Role of coal type and rank on methane sorption characteristics of Bowen Basin, Australia coals 总被引:5,自引:0,他引:5
The effect of coal composition, particularly the organic fraction, upon gas sorption has been investigated for Bowen Basin and Sydney Basin, Australia coals. Maceral composition influences on gas retention and release were investigated using isorank pairs of hand-picked bright and dull coal in the rank range of high volatile bituminous (0.78% Ro max) to anthracite (3.01% Ro max). Adsorption isotherm results of dry coals indicated that Langmuir volume (VL) for bright and dull coal types followed discrete, second-order polynomial trends with increasing rank. Bright coals had a minimum VL at 1.72% Ro max and dull coals had a minimum VL at 1.17% Ro max. At low rank, VL was greater in bright coal by about 10 cm3/g, but as rank increased, the bright and dull trends converged and crossed at 1.65% Ro max. At ranks higher than 1.65% Ro max, both bright and dull coals followed similar trends. These competing trends mean that the importance of maceral composition on VL varies according to rank. In high volatile bituminous coals, increases in vitrinite content are associated with increases in adsorption capacity. At ranks higher than medium to low volatile bituminous, changes in maceral composition may exert relatively little influence on adsorption capacity. The Langmuir pressure (PL) showed a strong relationship of decreasing PL with increasing rank, which was not related to coal type. It is suggested that the observed trend is related to a decrease in the heterogeneity of the pore surfaces, and subsequent increased coverage by the adsorbate, as coal rank increases. Desorption rate studies on crushed samples show that dull coals desorb more rapidly than bright coals and that desorption rate is also a function of rank. Coals of lower rank have higher effective diffusivities. Mineral matter was found to have no influence on desorption rate of these finely crushed samples. The evolution of the coal pore structure with changing rank is implicated in diffusion rate differences. 相似文献
134.
There are abundant coal and coalbed methane(CBM)resources in the Xishanyao Formation in the western region of the southern Junggar Basin,and the prospects for CBM exploration and development are promising.To promote the exploration and development of the CBM resources of the Xishanyao Formation in this area,we studied previous coalfield survey data and CBM geological exploration data.Then,we analyzed the relationships between the gas content and methane concentration vs.coal seam thickness,burial depth,coal reservoir physical characteristics,hydrogeological conditions,and roof and floor lithology.In addition,we briefly discuss the main factors influencing CBM accumulation.First,we found that the coal strata of the Xishanyao Formation in the study area are relatively simple in structure,and the coal seam has a large thickness and burial depth,as well as moderately good roof and floor conditions.The hydrogeological conditions and coal reservoir physical characteristics are also conducive to the enrichment and a high yield of CBM.We believe that the preservation of CBM resources in the study area is mainly controlled by the structure,burial depth,and hydrogeological conditions.Furthermore,on the basis of the above results,the coal seam of the Xishanyao Formation in the synclinal shaft and buried at depths of 700-1000 m should be the first considered for development. 相似文献
135.
现有常规油气井产出剖面测试方法在煤层气井中适应性较差,测试范围和测量工艺等存在局限性,施工成功率低。因此,本文对煤层气井产出剖面测试技术进行了整体的系统化设计和研发。通过紧凑的结构设计、高度集成,研发了一套可同时进行温度、压力、磁性定位、热式流量、探针持气率、微波持气、涡轮流量和超声流量等多参数测量的煤层气井测井仪,并研制了一套一次下井可进行多种测试技术测量的煤层气井产出剖面测试技术。同时提高了测试仪器的精度和抗干扰能力,开发了多任务多窗口的便携地面系统操作,并研制新型偏心测试井口应用于煤层气井,实现修井作业时不间断连续测试。该技术在鄂尔多斯盆地石楼北区块3口煤层气井进行了现场试验,取得精确、连续的测试数据。测试结果显示,石楼北区块8#+9#煤层为主力产气、产水层。 相似文献
136.
Dan Lei Jia Liu Junwei Zhang Andreas Lorke Shangbin Xiao Yuchun Wang Wei Wang Ye Li 《洁净——土壤、空气、水》2019,47(9)
Four field campaigns are carried out to quantify the methane (CH4) oxidation rate in Xiangxi Bay (XXB) of the Three Gorges Reservoir (TGR), China. The water depth of the sampling site varied from 13 to 30 m resulting from the water level fluctuation of the TGR. The CH4 oxidation rates are measured in situ as the decline of dissolved CH4 concentration versus time in incubated, and those rates. The CH4 oxidation rates range from 1.18 × 10?3 to 3.69 × 10?3 µmol L?1 h?1, with higher values and stronger variation during summer. A static floating chamber method is used to measure CH4 emitted to the atmosphere resulting in an annual mean flux of 4.79 µmol m?2 h?1. The CH4 emission rate is significantly negatively correlated with the water level. The results show that a large fraction of CH4 is consumed in the water column with a range of 28.97–55.90 µmol m?2 h?1, accounting for ≈69–98% of the total CH4 input into the water column, and more than 90% is consumed outside the summer, when the water level is lowest. Water depth, which is dominated by water level of the TGR, is a potentially important driver for CH4 oxidation and atmospheric emission in the tributary bay. 相似文献
137.
In this comment we argue that the premise on which the peat mound model developed by Armstrong (Earth Surface Process and Landforms, 1995, 20 , 473–477) is based, that hydraulic conductivity shows an exponential decline with depth in bog peats, is unsound. Empirical evidence in the literature for such an exponential decline is less sound than Armstrong suggests. In addition, Armstrong's suggestion that the hypothesis of Baird and Gaffney (Earth Surface Processes and Landforms, 1995, 20 , 561–566) supports an exponential decline is shown to be erroneous. 相似文献
138.
Anatoly Obzhirov 《世界地质(英文版)》2006,9(2)
The research works of methane concentration in water column of the Okhotsk Sea from 1984 to 2005 were reviewed. And some regularities of methane distribution in water column in the North-East Sakhalin slope of the Okhotsk Sea were concluded. 相似文献
139.
为实现天然气水合物开采过程沉积物内甲烷气泄漏过程有效监测,设计了一种海床基原位电学监测方法。为界定该方法对不同模式泄露甲烷气的探测能力,以南海神狐海域天然气水合物试采区为研究区,构建相应地质及电阻率模型,模拟利用设计电学系统对其进行监测,计算得到不同采集参数的电阻率剖面,并对其进行对比分析。研究结果表明:海水层会在探测剖面上某深度区间内形成层状低阻异常带,对该深度区间有效电信号形成压制。将该异常带顶界深度定义为系统有效探测深度后,发现该深度受电极距直接影响,10 m极距偶极装置有效探测深度约为50 m。电学探测剖面对有效探测深度内分布的层状和团状甲烷气聚集区、慢速甲烷气泄露区、沿断层泄露的甲烷气区具有良好反映能力,数据处理得到的相对电阻率剖面与电学探测剖面相比能更好地反映甲烷气聚集区边界。该监测方法能够实时监测含气区空间变化。 相似文献
140.
南海东北部冷泉区沉积物中有机质来源的生物标志物分析与环境指示意义 总被引:2,自引:2,他引:0
Multi-biomarker indexes were analyzed for two piston cores from potential cold seep areas of the South China Sea off southwestern Taiwan. Total organic carbon(TOC) normalized terrestrial(n-alkanes) and marine(brassicasterol, dinosterol, alkenones and iso-GDGTs) biomarker contents and ratios(TMBR, 1/Pmar-aq, BIT) were used to evaluate the contributions of terrestrial and marine organic matter(TOM and MOM respectively) to the sedimentary organic matter, indicating that MOM dominated the organic sources in Core MD052911 and the sedimentary organic matter in Core ORI-_(86)0-22 was mainly derived from terrestrial inputs, and different morphologies were the likely reason for TOM percentage differences. BIT results suggested that river-transported terrestrial soil organic matter was not a major source of TOM of sedimentary organic matter around these settings.Diagnostic biomarkers for methane-oxidizing archaea(MOA) were only detected in one sample at 172 cm depth of Core ORI-_(86)0-22, with abnormally high iso-GDGTs content and Methane Index(MI) value(0.94). These results indicated high anaerobic oxidation of methane(AOM) activities at or around 172 cm in Core ORI-_(86)0-22.However in Core MD052911, MOA biomarkers were not detected and MI values were lower(0.19–0.38), indicated insignificant contributions of iso-GDGTs from methanotrophic archaea and the absence of significant AOM activities. Biomarker results thus indicated that the discontinuous upward methane seepage and insufficient methane flux could not induce high AOM activities in our sampling sites. In addition, the different patterns of TEX_(86) and U_(37)~(K′) temperature in two cores suggested that AOM activities affected TEX_(86)37 temperature estimates with lower values in Core ORI-_(86)0-22, but not significantly on TEX_(86) temperature estimates in Core MD052911. 相似文献